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1. 发明公开

EP1413199A1 An agricultural and horticultural disease controller and a method for controlling the diseases 失效
标题翻译：农药农业，园艺和控制害虫的方法
公开(公告)号：EP1413199A1
公开(公告)日：2004-04-28
申请号：EP04001677.6
申请日：1996-03-26
申请人： Nihon Nohyaku Co., Ltd.
发明人： Kuroda, Kiyoshi , Tajima, Sokichi , Uchikurohane, Toru , Tsubata, Kenji
IPC分类号： A01N43/828
CPC分类号： C07D285/135 , A01N43/82 , A01N43/84 , A01N47/44 , A01N55/00 , C07D231/12 , C07D233/56 , C07D249/08 , C07D285/06 , C07D417/06 , C07D417/12
摘要： A method for using a compound represented by the general formula:
(wherein R 1 and R 2 are the substituents, respectively, defined in the specification) for agricultural and horticultural disease control, and a composition used in said method.
摘要翻译：农业园艺病害防治剂包括1，2，3噻二唑DERIV。式（I）或其盐R 1 = H，烷基1-12C，1-12C卤代烷基，C 2-12炔基，卤代链烯基2-12C，2-12C炔基，卤代炔基2-12C，3-6C环烷基，苯基（的选择。substd。由卤素，NO2，CN，1-6C烷基，1-6C卤代烷基，1-6C烷氧基，卤代烷氧基1-6C，1-6C烷硫基，卤代烷硫基1-6C，2-6C烯基和/或2- 图6C炔基），R 2 = XR12例如，ON = CR19R20，NR 21 R 22等R19，R20 = H，卤素，NO2，CN，烷基1-12C，1-12C卤代烷基，3-6C环烷基，链烯基2-12C，2- 12C炔基，烷氧基 - 1-12C 1-12C的烷基，烷氧基羰基1-12C，苯基（优化由Q substd。），5-或6元杂环contg。 O，S和/或N（优化Substd。通过Q），或R19 + R20 = 3-6C环烷烃或5-或6-元杂环contg。 O，S和/或N; R21，R22 = H，烷基1-12C，1-12C卤代（优化Substd，通过OH或1-6C烷氧基），链烯基2-12C，2-12C炔基，烷氧基1-12C 1-6C烷基，1 12C烷硫基 - 1-6C烷基，氰基烷基1-12C（由选择。substd 1-6C。烷氧基，2-6C烯氧基，炔2-6C，1-6C烷硫基，烷氧基羰1-6C-1-6C烷氧基，烷氧基羰基1-6C 1-6C烷硫基，苯氧基，苯硫基，吡唑-1-基，氨基甲酰基（1-6C）烷基（优化substd。），羟基 - 烷基1-16C，二（1-6C）烷氧基 1-6C烷基，1-6C烷氧基羰基C 1-6烷基（优化substd。），苯基（优化substd。），苯基C 1-6烷基（优化substd。），萘基等或R21 + R22 = 。contg 4-6C亚烷基选择二氨基亚甲基O或;

