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1. 发明公开

EP4222131A1 ALKYLATION PROCESS WITH THERMAL OXIDATION SYSTEM 审中-实审
公开(公告)号：EP4222131A1
公开(公告)日：2023-08-09
申请号：EP21876683.0
申请日：2021-07-30
申请人： Honeywell International Inc.
发明人： TERTEL, Jonathan A. , GATTUPALLI, Rajeswar R. , DE REN, Jan , WHYMAN, William , ROMAN, David A.
IPC分类号： C07C2/62 , B01D53/40 , C02F1/72

2. 发明公开

EP3655156A1 ALKYLATION CATALYST 无效转让
公开(公告)号：EP3655156A1
公开(公告)日：2020-05-27
申请号：EP18749616.1
申请日：2018-06-26
申请人： Exxonmobil Research And Engineering Company
发明人： NANDI, Partha , IDE, Matthew S. , DAKKA, Jihad M. , NIZAMI, Quddus A. , AFEWORKI, Mobae
IPC分类号： B01J29/70 , C07C2/62 , C01B39/02 , C07C2/66 , C10G29/12 , B01J27/12 , B01J23/14 , B01J27/135

3. 发明授权

EP1714952B1 SOLID CATALYTIC PROCESS FOR ALKYLATING AN AROMATIC HYDROCARBON OR AN ISOALKANE WITH AN OLEFIN 有权
标题翻译：具有固定催化剂的芳族烃或异烷烃与烯烃的烷基化方法
公开(公告)号：EP1714952B1
公开(公告)日：2016-10-05
申请号：EP05700461.6
申请日：2005-01-19
申请人： China Petroleum & Chemical Corporation , RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
发明人： HE, Yigong , MAN, Zheng
IPC分类号： C07C2/58 , C07C2/62 , C07C2/66 , C07C2/70 , C07C9/21 , C07C15/085 , B01J21/08 , B01J27/188
CPC分类号： C07C2/62 , B01J21/08 , B01J27/188 , C07C2/58 , C07C2/66 , C07C2/70 , C07C2521/04 , C07C2521/08 , C07C2527/053 , C07C2527/12 , C07C2527/18 , C07C2529/70 , Y02P20/52 , Y10S585/906 , C07C9/21 , C07C15/085

4. 发明公开

EP2597078A1 Alkylation process using an alkyl halide promoted pyridinium ionic liquid catalyst 有权转让
标题翻译：烷基卤化物烷基卤化物
公开(公告)号：EP2597078A1
公开(公告)日：2013-05-29
申请号：EP13156447.8
申请日：2007-03-20
申请人： Chevron U.S.A. Inc.
发明人： Elomari, Saleh
IPC分类号： C07C2/60 , C07C2/62 , C10G29/20
CPC分类号： C07C2/62 , C07C2/60 , C07C2527/11 , C07C2531/02 , C10G29/205
摘要： Disclosed is an alkylation process. The process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions in the presence of an acidic ionic liquid catalyst. The catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The acidic ionic liquid is a chloroaluminate ionic liquid prepared by mixing aluminum trichloride (AlCl 3 ) and a hydrocarbyl substituted pyridinium halide having the general formula A:

where R = H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate; and wherein the isoparaffin and the olefin are alkylated.
摘要翻译：公开了烷基化方法。该方法包括在酸性离子液体催化剂存在下，在烷基化条件下使包含至少一种具有2至6个碳原子的烯烃和至少一个具有3至6个碳原子的异链烷烃的烃混合物接触。催化剂包含至少一种酸性离子液体和至少一种烷基卤化物的混合物。酸性离子液体是通过将三氯化铝（AlCl 3）和具有通式A的烃基取代的吡啶鎓卤化物混合制备的氯铝酸盐离子液体，其中R = H，甲基，乙基，丙基，丁基，戊基或己基，X是氯铝酸盐; 并且其中异链烷烃和烯烃被烷基化。

