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1. 发明公开

EP1151983A4 PROCESS FOR CONTINUOUSLY PRODUCING TETRACYCLODODECENE COMPOUND 有权
标题翻译： VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG EINES TETRACYCLODODECEN-DERIVATES
公开(公告)号：EP1151983A4
公开(公告)日：2005-02-16
申请号：EP00974907
申请日：2000-11-10
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： AIDA FUYUKI , SUZUKI TAKASHI , MATSUMURA YASUO
IPC分类号： C07C2/50 , C07C13/66 , C07C13/68 , C07C2/42
CPC分类号： C07C13/66 , C07C2/50 , C07C2603/86 , C07C13/68
摘要： A process by which tetracyclododecene for use as a material for cycloolefin (co)polymers having excellent optical properties, high transparency, heat resistance, and oil-absorbing properties can be continuously and stably produced over long even from inexpensive crude DCPD. In the process for the continuous production of a tetracyclododecene compound, a 2-norbornene compound is separated and recovered after reaction and reused as a starting material. Thus, the material is effectively utilized and the target compound can be efficiently synthesized. Further, at least part of a 2-methyl-2-norbornene compound which generates as a by-product and is apt to come into the 2-norbornene compound to be circulated is removed from the system. Thus, adverse influences of the accumulation of that by-product are diminished to enable the operation to be stably and continuously conducted over long.
摘要翻译：本发明涉及一种制备四环十二碳烯的方法，其可以是廉价的原油原料，其具有光学性能，高透明性，耐热性和吸油性等特性的环烯烃（共）聚合物的原料 DCPD在稳定，连续和长期的过程中。在本发明中所述的四环十二碳烯的连续制备中，可有效地利用反应后的2-降冰片烯的分离和回收的原料的有效利用来高效制备目标产物。基于抑制副产物如2-甲基-2-降冰片烯的积累产生的不良影响，可以保持稳定，连续和长期的操作，其易于蠕变进入循环的2-降冰片烯，通过在反应体系中至少一部分所述产物。

2. 发明公开

EP1151982A4 PROCESS FOR CONTINUOUSLY PRODUCING TETRACYCLODODECENE COMPOUND 有权
标题翻译： VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG VON TETRACYCLODODECEN
公开(公告)号：EP1151982A4
公开(公告)日：2004-12-15
申请号：EP00974908
申请日：2000-11-10
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： AIDA FUYUKI , SUZUKI TAKASHI , MATSUMURA YASUO
IPC分类号： C07C2/50 , C07C13/66 , C07C13/08 , C07C2/42
CPC分类号： C07C13/66 , C07C2/50 , C07C2603/86 , C07C13/68
摘要： A process by which high-purity tetracyclododecene for use as a material for cycloolefin (co)polymers having excellent optical properties, high transparency, heat resistance, and oil-absorbing properties can be continuously and stably produced over long even from inexpensive crude DCPD. In the process for the continuous production of a tetracyclododecene compound, it is possible to use crude DCPD, which is low-purity dicyclopentadiene, as a starting material. The feed materials to be introduced into a reactor are regulated so that the amount of any one, any two, or all of isoprene, piperylene, a 1-methyl-2-norbornene compound represented by the general formula (4) relative to the total amount of the cyclopentadiene and dicyclopentadiene is within a given range. The tetracyclododecene compound having a high purity can be stably produced over long.
摘要翻译：本发明涉及一种制备高纯度四环十二碳烯的方法，该四环十二碳烯可以是廉价原料的具有优异的光学性能，高透明性，耐热性和吸油性的环烯烃（共）聚合物的原料的原油DCPD在稳定，连续和长期的过程中。在本发明中描述的四环十二碳烯的连续制备中，可以使用粗二环戊二烯，即纯度低的二环戊二烯作为原料。还可以通过将通式（4）所示的异戊二烯，戊间二烯和1-甲基-2-降冰片烯中的一种，两种或三种化合物的比例相对于通式（4）所示的比例保持为高纯度的四环十二碳烯，二环戊二烯和环戊二烯在规定范围内，其中所有这些物质都包含在进料到反应器中的原料中。

