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1. 发明公开

EP0765895A3 Metal coating resin and coated metal member 失效
标题翻译： Harzmasse zum Beschichten eines Metallgegenstandes und beschichteter Metallgegenstand
公开(公告)号：EP0765895A3
公开(公告)日：1998-11-11
申请号：EP96306817
申请日：1996-09-19
申请人： KUREHA CHEMICAL IND CO LTD
发明人： NISHIHATA NAOMITSU , OUCHI KIYOMI , TADA MASAHITO , SATAKE YOSHIKATSU
IPC分类号： C08G75/02 , H01B3/30
CPC分类号： C08G75/0254 , C08G75/0231 , H01B3/30
摘要： Disclosed herein are a metal coating resin comprising a branched poly(arylene sulfide) resin obtained by polymerizing an alkali metal sulfide and a dihalo-aromatic compound in the presence of a trihalo-aromatic compound, wherein the poly(arylene sulfide) resin has a melt viscosity η
200 of 50-3,000 Pa·s as measured at 310°C and a shear rate of 200/sec, and a ratio R (η
200 /η
1200 ) of the melt viscosity η
200 to a melt viscosity η
1200 as measured at 310°C and a shear rate of 1200/sec satisfies the following relationship (1):

0.91 x log(η
200 ) - 0.3 ≤ R ≤ 0.91 x log(η
200 ) + 0.3
a coated metal member obtained by coating a metal base with the resin, and a production process thereof. A coated metal member obtained by coating a metal base with a poly(arylene sulfide) resin, wherein the poly(arylene sulfide) resin has an elongational viscosity of at least 10,000 Pa·s as measured at 310°C and a shear rate of 400/sec, and a crystallization temperature upon heating of a coating layer formed of the poly(arylene sulfide) resin, which is measured by means of a differential scanning calorimeter, is lower by at least 6°C than that of an unorientated noncrystalline sheet of the poly(arylene sulfide) resin, and a production process thereof are also disclosed.
摘要翻译：本文公开了包含通过在三卤代芳族化合物的存在下使碱金属硫化物和二卤代芳族化合物聚合而获得的支化聚（亚芳基硫醚）树脂的金属涂层树脂，其中聚（亚芳基硫醚）树脂具有熔体粘度等于200，在310℃和200 /秒的剪切速率下测量的50-3,000Pa.s的熔体粘度eta 200与熔体粘度等于1200的比例R（eta 200 / eta 1200）在310℃和1200 /秒的剪切速率下满足以下关系式（1）：＆lt; MATH＆gt;通过用树脂涂覆金属基底而获得的涂覆金属构件及其制造方法。通过用聚（亚芳基硫醚）树脂涂覆金属基底而获得的涂覆金属构件，其中聚（亚芳基硫醚）树脂在310℃下测得的伸长粘度至少为10,000Pa.s，剪切速率为400 /秒，通过差示扫描量热计测定的由聚（亚芳基硫醚）树脂形成的涂层的加热结晶温度比未取向的非结晶性片材的结晶温度低至少6℃ 聚（亚芳基硫醚）树脂及其制备方法也被公开。

2. 发明公开

EP1288272A4 HEAT-EXPANDABLE MACROSPHERE AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：加热拉伸MAKROSPHERE和方法生产同样
公开(公告)号：EP1288272A4
公开(公告)日：2004-06-23
申请号：EP01917780
申请日：2001-04-02
申请人： KUREHA CHEMICAL IND CO LTD
发明人： SATAKE YOSHIKATSU , ASAI GENZO
IPC分类号： B01J13/14 , C08F2/18 , C08F2/44 , C08J9/16 , C08J9/20
CPC分类号： C08J9/20 , B01J13/14 , C08J9/16 , C08J2327/08 , C08J2333/00 , Y10T428/2987 , Y10T428/2991
摘要： Heat-expandable macrospheres which each has a shell made of a polymer obtained by polymerizing a polymerizable monomer with a crosslinkable monomer, the amount of the latter being 1 to 5 wt.%, excluding 1 wt.%, based on the polymerizable monomer, and which have a maximum expansion ratio of 5 or higher; and a process for producing heat-expandable macrospheres having a maximum expansion ratio of 5 or higher, which comprises suspension-polymerizing a polymerizable mixture comprising a polymerizable monomer and a crosslinkable monomer, the amount of the latter being 1 to 5 wt.%, excluding 1 wt.%, based on the polymerizable monomer.

3. 发明公开

EP1054034A4 EXPANDABLE MICROSPHERES AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译： EXPANDIERBAREMIKROKÜGELNUND HERSTELLUNDSVERFAHRENDAFÜR
公开(公告)号：EP1054034A4
公开(公告)日：2001-03-21
申请号：EP99901141
申请日：1999-01-22
申请人： KUREHA CHEMICAL IND CO LTD
发明人： EJIRI TETSUO , ASAI GENZO , SATAKE YOSHIKATSU
IPC分类号： B01J13/14 , B01J13/02
CPC分类号： B01J13/14
摘要： Expandable microspheres which each comprises a polymer shell and a foaming agent encapsulated therein, characterized by having an average particle diameter of 3 to 100 mu m and a coefficient of variation in particle diameter distribution of 1.50 % or lower; and a process for producing the expandable microspheres through suspension polymerization.
摘要翻译：各自包含聚合物壳和包封在其中的发泡剂的可膨胀微球体，其特征在于平均粒径为3至100μm，粒径分布变异系数为1.50％或更低; 以及通过悬浮聚合生产可膨胀微球体的方法。

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