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    • 6. 发明公开
    • METHOD FOR SEPARATING PERFLUORO(POLY)ETHER-GROUP-CONTAINING ALCOHOL COMPOUNDS
    • EP3505553A1
    • 2019-07-03
    • EP17843689.5
    • 2017-08-24
    • Daikin Industries, Ltd.
    • NAITOU, MasatoNOMURA, TakashiTAKANO, Shinya
    • C08G65/30B01D15/42
    • The present invention provides a method for chromatographically separating a mixture comprising a perfluoro(poly)ether group-containing monoalcohol compound represented by the following formula (2) and a perfluoro(poly)ether group-containing dialcohol compound represented by the following formula (3):

              A-Pf-Z ···     (2)

              Z-Pf-Z ···     ((3)

      wherein
      Pf represents a divalent perfluoropolyether group,
      A each independently represents an R 1 - group, an R 1 -O-group, an R 2 O-CH 2 -R 3 - group, or an R 2 O-CH 2 -R 3 -O- group,
      R 1 each independently represents an alkyl group,
      R 2 each independently represents an alkyl group,
      R 3 each independently represents a divalent organic group containing 1 to 4 carbon atoms,
      Z each independently represents an -R 5 -CH 2 OH group or an -O-R 5 -CH 2 OH group, and
      R 5 each independently represents a bond or a divalent organic group containing 1 to 4 carbon atoms,
      the method comprising:
      adsorbing the mixture onto a stationary phase, and
      eluting the perfluoro(poly)ether group-containing monoalcohol compound represented by formula (2) by one mobile phase selected from the group consisting of hydrofluorocarbons, hydrochlorofluorocarbons, hydrofluoroethers, fluorine-containing ester solvents, and fluorine-containing aromatic solvents to separate the perfluoro(poly)ether group-containing monoalcohol compound represented by formula (2) from the perfluoro(poly)ether group-containing monoalcohol compound represented by formula (3).