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1. 发明公开

EP0715609A1 ISOPARAFFIN-OLEFIN ALKYLATION 失效转让
标题翻译：异链烷烃，烯烃烷基化
公开(公告)号：EP0715609A1
公开(公告)日：1996-06-12
申请号：EP94924474.0
申请日：1994-07-19
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , MELLI, Tomas, Rodolfo
IPC分类号： C01B7 , C07B61 , C07C2 , C07C7 , C07C9 , C07D333 , C10G35 , C10L1
CPC分类号： C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206 , C07D333/48 , Y02P20/584
摘要： An isoparaffin-olefin alkylation process comprising (a) alkylating an isoparaffin-olefin feed stream (10) in the presence of an alkylation acid catalyst (12) containing HF and sulfolane in a riser reactor (20) where acid soluble oligomers (ASO) are formed; (b) separating the alkylator effluent (22) in a gravitational separator (30) to obtain a less dense stream (38) containing the alkylate and unreacted isoparaffin, and a more dense stream (32) containing HF, sulfolane and ASO; (c) recycling most of the more dense stream to the riser reactor (20) as recycled acid catalyst (36) along with make-up HF catalyst (14); (d) stripping the rest (34) of the more dense stream in a catalyst stripper (50) with a stripping isoparaffin fluid (57) to obtain an overhead stream (56) which flows to the product fractionator (90); (e) gravitationally separating the stripper bottom stream (54) in a separator (70) to obtain a less dense phase (76) enriched in ASO, a more dense stream (77) enriched in sulfolane and a bottoms stream (78) containing solids; (f) fractionating streams (38) and (56) in a product fractionator (90) to obtain an overhead stream (92) enriched in isoparaffin and HF, which condenses in overhead cooler (94) and separates into a hydrocarbon phase and an acid phase in the overhead accumulator (120); (g) recycling part (123) of the hydrocarbon phase in overhead accumulator as a reflux to the fractionator (90) and the rest (125) as isoparaffin recycle to the riser reactor (20); (h) recycling the acid phase (124) in the overhead accumulator as a catalyst to the riser reactor (20); and (i) obtaining the alkylate product (56) and an n-butane by-product (98) from the fractionator (90).

2. 发明公开

EP0632795A1 AN ISOPARAFFIN-OLEFIN ALKYLATION CATALYST COMPRISING HF, SULFONE AND WATER 失效转让
标题翻译：用于烷基化的异构烷烃与烯烃WHICH HF，砜和水中含有的催化剂。
公开(公告)号：EP0632795A1
公开(公告)日：1995-01-11
申请号：EP93906203.0
申请日：1993-02-23
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , DEL ROSSI, Kenneth, Joseph
IPC分类号： B01J31 , C07B61 , C07C2 , C07C9 , C10G35
CPC分类号： C07C2/62 , C07C2527/1206
摘要： The present invention provides a process for alkylation of an isoparaffin with an olefin in the presence of acid catalyst composition comprising from 50 to 80 weight percent hydrofluoric acid, from 20 to 50 weight percent sulfolane, and from 0.5 to 10 weight percent water. The addition of the water decreases the corrosivity of the mixture of hydrofluoric acid and sulfolane.

3. 发明授权

EP0404931B1 CONVERSION OF OLEFINS TO ETHERS 失效
标题翻译：烯烃转化为其他物质
公开(公告)号：EP0404931B1
公开(公告)日：1993-09-01
申请号：EP90902492.9
申请日：1990-01-10
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , CHOI, Byung, Chan , RAGONESE, Francis, Paul
IPC分类号： C07C43/04 , C07C41/06 , C07C41/09
CPC分类号： C07C41/42 , C07C41/06 , C07C41/09 , Y02P20/127 , C07C43/04
摘要： Light olefins are catalytically converted to ethers, e.g., propylene is converted to diisopropyl ether, in a two stage process in which product ether is recycled to a first stage reaction zone to significantly reduce the operating temperature of the olefin hydration/etherification reactions taking place in that zone. Alcohol produced in the first stage reaction zone undergoes conversion in the second stage reaction zone, e.g., by catalytic distillation, to provide additional product ether.

