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1. 发明公开

EP1138750A3 Integrated hydroisomerization/alkylation process 无效
标题翻译：整体加氢异构/烷基化过程
公开(公告)号：EP1138750A3
公开(公告)日：2002-08-21
申请号：EP01107717.9
申请日：2001-03-30
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Randolph, Bruce B.
IPC分类号： C10G69/12
CPC分类号： C10G69/123
摘要： A novel integrated olefin processing scheme is provided where olefins and paraffins are processed to produce high octane gasoline blending components. The integrated process involves the processing of olefins by hydroisomerization to produce a hydroisomerate stream which is subsequently alkylated in an alkylation process with branched chain paraffin hydrocarbons to produce an alkylate product. The alkylate product can further be separated into various fractions, including propane, n-butane, i-butane and a C 5 + alkylate stream. The C 5 + alkylate stream can be separated into an i-pentane stream and a deisopentanized C 5 + alkylate stream.
摘要翻译：提供了一种新的整体烯烃加工方案，其中加工烯烃和石蜡以生产高辛烷值汽油调合组分。该综合方法涉及通过加氢异构化处理烯烃以产生氢化异构体流，随后在烷基化过程中用支链烷烃烃烷基化以产生烷基化产物。烷基化产物可以进一步分离成各种馏分，包括丙烷，正丁烷，异丁烷和C 5+烷基化物料流。可将C5 +烷基化物流分离成异戊烷流和脱异戊烷化的C5 +烷基化物流。

2. 发明公开

EP1008384A1 Method of preparation of silica supported perfluoroalkylsulfonic acid catalyst system and use thereof in the oligomerization of olefins 有权
标题翻译： Verfahren zur Herstellung eines全氟烷基磺酸 - 卡塔列斯系统
公开(公告)号：EP1008384A1
公开(公告)日：2000-06-14
申请号：EP99124064.9
申请日：1999-12-10
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Greenwood, Gil J. , Randolph, Bruce B.
IPC分类号： B01J31/02 , C10G50/00
CPC分类号： B01J31/0227 , B01J21/08 , B01J31/0225 , B01J37/036 , B01J2231/20 , C10G50/00
摘要： A method of preparing a catalyst system which comprises mixing a first solid material comprising at least one perfluoroalkylsulfonic acid salt with a second solid material comprising at least one silanol comprising hydroxy groups and silicon to form a gel comprising silica and the at least one perfluororalkylsulfonic acid salt, and contacting the gel with an acidic solution to convert at least a portion of the at least one perfluoroalkylsulfonic acid salt to at least one perfluoroalkylsulfonic acid is disclosed.
Alternatively, a method of preparing a catalyst system which comprises mixing at least one perfluoroalkylsulfonic acid salt with silica gel to form a gel comprising silica and at least one perfluororalkylsulfonic acid salt, and contacting the gel with an acidic solution to convert at least a portion of the at least one perfluororalkylsulfonic acid salt to at least one perfluororalkylsulfonic acid is disclosed.
The thus-obtained catalyst systems are employed as catalysts in the oligomerization of a hydrocarbon feedstock comprising unsaturated hydrocarbons.
摘要翻译：一种制备催化剂体系的方法，其包括将包含至少一种全氟烷基磺酸盐的第一固体材料与包含至少一种包含羟基和硅的硅烷醇的第二固体材料混合以形成包含二氧化硅和至少一种全氟烷基磺酸盐并且将凝胶与酸性溶液接触以将至少一部分至少一种全氟烷基磺酸盐转化为至少一种全氟烷基磺酸。或者，制备催化剂体系的方法包括将至少一种全氟烷基磺酸盐与硅胶混合以形成包含二氧化硅和至少一种全氟烷基磺酸盐的凝胶，并使该凝胶与酸性溶液接触以将至少一部分公开了至少一种全氟烷基磺酸盐至至少一种全氟烷基磺酸。由此获得的催化剂体系用作包含不饱和烃的烃原料的低聚反应中的催化剂。

3. 发明公开

EP0601599A1 Isoparaffin-Olefin Alkylation 失效
标题翻译： Verfahren zur Isoparaffin / Olefinalkylierung。
公开(公告)号：EP0601599A1
公开(公告)日：1994-06-15
申请号：EP93119974.9
申请日：1993-12-10
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Randolph, Bruce B. , Anderson, Richard Lee , Hensley, Harvey Dean
IPC分类号： C07C2/62
CPC分类号： B01J19/2465 , C07C2/62 , C07C2527/1206
摘要： An alkylation process for reacting alkylatable hydrocarbons in the presence of a sulfolane and hydrofluoric acid catalyst within a natural circulation reaction and circulation system.
摘要翻译：在环丁砜和氢氟酸催化剂存在下，在自然循环反应和循环系统内使烷基化烃反应的烷基化方法。

4. 发明公开

EP1167327A1 Isopentane disproportionation 有权
标题翻译： Verfahren zur Disproportionierung von Isopentan
公开(公告)号：EP1167327A1
公开(公告)日：2002-01-02
申请号：EP01113638.9
申请日：2001-06-18
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Randolph, Bruce B. , Hoover, Kenneth C. , Pfile, Martyn E.
IPC分类号： C07C6/10
CPC分类号： C07C6/10 , C07C2527/054 , C07C2527/1206 , C07C2531/025
摘要： A novel i-pentane disproportionation process is provided and includes contacting i-pentane with an acidic disproportionation catalyst in the presence of a lower paraffin co-feed and, optionally, in the presence of an initiator.
摘要翻译：提供了一种新型的戊烷歧化方法，包括在低级链烷烃共进料存在下和任选地在引发剂存在下使异戊烷与酸性歧化催化剂接触。