5. 发明公开

EP1714952A1 SOLID CATALYTIC PROCESS FOR ALYLATING AROMATIC HYDROCARBON OR ISOMETRIC PARAFIN AND OLEFIN 有权
标题翻译：具有固定催化剂的芳族烃或异烷烃与烯烃的烷基化方法
公开(公告)号：EP1714952A1
公开(公告)日：2006-10-25
申请号：EP05700461.6
申请日：2005-01-19
申请人： China Petroleum & Chemical Corporation , RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
发明人： HE, Yigong , MAN, Zheng
IPC分类号： C07C2/62 , C07C2/70 , C07C9/21 , C07C9/14 , C07C15/00
CPC分类号： C07C2/62 , B01J21/08 , B01J27/188 , C07C2/58 , C07C2/66 , C07C2/70 , C07C2521/04 , C07C2521/08 , C07C2527/053 , C07C2527/12 , C07C2527/18 , C07C2529/70 , Y02P20/52 , Y10S585/906 , C07C9/21 , C07C15/085
摘要： The present invention discloses a process for alkylation of an aromatic hydrocarbon or isoalkane with an olefin over the catalysis of a solid acid, comprising contacting a reaction material containing an aromatic hydrocarbon or C 4 -C 6 isoalkane, C 2 -C 18 monoolefin and a compound containing a strongly electronegative element as promoter with a solid acid catalyst to carry out the alkylation, characterized in that the solid acid catalyst is contacted with a compound having a strongly electronegative element prior to its contact with the reaction material. Said process not only greatly increases the selectivity of the target product of the alkylation but also improves stability of the solid acid catalyst.
摘要翻译：本发明盘松处理的芳族烃的烷基化或与烯烃的异烷烃在固体酸的异烷烃催化，包括，使含有芳香族烃或C 4 -C 6的反应材料，C 2 -C 18单烯烃和一化合物含有强电负性元素作为助催化剂与固体酸催化剂，进行烷基化，在DASS特点死固体酸催化剂是具有其与反应材料接触之前，具有强电负性元素的化合物接触。所述方法不仅大大提高了烷基化的目标产物的选择性，但这样改进了固体酸催化剂的稳定性。

6. 发明授权

EP1286938B1 METHOD AND DEVICE FOR THE PRODUCTION OF ALKYLATES 有权
标题翻译：方法和设备用于生产烷基化物
公开(公告)号：EP1286938B1
公开(公告)日：2006-04-19
申请号：EP01932030.8
申请日：2001-06-01
申请人： Orgral International Technologies Corporation
发明人： GERSHUNI, Semen
IPC分类号： C07C2/62 , B01F5/02
CPC分类号： C07C2/62 , B01J19/088 , B01J2219/0809 , B01J2219/083 , B01J2219/0835 , B01J2219/0839 , B01J2219/0875 , B01J2219/0879 , B01J2219/0886 , B01J2219/0894 , C07C2527/054
摘要： Disclosed is a device for the production of alkylate(s) by sulfuric acid alkylation of at least one isoparaffin such as isobutane with at least one olefin, such as butylenes. The device includes a mixing chamber for preparing a mixture of the isoparaffin with recycled reaction products. It also includes an emulsion chamber for preparing a first hydrocarbons-in-sulfuric acid emulsion, where the mixture prepared in the mixing chamber is injected in multiple parallel jets into a sulfuric acid composition. The device further includes a pre-reaction chamber for preparing a second emulsion, where a given portion of the olefin is injected in jet streams into the first hydrocarbons-in-sulfuric acid emulsion coming from the emulsion chamber. Last of all, the device includes a reaction chamber of given height and cross-section where the second emulsion coming from the pre-reaction chamber is injected through nozzles and another portion of olefin is injected in jet streams all over the cross-section and height of the reaction chamber. The reaction chamber is devised so that the second emulsion is circulated in a closed circuit and it has an outlet through which a balanced amount of reaction mixture is continuously discharged. All of said mixing chamber, emulsion chamber, pre-reaction chamber and reaction chamber are coaxially arranged one above the other in vertical position and altogether form a reactor with the prechamber being located at the bottom of the reactor and the reaction chamber on top thereof. A method for the production of alkylates by means of the above device is also disclosed.

