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    • 1. 发明公开
    • FILM-FORMING COMPOSITION INCLUDING FLUORINE-CONTAINING SURFACTANT
    • 迷迭香ZUSAMMENSETZUNG MIT FLUORHALTIGEM TENSID
    • EP3106921A1
    • 2016-12-21
    • EP15749601.9
    • 2015-01-30
    • Nissan Chemical Industries, Ltd.
    • UMEZAKI, MakikoKARASAWA, RyoSHIGAKI, ShuheiMIZUOCHI, Ryuta
    • G03F7/11C08L33/04C08L101/00C08L101/04
    • C09D133/12C08F220/14C08L33/14C08L101/00C08L101/04G03F7/0752G03F7/094G03F7/11G03F7/16G03F7/20G03F7/30H01L21/0276C08F212/14
    • There is provided a film with reduced formation of an edge reservoir at a periphery of a film in which the edge reservoir causes an unnecessary residue that cannot be removed by an etching process, and a method for forming the film. A film forming composition for use in a lithography process, the film forming composition comprising a surfactant containing a polymer and an oligomer having a C 3-5 perfluoroalkyl partial structure. The perfluoroalkyl partial structure preferably has a carbon number of 4. The perfluoroalkyl partial structure may further include an alkyl partial structure, and the polymer and the oligomer are preferably a (meth)acrylate polymer and a (meth)acrylate oligomer, respectively. The surfactant is contained in an amount of 0.0001% by mass to 1.5% by mass based on the total solid content of the film forming composition. The film forming composition further comprises a coating film resin, and the coating film resin is a novolac resin, a condensation epoxy resin, a (meth)acylic resin, a polyether-based resin, or a silicon-containing resin, etc. The formed film can be used as a resist underlayer film or a resist overlayer film.
    • 提供了一种薄膜,其在边缘储存器的周围形成边缘储存器,其中边缘储存器引起不能通过蚀刻工艺去除的不必要的残留物,以及用于形成膜的方法。 一种用于光刻工艺的成膜组合物,所述成膜组合物包含含有聚合物的表面活性剂和具有C 3-5全氟烷基部分结构的低聚物。 全氟烷基部分结构优选碳数为4.全氟烷基部分结构还可以包括烷基部分结构,聚合物和低聚物分别优选为(甲基)丙烯酸酯聚合物和(甲基)丙烯酸酯低聚物。 表面活性剂的含量相对于成膜组合物的总固体成分为0.0001质量%〜1.5质量%。 成膜组合物还包含涂膜树脂,涂膜树脂是酚醛清漆树脂,缩合环氧树脂,(甲基)酰基树脂,聚醚基树脂或含硅树脂等。形成的 膜可以用作抗蚀剂下层膜或抗蚀剂覆盖膜。