5. 发明公开

EP1016642A1 Process for pentane disproportionation 审中-公开
标题翻译： Verfahren zur Disproportioneren von Pentan
公开(公告)号：EP1016642A1
公开(公告)日：2000-07-05
申请号：EP99126138.9
申请日：1999-12-29
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Johnson, Marvin M. , Randolph, Bruce B.
IPC分类号： C07C6/10
CPC分类号： B01J31/38 , B01J27/12 , B01J27/135 , B01J31/0222 , C07C6/10 , C07C2527/1206 , C07C2527/135 , C07C2531/02 , C07C2531/38
摘要： A process for the disproportionation of pentane to alkanes containing fewer carbon atoms per molecule and alkanes containing more atoms per molecule in the presence of a catalyst composition containing hydrogen fluoride (HF), titanium tetrafluoride (TiF 4 ) and sulfolane.
摘要翻译：在含有氟化氢（HF），四氟化钛（TiF 4）和环丁砜的催化剂组合物存在下，戊烷分解成每分子含有较少碳原子的烷烃和每分子含有更多原子的烷烃的方法。

6. 发明授权

EP0568090B1 Isoparaffin-olefin alkylation 失效
标题翻译：异链烷烃/烯烃亚烷基
公开(公告)号：EP0568090B1
公开(公告)日：1996-08-28
申请号：EP93107058.5
申请日：1993-04-30
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Abbott, Ronald Gordon , Randolph, Bruce B.
IPC分类号： C07C2/62
CPC分类号： B01J31/0222 , B01J2231/323 , C01B7/191 , C07C2/62 , C07C2527/1206

7. 发明公开

EP0679607A1 Transportation of hydrogen fluoride 失效
标题翻译：运输vonFlusssäure。
公开(公告)号：EP0679607A1
公开(公告)日：1995-11-02
申请号：EP95106374.2
申请日：1995-04-27
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Randolph, Bruce B. , Anderson, Richard L. , Eldridge, Robert B.
IPC分类号： C01B7/19
CPC分类号： C01B7/195 , C01B7/191
摘要： An improved method for the safe transportation and handling of hydrogen fluoride.
摘要翻译：一种改进的氟化氢运输和处理方法。

8. 发明公开

EP0590631A1 Alkylation catalyst regeneration 失效
标题翻译： Regenerierung eines Alkylierungskatalysators。
公开(公告)号：EP0590631A1
公开(公告)日：1994-04-06
申请号：EP93115708.5
申请日：1993-09-29
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Eastman, Alan Dan , Randolph, Bruce B. , Abbott, Ronald Gordon , Eldridge, Robert Bruce
IPC分类号： B01J31/40 , C07C2/62
CPC分类号： B01J31/0222 , B01J21/18 , B01J27/08 , B01J27/12 , B01J27/32 , B01J31/40 , B01J2231/4205
摘要： Described is a novel process for regenerating an ASO contaminated alkylation catalyst which contains a sulfone component and a hydrogen halide component. The alkylation catalyst undergoes a series of separation steps to remove a significant portion of the hydrogen halide component contained therein followed by a phase separation between an ASO phase and a sulfone phase. The sulfone phase is then contacted with a carbon material to remove a portion of any remaining ASO contained in the sulfone.
摘要翻译：描述了一种用于再生包含砜组分和卤化氢组分的ASO污染的烷基化催化剂的新方法。烷基化催化剂经历一系列分离步骤以除去其中所含的卤化氢组分的显着部分，然后在ASO相和砜相之间进行相分离。然后将砜相与碳材料接触以除去砜中所含的任何剩余的ASO的一部分。

9. 发明公开

EP1138750A2 Integrated hydroisomerization/alkylation process 无效
标题翻译： Integriertes Hydroisomerizierungs- und Alkylierungsverfahren
公开(公告)号：EP1138750A2
公开(公告)日：2001-10-04
申请号：EP01107717.9
申请日：2001-03-30
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Randolph, Bruce B.
IPC分类号： C10G69/12
CPC分类号： C10G69/123
摘要： A novel integrated olefin processing scheme is provided where olefins and paraffins are processed to produce high octane gasoline blending components. The integrated process involves the processing of olefins by hydroisomerization to produce a hydroisomerate stream which is subsequently alkylated in an alkylation process with branched chain paraffin hydrocarbons to produce an alkylate product. The alkylate product can further be separated into various fractions, including propane, n-butane, i-butane and a C 5 + alkylate stream. The C 5 + alkylate stream can be separated into an i-pentane stream and a deisopentanized C 5 + alkylate stream.
摘要翻译：提供了一种新颖的烯烃加工方案，其中加工烯烃和链烷烃以产生高辛烷值汽油调和组分。整合方法涉及通过加氢异构化处理烯烃以产生加氢异构体物流，其随后在烷基化方法中用支链链烷烃烷基化以产生烷基化物产物。烷基化产物可以进一步分离成各种馏分，包括丙烷，正丁烷，异丁烷和C 5+烷基化物流。 C5 +烷基化物流可以分离为异戊烷流和去异戊烷化的C5 +烷基化物流。

10. 发明授权

EP0764623B1 Method for removing sulfolane present in hydrocarbon 失效
标题翻译：一种用于从烃中分离的环丁砜过程
公开(公告)号：EP0764623B1
公开(公告)日：1998-11-11
申请号：EP96114890.5
申请日：1996-09-17
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Anderson, Richard L. , Randolph, Bruce B.
IPC分类号： C07C7/10
CPC分类号： C07C7/10 , C07C2/62 , C07C9/16 , C07C2527/1206

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