2. 发明公开

EP1006102A2 Aniline derivative and process for producing the same 有权
标题翻译： Verfahren zur Herstellung von perfluoralkylierten Anilinderivaten
公开(公告)号：EP1006102A2
公开(公告)日：2000-06-07
申请号：EP99123023.6
申请日：1999-11-19
申请人： NIHON NOHYAKU CO., LTD.
发明人： Onishi, Masanobu , Yoshiura, Akihiko , Kohno, Eiji , Tsubata, Kenji
IPC分类号： C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07C323/41 , C07D209/08
CPC分类号： C07C323/41 , C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07D209/08
摘要： The present invention provides an aniline derivative represented by the formula (I)
wherein R 1 and R 2 are each H, (C 1-12 )alkyl, (C 3-8 )cycloalkyl, hydroxy(C 1-12 )alkyl, hydroxycarbonyl (C 1-12 )alkyl, (C 1-6 )alkoxycarbonyl(C 1-6 )alkyl, -COR 8 , wherein R 8 is H, halo(C 1-12 )alkyl, (C 3-8 )cycloalkyl or (substituted) phenyl, COOR 9 , wherein R 9 is a halo(C 1-6 )alkyl group, (substituted) phenyl or (substituted) benzyl; R 3 , R 4 , R 5 , R 6 and R 7 are each H, halogen, OH, nitro, halo(C 1-12 )alkylthio, (substituted) amino(C 1-2 )alkyl, (substituted) phenyl, (substituted) benzyl, amino, -N(R 10 )R 11 wherein R 10 and R 11 are each H, alkyl, cycloalkyl, (substituted) phenyl, (substituted) benzyl, -COR 8 or COOR 9 , or (C 2-27 )perfluoroalkyl, etc., and a process for producing the aniline derivative. According to the process of the present invention, perfluoroalkylaniline derivatives can be obtained by using various anilines as the substrate with a high position selectivity and high yield.
摘要翻译：本发明提供由式（I）表示的苯胺衍生物，其中R 1和R 2各自为H，（C 1-12）烷基，（C 3-8）环烷基，羟基（C 1-12））烷基，羟基羰基（C 1-12）烷基，（C 1-6）烷氧基羰基（C 1-6）烷基，-COR 8，其中R 8为H，卤代（C 1-12）烷基，）环烷基或（取代的）苯基，COOR 9，其中R 9是卤代（C 1-6）烷基，（取代的）苯基或（取代的）苄基; R 3，R 4，R 5，R 6和R 7各自为H，卤素，OH，硝基，卤代（C 1-12）烷硫基，（取代的）氨基（C 1-2 ）取代的苯基，（取代的）苄基，氨基，-N（R 10）R 11其中R 10和R 11各自为H，烷基，环烷基，（取代的）苯基，（取代的）苄基，-COR 8或COOR 9，或（C2-27）全氟烷基等，以及苯胺衍生物的制备方法。根据本发明的方法，可以通过以高位置选择性和高产率使用各种苯胺作为基材来获得全氟烷基苯胺衍生物。

3. 发明公开

EP0704430A1 N-substituted phenylcarbamic acid derivatives, a process for production thereof, agricultural and horticultural fungicides, intermediates of the derivatives and a process for production thereof 失效
标题翻译： N-取代的苯基氨基甲酸衍生物，它们的制备方法，杀真菌剂用于农业和园艺，的中间体和它们的制备方法
公开(公告)号：EP0704430A1
公开(公告)日：1996-04-03
申请号：EP95114900.4
申请日：1995-09-21
申请人： NIHON NOHYAKU CO., LTD.
发明人： Ohnishi, Masanobu , Tajima, Sohkichi , Nishiguchi, Tsutomu , Tsubata, Kenji
IPC分类号： C07C271/28 , C07D273/01 , C07C333/12 , A01N37/52 , A01N43/00 , A01N33/26
CPC分类号： C07D213/53 , A01N47/24 , C07C251/88 , C07C271/28 , C07C323/48 , C07D241/12 , C07D273/00 , C07D333/22
摘要： An N-substituted phenylcarbamic acid derivative represented by the general formula (I):

[wherein R¹ is H, a (C₁₋₆)alkyl group, a halo(C₁₋₆)alkyl group, a (C₁₋₆)alkoxy(C₁₋₆)alkyl group, a (C₂₋₆)alkenyl group, a (C₂₋₆)alkynyl group or a halo(C₁₋₆)alkoxy(C₁₋₆)alkyl group, R² is H, a (C₁₋₆)alkyl group, a halo(C₁₋₆)alkyl group, a (C₁₋₆)alkoxy(C₁₋₆)alkyl group, a (C₂₋₆)alkenyl group, a (C₂₋₆)alkynyl group, a halo(C₁₋₆)alkoxy(C₁₋₆)alkyl group or a cyano(C₁₋₆)alkyl group, R³ is a (C₁₋₆)alkyl group or a halo(C₁₋₆)alkyl group, each of R⁴ and R⁵ is a specific group, and Y is O or S] which is very effective in controlling powdery mildew, scab, late blight and gray mold; a process for producing said derivative; an agricultural and horticultural fungicide containing said derivative as an active ingredient; an intermediate of said derivative; and a process for producing the intermediate.
摘要翻译：由通式（I）表示的N- substituiertem苯基氨基甲酸衍生物： a其中[R <1>为H，（C 1-6）烷基，卤代（C 1-6）烷基，（C 1 -C 6）烷氧基（C 1-6）烷基，（C 2-6）链烯基，（C 2-6）炔基或卤代（C 1-6）烷氧基（C 1-6）烷基，R <2>是 H，一（C 1-6）烷基，卤代（C 1-6）烷基，（C 1-6）烷氧基（C 1-6）烷基，（C 2-6）链烯基，（C 2-6链）炔基，卤代（C 1-6）烷氧基（C 1-6）烷基或氰基（C 1-6）烷基，R <3>是一个（C 1-6）烷基或卤代（C 1-6 ）烷基，每个R <4>和R <5>是一个特定的基团，Y为O或SR的所有这是在控制白粉病，赤霉病，晚疫病和灰霉病非常有效; 用于产生所述衍生物的方法; 在农业和园艺杀菌剂含有所述作为活性成分的衍生物; 在中间所述衍生物的; 及其制造中间体的方法。