4. 发明公开

EP0715610A1 ISOPARAFFIN-OLEFIN ALKYLATION 失效转让
标题翻译：异链烷烃 - 烯烃烷基化
公开(公告)号：EP0715610A1
公开(公告)日：1996-06-12
申请号：EP94924543.0
申请日：1994-08-01
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , MELLI, Tomas, Rodolfo , YURCHAK, Sergei
IPC分类号： B01J31 , C07B61 , C07C2 , C07C7 , C07C9 , C10G35 , C10L1
CPC分类号： C07C2/62 , C07C2527/1206
摘要： An isoparafin-olefin alkylation process comprising the sequential steps of (a) alkylating a mixed isoparaffin-olefin feed (10) in the presence of an alkylation catalyst (12) comprising HF and sulfolane in a riser reactor (20), whereby acid soluble oligomers (ASO) are formed; (b) gravitationally separating the effluent (22) in separator (30) into a less dense stream (38) containing the alkylate and unreacted isoparaffin and a more dense stream (32) containing sulfolane, ASO and HF, part (36) of which is recycled into the riser reactor (20) as the acid catalyst; (c) stripping HF from the rest (34) of the more dense stream (32) in a multi-step stipping column (50) with a stripping isoparaffin fluid (52) to obtain a stripped bottom stream (54) containing less than 30 % HF and an overhead stream (58) containing HF, isoparaffin, and a fraction of low-boiling ASO; (d) gravitationally separating the stripped bottom (54) in a separator (70) into a more dense sulfolane-enriched stream (78) and a less dense ASO-enriched stream (76); (e) charging the stripper overhead stream (56) into an alkylate fractionator (90) to obtain an overhead stream (92) containing isoparaffin and HF; (f) condensing the overhead stream (92) in overhead accumulator (100), a part (103) of which is recycled as reflux to the fractionator (90) and the rest (105) is recycled as isoparaffin stream to the riser reactor (20); (g) recycling the acid phase (104) condensate in overhead accumulator (100) back to the riser reactor (20) as catalyst; (h) and recovering an alkylate product (96) and an n-butane product (98).
摘要翻译：（a）在包含HF和环丁砜的烷基化催化剂（12）存在下，在提升管反应器（20）中将混合的异链烷烃 - 烯烃原料（10）烷基化，由此得到酸可溶低聚物（ASO）; （b）将分离器（30）中的流出物（22）重力分离成含有烷基化物和未反应的异链烷烃的低密度流（38）和含有环丁砜，ASO和HF的更密集流（32），其中部分（36）作为酸催化剂再循环到提升管反应器（20）中; （c）用汽提异链烷烃流体（52）在多步骤提升塔（50）中从更密集流（32）的剩余物（34）中汽提HF以获得含有少于30 ％的HF和含有HF，异链烷烃和一部分低沸点ASO的顶部料流（58）（d）将分离器（70）中的汽提底部（54）重力分离成更稠密的富含环丁砜的物流（78）和不太致密的富含ASO的物流（76）; （e）将汽提塔顶部物流（56）装入烷基化分馏塔（90）以获得含有异链烷烃和HF的顶部物流（92）; （f）将塔顶馏出物流（92）冷凝在顶部储存器（100）中，塔顶馏出物（103）的一部分（103）作为回流物循环至分馏塔（90），剩余物（105）作为异链烷烃物流循环至提升管反应器 20）; （g）将在塔顶收集器（100）中的酸相（104）冷凝物作为催化剂再循环回提升管反应器（20）; （h）并回收烷基化产物（96）和正丁烷产物（98）。

5. 发明公开

EP0464156A1 ISOPARAFFIN-OLEFIN ALKYLATION PROCESS 无效
标题翻译：异链烷烃 - 烯烃烷基化过程
公开(公告)号：EP0464156A1
公开(公告)日：1992-01-08
申请号：EP90907977.0
申请日：1990-04-09
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , HAN, Scott , HUSS, Albin, Jr. , KENNEDY, Clinton, Robert , KEVILLE, Kathleen, Marie , KIRKER, Garry, Wayne , MARLER, David, Owen , TABAK, Samuel, Allen , THOMSON, Robert, Thomas
IPC分类号： C07C2 , B01J29 , C07B61 , C07C9 , C10G35
CPC分类号： C07C2/58 , C07C2/60 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/12 , C07C2527/1213 , C07C2529/06
摘要： L'alkylation d'une isoparaffine avec une oléfine, afin d'obtenir un alkylat, s'effectue en présence d'une zéolite, en tant que catalyseur, dont les caractéristiques de diffraction des rayons X sont indiquées dans le tableau.
摘要翻译：异构烷烃与烯烃的烷基化以获得烷基化物是在作为催化剂的沸石存在下进行的，其X射线衍射特征在表中示出。

6. 发明授权

EP0464156B1 ISOPARAFFIN-OLEFIN ALKYLATION PROCESS 无效
标题翻译：异链烷烃 - 烯烃烷基化过程
公开(公告)号：EP0464156B1
公开(公告)日：1996-05-29
申请号：EP90907977.4
申请日：1990-04-09
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , HAN, Scott , HUSS, Albin, Jr. , KENNEDY, Clinton, Robert , KEVILLE, Kathleen, Marie , KIRKER, Garry, Wayne , MARLER, David, Owen , TABAK, Samuel, Allen , THOMSON, Robert, Thomas
IPC分类号： C07C2/58
CPC分类号： C07C2/58 , C07C2/60 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/12 , C07C2527/1213 , C07C2529/06
摘要： The alkylation of an isoparaffin with an olefin to provide alkylate is carried out in the presence of, as catalyst, a zeolite having the above X-ray diffraction lines.
摘要翻译：异链烷烃与烯烃的烷基化以提供烷基化作用是在作为催化剂的具有上述X射线衍射线的沸石存在下进行的。

7. 发明公开

EP0404931A1 CONVERSION OF OLEFINS TO ETHERS 失效
标题翻译：转换乙醚烯烃。
公开(公告)号：EP0404931A1
公开(公告)日：1991-01-02
申请号：EP90902492.0
申请日：1990-01-10
申请人： MOBIL OIL CORPORATION
发明人： CHILD, Jonathan, Edward , CHOI, Byung, Chan , RAGONESE, Francis, Paul
IPC分类号： B01J29 , C07B61 , C07C41 , C07C43
CPC分类号： C07C41/42 , C07C41/06 , C07C41/09 , Y02P20/127 , C07C43/04
摘要： On procède à la conversion par voie catalytique d'oléfines légères en éthers, par exemple de propylène en éther di-isopropyle, par un procédé à deux phases, dans lequel l'éther produit est recyclé dans une zone de réaction de première phase, pour obtenir une réduction sensible de la température opérationnelle des réactions d'hydratation/éthérification des oléfines qui se produisent dans cette zone. L'alcool produit dans la zone de réaction de première phase subit une conversion dans la zone de réaction de seconde phase, par exemple par distillation catalytique, pour former un éther supplémentaire.

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