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    • 1. 发明公开
    • Method of making metal composite materials
    • Verfahren zur Herstellung von metallischem Verbundmaterial
    • EP0927772A1
    • 1999-07-07
    • EP98850182.1
    • 1998-12-01
    • SANDVIK AKTIEBOLAG
    • Waldenström, MatsSvensson, Rolf
    • C22C1/05
    • C22C1/051B22F1/025B22F2998/10B22F2999/00B22F9/24B22F9/22
    • According to the method of the present invention one or more metal salts of at least one iron group metal containing organic groups are dissolved in at least one polar solvent and complex bound with at least one complex former comprising functional groups in the form of OH or NR 3 , (R=H or alkyl). In addition at least one insoluble, reducible salt of at least one iron group metal is suspended in the solution. Hard constituent powder and, optionally, a soluble carbon source are added to the solution. The solvent is evaporated and powder mass is heat treated in inert and/or reducing atmosphere. As a result a powder mixture is obtained which after addition of pressing agent can be compacted and sintered according to standard practice to a body containing hard constituents in a binder phase.
    • 根据本发明的方法,将至少一种含有铁基金属的有机基团的一种或多种金属盐溶解在至少一种极性溶剂中,并与至少一种包含OH或NR 3形式的官能团的络合物结合的络合物 ,(R = H或烷基)。 此外,至少一种不可溶的至少一种铁族金属的可还原的盐悬浮在溶液中。 将硬组分粉末和任选的可溶性碳源加入到溶液中。 蒸发溶剂,并在惰性和/或还原气氛中热处理粉末物质。 结果得到粉末混合物,其中加入压制剂之后,按照标准做法将其压实并烧结成在粘结相中含有硬组分的物质。
    • 4. 发明公开
    • Method of making metal composite materials
    • Verfahren zur Herstellung von metallischem Verbundmaterial
    • EP1043411A2
    • 2000-10-11
    • EP00105246.3
    • 2000-03-14
    • SANDVIK AKTIEBOLAG
    • Waldenström, MatsSvensson, Rolf
    • C22C1/05
    • C22C1/051B22F2999/00C22C29/08B22F1/025B22F9/04
    • The present invention provides a method of producing a metal composite material by dissolving at least one inorganic metal salt of Mo and/or W optionally together with one or more organic iron group metal salts in water and possibly at least another polar solvent, complex binding the metals with at least one complex former comprising functional groups in the form of OH or NR 3 , (R=H or alkyl). The amount of said salt of Mo and/or W in the solution should be no more than 4 x 10 -3 x (wt% H 2 O) 2 g/100 ml solution and not less than 10 wt-% water. The method further includes adding hard constituent powder to the solution, evaporating the solvent and heat treating the remaining powder in an inert and/or reducing atmosphere. As a result coated hard constituent powder is obtained which after addition of pressing agent and optionally with other coated hard constituent powders and/or carbon to obtain the desired composition can be compacted and sintered according to standard practice.
    • 本发明提供一种通过将至少一种Mo和/或W的无机金属盐任选地与一种或多种有机铁族金属盐一起溶解在水中和可能地至少另一种极性溶剂中来制备金属复合材料的方法, 具有至少一个复合体的金属,其包含OH或NR 3(R = H或烷基)形式的官能团。 所述溶液中所述的Mo和/或W的盐的量应不超过4×10 -3(重量%H 2 O)2/10毫升溶液和不少于10重量%的水。 该方法还包括向溶液中加入硬组分粉末,蒸发溶剂并在惰性和/或还原气氛中热处理剩余的粉末。 结果,得到涂布的硬质组分粉末,其可以按照标准实践压制和加入加压剂和任选与其它涂覆的硬质组分粉末和/或碳以获得所需组合物之后。
    • 5. 发明公开
    • Method of making metal composite materials
    • Verfahren zur Herstellung von Metallverbundwerkstoffen
    • EP0916743A1
    • 1999-05-19
    • EP98850155.7
    • 1998-10-08
    • SANDVIK AKTIEBOLAG
    • Waldenström, MatsSvensson, Rolf
    • C22C1/05C22C29/02
    • C22C1/051B22F2003/1032C22C1/053
    • According to the method of the present invention one or more organic or inorganic metal salts or compounds of at least one of the groups IV, V and VI of the periodic system particularly, V, Cr, Mo and W optionally together with one or more organic iron group metal salts are dissolved in at least one polar solvent with at least one complex former comprising functional groups in the form of OH or NR 3 , (R=H or alkyl) and complex bound with at least one complex former. Hard constituent powder and optionally soluble carbon source are added to the solution. The solvent is evaporated and remaining powder is heat treated in inert and/or reducing atmosphere. As a result coated hard constituent powder is obtained which after addition of pressing agent and optionally with other coated hard constituent powders and/or carbon to obtain the desired composition can be compacted and sintered according to standard practice.
    • 根据本发明的方法,一种或多种周期系统中IV,V和VI族中的至少一种的有机或无机金属盐或化合物,特别是V,Cr,Mo和W任选地与一种或多种有机 铁族金属盐溶解在至少一种极性溶剂中,其中至少一种含OH或NR 3(R = H或烷基)形式的官能团和与至少一个络合物结合的络合物的络合物。 将硬组分粉末和任选的可溶性碳源加入到溶液中。 蒸发溶剂,剩余的粉末在惰性和/或还原气氛中进行热处理。 结果,得到涂布的硬质组分粉末,其可以按照标准实践压制和加入加压剂和任选与其它涂覆的硬质组分粉末和/或碳以获得所需组合物之后。