4. 发明授权

EP1006102B1 Process for the production of perfluoroalkylated aniline derivatives 有权
标题翻译：一种用于生产全氟烷基化的苯胺衍生物的方法
公开(公告)号：EP1006102B1
公开(公告)日：2006-08-30
申请号：EP99123023.6
申请日：1999-11-19
申请人： NIHON NOHYAKU CO., LTD.
发明人： Onishi, Masanobu , Yoshiura, Akihiko 357-5-103, Aza Oona , Kohno, Eiji , Tsubata, Kenji
IPC分类号： C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07C323/41 , C07D209/08
CPC分类号： C07C323/41 , C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07D209/08
摘要： The present invention provides an aniline derivative represented by the formula (I) wherein R and R are each H, (C1-12)alkyl, (C3-8)cycloalkyl, hydroxy (C1-12)alkyl , hydroxycarbonyl (C1-12)alkyl, (C1-6)-alkoxycarbonyl(C1-6)alkyl, -COR , wherein R is H, halo-(C1-12)alkyl, (C3-8)cycloalkyl or (substituted) phenyl, COOR , wherein R is a halo(C1-6)alkyl group, (substituted) phenyl or (substituted) benzyl; R , R , R , R and R are each H, halogen, OH, nitro, halo(C1-12)alkylthio, (substituted) amino-(C1-2)alkyl, (substituted) phenyl, (substituted) benzyl, amino, -N(R )R wherein R and R are each H, alkyl, cycloalkyl, (substituted) phenyl, (substituted) benzyl, -COR or COOR , or (C2-27)perfluoroalkyl, etc., and the use of aniline derivative represented by formula (I) as an intermediate in the preparation of agricultural and horticultural insecticides.

5. 发明公开

EP0987255A2 Substituted aminoquinazolinone (thione) derivatives 失效
标题翻译：取代基Aminochinazolinon（thion）Derivate
公开(公告)号：EP0987255A2
公开(公告)日：2000-03-22
申请号：EP99123596.1
申请日：1996-03-28
申请人： NIHON NOHYAKU CO., LTD.
发明人： Uehara, Masahiro , Shimizu, Toshiaki , Fujioka, Shinsuke , Kimura, Masayuki , Tsubata, Kenji
IPC分类号： C07D239/80 , C07D401/12 , C07D405/06 , C07D405/12 , C07D417/12 , A01N43/54
CPC分类号： C07D401/12 , A01N43/54 , A01N43/78 , A01N47/16 , C07D239/80 , C07D405/06 , C07D405/12 , C07D417/12 , C07D491/04
摘要： The present invention is directed to a compound of general formula (II)
(wherein X, n and Y are as defined in the specification), processes for the production of the compound of general formula (II) and the use of the compound of general formula (II) for the preparation of compounds of general formula (I)
(wherein R, R 1 , X, Y and n are as defined in the specification).
摘要翻译：本发明涉及通式（II）的化合物（其中X，n和Y如说明书中所定义），通式（II）化合物的制备方法和用于制备通式（I）化合物的通式（II）化合物（其中R，R 1，X，Y和n如说明书中所定义）。

