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    • 5. 发明公开
    • NEGATIVE ELECTRODE ACTIVE MATERIAL AND SECONDARY BATTERY INCLUDING SAME
    • 负极活性物质和包含该物质的二次电池
    • EP3322005A1
    • 2018-05-16
    • EP16855803.9
    • 2016-10-17
    • LG Chem, Ltd.
    • CHOI, Jung HyunLEE, Yong JuKIM, Eun KyungKIM, Hyun Chul
    • H01M4/36H01M4/587H01M4/38H01M2/10H01M10/052H01M4/133H01M4/134H01M4/1393H01M4/1395H01M10/0525H01M4/62
    • H01M4/587H01M4/133H01M4/134H01M4/1393H01M4/1395H01M4/364H01M4/366H01M4/386H01M4/622H01M4/625H01M10/052H01M2220/20Y02E60/122
    • The present invention relates to a negative electrode active material and a secondary battery including the same, and specifically, provides a negative electrode active material particle including a core, which includes a carbon-based active material and an oxygen functional group, and a shell, which surrounds the core and includes a silicon-based active material. The negative electrode active material particles according to the present invention include an oxygen functional group such that a silicon-based active material may adhere to the surface of a carbon-based active material. The oxygen function group, being negatively charged due to the highly electronegative oxygen, pulls in the positively charged silicon atoms of the silicon-based active material via electrostatic attraction, and thus the silicon-based active material may be strongly adhered with the carbon-based active material. Moreover, since oxygen functional groups are bonded to 2.0 to 4.0% of the total number of covalently bondable sites on the outermost carbon atoms on the surface of the carbon-based active material, it is possible for the conductive properties of the negative electrode active material particle to not be degraded by the oxygen functional groups.
    • 本发明涉及负极活性物质及具备该负极活性物质的二次电池,具体而言,提供一种负极活性物质粒子,该负极活性物质粒子含有包含碳系活性物质和氧官能团的核以及壳, 其围绕核心并包括硅基活性材料。 根据本发明的负极活性物质颗粒包含氧官能团,使得硅基活性物质可以粘附到碳基活性物质的表面。 由于高电负性的氧而带负电荷的氧官能团通过静电引力吸引硅基活性材料的带正电的硅原子,因此硅基活性材料可强烈地与基于碳的活性材料粘附 活性物质。 另外,由于氧官能团与碳系活性物质表面的最外层的碳原子上的共价键合点的总数的2.0〜4.0%键合,所以能够使负极活性物质 颗粒不被氧官能团降解。