7. 发明公开

EP1558549A2 METHOD OF REMOVING ENTRAINED SULFURIC ACID FROM ALKYLATE BACKGROUND OF THE INVENTION 审中-公开
标题翻译：从烷基化物中除去被吸收的硫酸的方法发明背景
公开(公告)号：EP1558549A2
公开(公告)日：2005-08-03
申请号：EP03749730.2
申请日：2003-09-17
申请人： Catalytic Distillation Technologies
发明人： SMITH, Lawrence, A., Jr.
IPC分类号： C07C2/62 , C07C7/144
CPC分类号： C07C7/04 , C07C2/62 , C07C2527/054 , C07C9/14
摘要： An improvement in the alkylation of olefins with isoalkanes in the presence of sulfuric acid wherein the sulfuric acid is removed from the product by a mechanical coalescer means prior to fractionation. No water wash or caustic treatment is required. Any sulfonates or sulfonic esters are removed by hydrodesulfurization or decomposition catalyst in a separate reactor or in either the deisobutanizer (DIB) or debutanizer (DB) column.
摘要翻译：在硫酸存在下用异烷烃烷基化烯烃的改进，其中在分馏之前通过机械聚结器将硫酸从产物中除去。不需要水洗或苛性处理。任何磺酸盐或磺酸酯都可通过加氢脱硫或分解催化剂在单独的反应器中或在脱异丁烷（DIB）或脱丁烷（DB）塔中除去。

8. 发明公开

EP1286938A1 METHOD AND DEVICE FOR THE PRODUCTION OF ALKYLATES 有权
标题翻译：方法和设备用于生产烷基化物
公开(公告)号：EP1286938A1
公开(公告)日：2003-03-05
申请号：EP01932030.8
申请日：2001-06-01
申请人： Orgral International Technologies Corporation
发明人： GERSHUNI, Semen
IPC分类号： C07C2/62 , B01F5/02
CPC分类号： C07C2/62 , B01J19/088 , B01J2219/0809 , B01J2219/083 , B01J2219/0835 , B01J2219/0839 , B01J2219/0875 , B01J2219/0879 , B01J2219/0886 , B01J2219/0894 , C07C2527/054
摘要： Disclosed is a device for the production of alkylate(s) by sulfuric acid alkylation of at least one isoparaffin such as isobutane with at least one olefin, such as butylenes. The device includes a mixing chamber for preparing a mixture of the isoparaffin with recycled reaction products. It also includes an emulsion chamber for preparing a first hydrocarbons-in-sulfuric acid emulsion, where the mixture prepared in the mixing chamber is injected in multiple parallel jets into a sulfuric acid composition. The device further includes a pre-reaction chamber for preparing a second emulsion, where a given portion of the olefin is injected in jet streams into the first hydrocarbons-in-sulfuric acid emulsion coming from the emulsion chamber. Last of all, the device includes a reaction chamber of given height and cross-section where the second emulsion coming from the pre-reaction chamber is injected through nozzles and another portion of olefin is injected in jet streams all over the cross-section and height of the reaction chamber. The reaction chamber is devised so that the second emulsion is circulated in a closed circuit and it has an outlet through which a balanced amount of reaction mixture is continuously discharged. All of said mixing chamber, emulsion chamber, pre-reaction chamber and reaction chamber are coaxially arranged one above the other in vertical position and altogether form a reactor with the prechamber being located at the bottom of the reactor and the reaction chamber on top thereof. A method for the production of alkylates by means of the above device is also disclosed.

9. 发明公开

EP0987237A3 Process for the catalytic alkylation of a hydrocarbon feed 有权
标题翻译：处理烃进料的催化烷基化
公开(公告)号：EP0987237A3
公开(公告)日：2001-01-10
申请号：EP99117305.5
申请日：1999-09-03
申请人： Haldor Topsoe A/S
发明人： Hommeltoft, Sven Ivar
IPC分类号： C07C2/62 , B01J31/02 , C07C2/70
CPC分类号： C07C2/70 , C07C2/62 , C07C2531/025
摘要： Process for the alkylation of paraffinic and/or aromatic hydrocarbon feedstock with an olefinic alkylating agent by contact with a perfluorinated alkyl sulphonic acid movably adsorbed within a confined area of a fixed bed of particle contact material, wherein the fixed bed of particle contact material is subdivided in a number of elongated channels.

10. 发明授权

EP0703002B1 Regeneration of hydrogen fluoride alkylation catalyst 失效
标题翻译：氟化氢烷基化催化剂的再生
公开(公告)号：EP0703002B1
公开(公告)日：1999-11-03
申请号：EP95113560.7
申请日：1995-08-29
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Carlson, LeRoy W.
IPC分类号： B01J27/32 , C07C2/62
CPC分类号： B01J27/32 , C07C2/62 , C07C2527/1206 , Y02P20/584

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