6. 发明公开

EP0414153A1 N-(substituted benzyloxy)imine derivatives, process for the production thereof, use thereof, and method of use thereof 失效
标题翻译： N-取代苯甲氧基羰基化合物，Verfahren zu deren Herstellung und deren Verwendung。
公开(公告)号：EP0414153A1
公开(公告)日：1991-02-27
申请号：EP90115822.0
申请日：1990-08-17
申请人： NIHON NOHYAKU CO., LTD.
发明人： Tsubata, Kenji , Niino, Nobuyuki , Endo, Katsutoshi , Yamamoto, Yoshinobu , Kanno, Hideo
IPC分类号： C07C251/60 , C07C323/47 , A01N33/24
CPC分类号： C07D207/335 , A01N37/36 , A01N37/38 , A01N37/40 , A01N37/50 , A01N37/52 , A01N41/06 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/14 , A01N43/28 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/56 , A01N43/60 , A01N43/653 , A01N43/84 , A01N43/90 , A01N47/22 , A01N47/42 , A01N57/22 , C07C251/60 , C07C255/54 , C07C255/64 , C07C311/08 , C07C317/28 , C07C323/47 , C07C323/52 , C07C323/57 , C07C323/60 , C07C327/22 , C07C2601/02 , C07C2601/10 , C07C2601/14 , C07C2602/08 , C07D209/14 , C07D213/53 , C07D213/74 , C07D215/06 , C07D231/12 , C07D231/16 , C07D231/48 , C07D233/56 , C07D239/26 , C07D239/34 , C07D239/42 , C07D241/12 , C07D249/08 , C07D265/36 , C07D295/125 , C07D295/13 , C07D295/192 , C07D307/30 , C07D307/38 , C07D307/52 , C07D309/28 , C07D311/68 , C07D317/58 , C07D333/22 , C07D335/02 , C07D335/06 , C07D339/06 , C07D339/08 , C07D491/10 , C07F9/4006
摘要： Compound of the general formula (I), which is useful as an agricultural and horticultural fungicide, an agricultural and horticultural fungicidal composition containing said compound, use of said composition for controlling plant disease, and process for the production of said compound:

shows a case in which R 3 and R 4 together form a cyclic substituent, and R 1 to R 4 are substituents disclosed in
the specification.
摘要翻译：可用作农业和园艺杀真菌剂的通式（I）的化合物，含有所述化合物的农业和园艺杀真菌组合物，所述组合物用于控制植物病害的用途，以及所述化合物的制备方法：表示R 3和R 4一起形成环状取代基，R 1至R 4为说明书中公开的取代基的情况。

7. 发明公开

EP1688041A1 An agricultural and horticultural disease controller and a method for controlling the diseases 失效
标题翻译：农药农业，园艺和控制害虫的方法
公开(公告)号：EP1688041A1
公开(公告)日：2006-08-09
申请号：EP06008951.3
申请日：1996-03-26
申请人： NIHON NOHYAKU CO., LTD.
发明人： Kuroda, Kiyoshi , Tajima, Sokichi , Uchikurohane, Toru , Tsubata, Kenji
IPC分类号： A01N43/828
CPC分类号： C07D285/135 , A01N43/82 , A01N43/84 , A01N47/44 , A01N55/00 , C07D231/12 , C07D233/56 , C07D249/08 , C07D285/06 , C07D417/06 , C07D417/12
摘要： A method for using a compound represented by the general formula:

(wherein R 1 and R 2 are the substituents, respectively, defined in the specification) for agricultural and horticultural disease control, and a composition used in said method.
摘要翻译：一种用于使用由所述通式表示的化合物的方法：（worin R 1和R 2是取代基，分别在说明书中定义），用于农业和园艺病害控制，并且在所述方法中使用的组合物。

8. 发明授权

EP0987255B1 Substituted aminoquinazolinone (thione) derivatives 失效
标题翻译：取代氨基喹唑啉酮（硫酮）衍生物
公开(公告)号：EP0987255B1
公开(公告)日：2003-07-16
申请号：EP99123596.1
申请日：1996-03-28
申请人： NIHON NOHYAKU CO., LTD.
发明人： Uehara, Masahiro , Shimizu, Toshiaki , Fujioka, Shinsuke , Kimura, Masayuki , Tsubata, Kenji
IPC分类号： C07D239/80 , C07D401/12 , C07D405/06 , C07D405/12 , C07D417/12 , A01N43/54
CPC分类号： C07D401/12 , A01N43/54 , A01N43/78 , A01N47/16 , C07D239/80 , C07D405/06 , C07D405/12 , C07D417/12 , C07D491/04