3. 发明公开

EP1020420A4 1,4-METHANO-1,4,4a,9a-TETRAHYDROFLUORENE COMPOSITION AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译： 1,4-METHANO-1,4,4a，9a-TETRAHYDROFLUOREN-ZUBEREITUNG UND VERFAHREN ZU SEINER HERSTELLUNG
公开(公告)号：EP1020420A4
公开(公告)日：2001-11-07
申请号：EP99926960
申请日：1999-07-06
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： AIDA FUYUKI , SUZUKI TAKASHI , INOMATA YOSHIHISA , MATSUMURA YASUO
IPC分类号： C07C2/50 , C07C13/64 , C07C13/68
CPC分类号： C07C13/68 , C07C2/50 , C07C13/64 , C07C2603/86 , C07C2603/90
摘要： A process for producing a 1,4-methano-1,4,4a,9a-tetrahydrofluorene composition in which the contents of two cyclopentadiene trimers each having a specific structure are regulated to 100 to 5,000 ppm, which comprises reacting cyclopentadiene and/or dicyclopentadiene with 2 to 50 mol of indene per mol of the diene with heating and purifying the reaction product by distillation. By using the composition as a feed material for various polymerizations, gelation in polymerization is inhibited and resins having excellent optical properties can be obtained.
摘要翻译：一种生产1,4-亚甲基-1,4,4a，9a-四氢芴组合物的方法，其中将每种具有特定结构的两种环戊二烯三聚物的含量调节到100-5000ppm，该方法包括使环戊二烯和/或二环戊二烯每摩尔二烯加入2至50摩尔茚，加热并通过蒸馏纯化反应产物。通过将该组合物用作各种聚合的原料，可以抑制聚合中的凝胶化，可以得到光学特性优异的树脂。

4. 发明公开

EP1016682A4 TETRACYCLODODECENE COMPOSITIONS AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：四环组成和方法及其
公开(公告)号：EP1016682A4
公开(公告)日：2002-08-28
申请号：EP99926913
申请日：1999-07-02
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： HASHIZUME MASAKI , UCHIDA TOMONOBU , AIDA FUYUKI , SUZUKI TAKASHI , INOMATA YOSHIHISA , MATSUMURA YASUO
IPC分类号： C08G61/08 , C08F32/08 , C07C2/50 , C07C13/68
CPC分类号： C08G61/08
摘要： A tetracyclododecene composition having a regulated cyclopentadiene trimer content is used, whereby addition polymerization with the aid of a Ziegler catalyst can be conducted while preventing gelling caused by crosslinking. A tetracyclododecene composition regulated with respect to the content of a specific ingredient having a molecular weight of 188 is used, whereby polymers having high glass transition temperatures can be obtained through various polymerizations. In producing the tetracyclododecene, use of an aliphatic solvent having a boiling point close to that of norbornene is effective in inhibiting the recovered norbornene from solidifying. Preferred for obtaining high-purity tetracyclododecene by removing the methyltetrahydroindene contained in a dicyclopentadiene feedstock is a continuous process comprising a combination of reaction, distillation, recovery/circulation, etc.

5. 发明公开

EP1016683A4 2-ETHYL-1,4,5,8-DIMETHANO-1,2,3,4,4a,5,8,8a-OCTAHYDRONAPHTHALENE COMPOSITION FOR POLYMERIZATION AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：组成2-乙基-1,4,5,8-二亚甲基-1,2,3,4,4a，5,8,8a-八氢化萘聚合及其制备方法
公开(公告)号：EP1016683A4
公开(公告)日：2001-11-07
申请号：EP99926961
申请日：1999-07-06
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： AIDA FUYUKI , SUZUKI TAKASHI , INOMATA YOSHIHISA , MATSUMURA YASUO
IPC分类号： C07C2/50 , C07C13/68 , C08G61/08
CPC分类号： C08G61/08 , C07C2/50 , C07C13/68 , C07C2603/86
摘要： A process for producing a 2-ethyl-1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene composition in which the total content of two specific cyclopentadiene trimers is 100 to 5,000 ppm, which comprises reacting cyclopentadiene and/or dicyclopentadiene with 5-ethyl-2-norbornene under specific conditions. By using the composition as a feed material for various polymerizations, homogeneous and transparent polymers containing no gel can be obtained.

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