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    • 10. 发明授权
    • VERFAHREN ZUR HERSTELLUNG CELLULOSISCHER FORMKÖRPER
    • VERFAHREN ZUR HERSTELLUNG CELLULOSISCHERFORMKÖRPER
    • EP0695324B1
    • 1997-10-29
    • EP95906834.7
    • 1995-02-01
    • LENZING AKTIENGESELLSCHAFT
    • KALT, WolframFIRGO, HeinrichMÄNNER, JohannMÜLLEDER, EduardMANGENG, BrunoNIGSCH, ArnoldSCHWENNINGER, FranzSCHREMPF, Christoph
    • C08L1/02D01F2/00C08J3/09
    • C07C291/04C08B1/003C08J3/096C08J2301/00C08L1/02D01F2/00
    • The invention relates to a process for producing cellulose shaped bodies, said process comprising the following steps: (A) dissolving cellulose in an aqueous solution of a tertiary amino oxide, in particular N-methylmorpholine-N-oxide (NMMO), to form a cellulose solution which can be shaped; (B) shaping the cellulose solution and guiding the shaped cellulose solution into an aqueous precipitation bath in which the cellulose is precipitated, whereby a shaped body and a used precipitation bath are formed; (C) regenerating the used precipitation bath, a regenerated, aqueous amino oxide solution being formed which is used in step (A) again for dissolving cellulose. The invention is characterized in that in step (A) a regenerated, aqueous amino oxide solution is used which has a pH in a range whose upper and lower limits are defined, as a function of the tertiary amino oxide concentration, by the equation pH = - 0.0015 x A2 + 0.2816 x A + f, A being the tertiary amino oxide concentration in the aqueous solution, expressed in weight % of the aqueous solution, and satisfying the condition: 40 % ≤ A ≤ 86 %, and preferably ≤ 70 % A ≤ 80 %, and f having the value 1.00 for the upper limit and -1.80, and preferably -1.00, for the lower limit.
    • (A)将纤维素溶解在叔氨基氧化物,特别是N-甲基吗啉-N-氧化物(NMMO)的水溶液中以形成 可成形的纤维素溶液; (B)使纤维素溶液成形并引导成形的纤维素溶液进入沉淀纤维素的水沉淀浴中,由此形成成形体和使用的沉淀浴; (C)再生使用的沉淀浴,再次形成再生的氨基氧化物水溶液,其在步骤(A)中再次用于溶解纤维素。 本发明的特征在于,在步骤(A)中使用再生的氨基氧化物水溶液,其具有根据叔氨基氧化物浓度定义其上限和下限的pH值,通过方程式pH = -0.0015×A2 + 0.2816×A + f,A是水溶液中叔氨基氧化物浓度,以水溶液的重量%表示,并满足条件:40%≤A≤86%,优选≤70% A≤80%,f的上限值为1.00,下限值为-1.00,最好为-1.00。