9. 发明公开

EP0735035A1 Substituted aminoquinazolinone (thione) derivatives or salts thereof, intermediates thereof, and pest controllers and a method for using the same 失效
标题翻译：取代氨基喹唑啉酮（硫酮）衍生物及其盐，它们的中间体和它们的用途是指Pestkontrollemittel和
公开(公告)号：EP0735035A1
公开(公告)日：1996-10-02
申请号：EP96104992.1
申请日：1996-03-28
申请人： NIHON NOHYAKU CO., LTD.
发明人： Uehara, Masahiro , Shimizu, Toshiaki , Fujioka, Shinsuke , Kimura, Masayuki , Tsubata, Kenji
IPC分类号： C07D401/12 , C07D405/12 , C07D239/80 , A01N43/54
CPC分类号： C07D401/12 , A01N43/54 , A01N43/78 , A01N47/16 , C07D239/80 , C07D405/06 , C07D405/12 , C07D417/12 , C07D491/04
摘要： There are disclosed a compound represented by the general formula (I):
(wherein R, R 1 , X, Y and n are as defined in the specification), a pest controller containing said compound as an active ingredient, a pest control method using said controller, and an intermediate for producing the compound of the above general formula (I).
摘要翻译：有圆盘游离缺失由通式（I）表示的化合物：（worin R，R <1>，X，Y和n如说明书中所定义），害虫控制器含有所述化合物作为活性成分的，使用所述控制器，并在中间生产上述通式（I）的化合物中的害虫防治方法。

10. 发明公开

EP1380568A2 Perfluoroalkylaniline derivatives 审中-公开
标题翻译：全氟烷基苯胺衍生物
公开(公告)号：EP1380568A2
公开(公告)日：2004-01-14
申请号：EP03023120.3
申请日：1999-11-19
申请人： NIHON NOHYAKU CO., LTD.
发明人： Onishi, Masanobu , Yoshiura, Akihiko , Kohno, Eiji , Tsubata, Kenji
IPC分类号： C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07C323/41 , C07D209/08
CPC分类号： C07C323/41 , C07C209/68 , C07C211/52 , C07C213/08 , C07C215/76 , C07C217/84 , C07C233/15 , C07C271/14 , C07C323/36 , C07D209/08
摘要： The present invention provides an aniline derivative represented by the formula (I)
wherein R 1 and R 2 are each H, (C 1-12 )alkyl, (C 3-8 )cycloalkyl, hydroxy (C 1-12 )alkyl , hydroxycarbonyl (C 1-12 )alkyl, (C 1-6 )-alkoxycarbonyl(C 1-6 )alkyl, -COR 8 , wherein R 8 is H, halo-(C 1-12 )alkyl, (C 3-8 )cycloalkyl or (substituted) phenyl, COOR 9 , wherein R 9 is a halo(C 1-6 )alkyl group, (substituted) phenyl or (substituted) benzyl; R 3 , R 4 , R 5 , R 6 and R 7 are eachH, halogen, OH, nitro, halo(C 1-12 )alkylthio, (substituted) amino-(C 1-2 )alkyl, (substituted) phenyl, (substituted) benzyl, amino, -N(R 10 )R 11 wherein R 10 and R 11 are each H, alkyl, cycloalkyl, (substituted) phenyl, (substituted) benzyl, -COR 8 or COOR 9 , or (C 2-27 )perfluoroalkyl, etc., and a process for producing the aniline derivative. According to the process of the present invention, perfluoroalkylaniline derivatives can be obtained by using various anilines as the substrate with a high position selectivity and high yield.
摘要翻译：（I）表示的苯胺衍生物，其中R1和R2各自为H，（C1-12）烷基，（C3-8）环烷基，羟基（C1-12）烷基，羟基羰基（C1-12）（C 1-6） - 烷氧基羰基（C 1-6）烷基，-COR 8，其中R 8是H，卤代 - （C 1-12）烷基，（C 3-8）环烷基或（取代）苯基，COOR 9，卤代（C 1-6）烷基，（取代的）苯基或（取代的）苄基; （取代）氨基 - （C1-2）烷基，（取代）苯基，（取代）苄基，氨基，（取代）氨基，其中R10和R11各自为H，烷基，环烷基，（取代）苯基，（取代的）苄基，-COR8或COOR9或（C2-27）全氟烷基等的-N（R10）R11等。苯胺衍生物。根据本发明的方法，全氟烷基苯胺衍生物可以通过使用各种苯胺作为具有高位置选择性和高收率的底物而获得。

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