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    • 9. 发明公开
    • CEMENTED CARBIDE AND COATED CEMENTED CARBIDE
    • 硬质合金和涂层硬质合金
    • EP3309267A1
    • 2018-04-18
    • EP16807393.0
    • 2016-06-02
    • Tungaloy Corporation
    • ORI, Shinya
    • C22C29/02B23B27/14
    • C22C29/02B22F7/06B22F2005/001B23B27/148B23B2228/10B23B2228/36C22C29/08
    • A cemented carbide and a coated cemented carbide are provided which each comprise a Zr carboxide and have fracture resistance. A cemented carbide according to the present invention is a cemented carbide comprising a hard phase containing tungsten carbide as its main component and a binder phase containing an element of at least one kind selected from the group consisting of Co, Ni and Fe as its main component, wherein: the cemented carbide comprises 75 mass% or more to 95 mass% or less of the hard phase and 5 mass% or more to 25 mass% or less of the binder phase in an inner region inner than a position of 500 µm in depth below a surface of the cemented carbide; the hard phase comprises a Zr carboxide; and Zr sur /Zr in is from 0.25 or more to 0.80 or less when an average content (volume%) of the Zr carboxide in a surface region which ranges from the surface of the cemented carbide to a depth of 500 µm therebelow is denoted by Zr sur and an average content (volume%) of the Zr carboxide in an inner region inner than the surface region is denoted by Zr in .
    • 提供了一种硬质合金和涂覆的硬质合金,每种硬质合金都包含Zr碳化物并具有抗断裂性。 根据本发明的硬质合金是一种硬质合金,其包含含有碳化钨作为其主要组分的硬质相和含有选自Co,Ni和Fe中的至少一种元素作为其主要组分的粘结相 其特征在于,所述超硬合金在所述硬质相中含有75质量%以上且95质量%以下的所述粘结相,并且所述硬质相的内部区域内的所述粘结相的含量为5质量%以上且25质量%以下, 在硬质合金表面下方的深度; 硬相包含Zr碳化物; Zrsur / Zrin在从超硬合金的表面到500μm以下的表面区域的Zr碳化物的平均含量(体积%)用Zrsur表示时为0.25以上且0.80以下, Zrin表示内表面区域内的内侧区域的Zr碳化物的平均含量(体积%)。