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1. 发明公开

EP0007748A1 Composition containing atactic polypropylene and a filler treated with an organo-titanate chelate 失效
标题翻译：含有混合物和与有机钛酸酯螯合物填料处理无规立构聚丙烯。
公开(公告)号：EP0007748A1
公开(公告)日：1980-02-06
申请号：EP79301373.1
申请日：1979-07-12
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Monte, Salvatore J. , Sugerman, Gerald
IPC分类号： C08L23/12 , C08K9/00
CPC分类号： C08K9/04 , C08L23/12
摘要： Atactic polypropylene is upgraded to form composites which are workable by conventional thermoplastic shaping techniques by admixing the amorphous polypropylene with a filler which has been treated with an organo titanate cheiate. Preferred fillers are the reinforcing fillers such as the silicates and silica. The organo titanate chelates are alphs, omega-alkylene titanates having two non-hydrolyzable groups.

2. 发明授权

EP0164227B1 Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents 失效
标题翻译：有机金属有机钛酸酯和有机 - 锆石作为偶联剂和聚合物加工剂有用
公开(公告)号：EP0164227B1
公开(公告)日：1990-08-16
申请号：EP85303352.0
申请日：1985-05-13
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Sugerman, Gerald , Monte, Salvatore J.
IPC分类号： C07F7/00 , C07F9/09 , C08F8/42 , C08G85/00 , C08K5/06 , C08K5/52 , C08K5/17 , C08K5/41 , C08K5/09 , C08K5/05 , C08K9/04
CPC分类号： C08K5/0091 , C07F7/006 , C07F9/09 , C07F9/098 , C08F8/42

3. 发明公开

EP0007761A1 Cumylphenol derivatives and their use in synthetic resin compositions 失效
标题翻译： Cumylphenolderivate and ihre Verwendung in synthetischen Harz-Zusammensetzungen。
公开(公告)号：EP0007761A1
公开(公告)日：1980-02-06
申请号：EP79301403.6
申请日：1979-07-16
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Monte, Salvatore J. , Sugerman, Gerald
IPC分类号： C07C43/205 , C07C43/215 , C07C69/353 , C07C69/527 , C08K5/04 , C08K5/55
CPC分类号： C08K5/55 , C08K5/105
摘要： New cumylphenol derivatives are described which are useful as reactive diluents. plasticizers and impact modifiers for polymeric materials. The derivatives include alkenyl esters of monocarboxylic acids, esters of polycarboxylic acids, and the esters of boric acid, and alkenyl and aralkyl esters. The borate ester of cumylphenol is particularly useful as impact modifiers with flame retardant properties.
摘要翻译：描述了新的枯烯酚衍生物，其可用作聚合物材料的反应性稀释剂，增塑剂和抗冲改性剂。衍生物包括一元羧酸的烯基酯，多元羧酸的酯和硼酸的酯，以及链烯基和芳烷基酯。异丙苯酚的硼酸酯特别可用作具有阻燃性能的抗冲改性剂。

4. 发明公开

EP0164227A3 Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents 失效
标题翻译：用作联接和聚合物加工剂的有机有机钛酸酯和有机 - 锆石有用
公开(公告)号：EP0164227A3
公开(公告)日：1987-09-02
申请号：EP85303352
申请日：1985-05-13
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Sugerman, Gerald , Monte, Salvatore J.
IPC分类号： C07F07/00 , C07F09/09 , C08F08/42 , C08G85/00 , C08K05/06 , C08K05/52 , C08K05/17 , C08K05/41 , C08K05/09 , C08K05/05 , C08K09/04
CPC分类号： C08K5/0091 , C07F7/006 , C07F9/09 , C07F9/098 , C08F8/42
摘要： A neoalkoxy compound having the following formula:
wherein M is titanium or zirconium, R, R 1 and R 2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to twenty carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R 2 may also be an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a + b + c = 3. The compound is useful as a coupling and polymer processing agent and compositions containing the compound and methods of preparing polymeric material including the compound are also described.

5. 发明公开

EP0164227A2 Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents 失效
标题翻译：新型烷氧基有机钛酸酯和有机硅氧烷（Nützlichals Kuppler und Polymerbehandlungsagenzien）。
公开(公告)号：EP0164227A2
公开(公告)日：1985-12-11
申请号：EP85303352.0
申请日：1985-05-13
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Sugerman, Gerald , Monte, Salvatore J.
IPC分类号： C07F7/00 , C07F9/09 , C08F8/42 , C08G85/00 , C08K5/06 , C08K5/52 , C08K5/17 , C08K5/41 , C08K5/09 , C08K5/05 , C08K9/04
CPC分类号： C08K5/0091 , C07F7/006 , C07F9/09 , C07F9/098 , C08F8/42
摘要： A neoalkoxy compound having the following formula:
wherein M is titanium or zirconium, R, R 1 and R 2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to twenty carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R 2 may also be an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a + b + c = 3. The compound is useful as a coupling and polymer processing agent and compositions containing the compound and methods of preparing polymeric material including the compound are also described.
摘要翻译：具有下式的新烷氧基化合物：其中M是钛或锆，R，R 1和R 2各自是具有至多20个碳的一价烷基，烯基，炔基，芳烷基，芳基或烷芳基原子或其卤素或醚取代的衍生物，另外R 2也可以是所述基团的氧基衍生物或醚取代的氧代衍生物; A，B和C各自为含有至多30个碳原子的单价芳氧基，硫代羟基，二酯磷酸酯，二酯焦磷酸酯，氧烷基氨基，磺酰基或羧基; 和a + b + c = 3。该化合物可用作偶联剂和聚合物加工剂，并且还描述了含有该化合物的组合物和制备包括该化合物的聚合物材料的方法。

6. 发明授权

EP0007761B1 Cumylphenol derivatives and their use in synthetic resin compositions 失效
标题翻译：氰基苯酚衍生物及其在合成树脂组合物中的用途
公开(公告)号：EP0007761B1
公开(公告)日：1984-01-18
申请号：EP79301403.6
申请日：1979-07-16
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Monte, Salvatore J. , Sugerman, Gerald
IPC分类号： C07C43/205 , C07C43/215 , C07C69/353 , C07C69/527 , C08K5/04 , C08K5/55
CPC分类号： C08K5/55 , C08K5/105

7. 发明授权

EP0024899B1 Pyrophosphato titanate adducts and methods for treating particulate fillers using such adducts 失效
标题翻译：磷酸氢钙钛酸盐添加剂和使用这种添加剂处理颗粒填料的方法
公开(公告)号：EP0024899B1
公开(公告)日：1983-08-10
申请号：EP80302921.4
申请日：1980-08-22
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Monte, Salvatore J. , Sugarman, Gerald
IPC分类号： C07F9/09 , C07F9/141 , C08K5/51 , C08K9/04 , B01J27/18
CPC分类号： B01J31/1805 , B01J27/18 , B01J31/185 , B01J31/223 , B01J2531/46 , C07F9/02 , C07F9/098 , C08K5/51 , C08K9/04

8. 发明公开

EP0024899A1 Pyrophosphato titanate adducts and methods for treating particulate fillers using such adducts 失效
标题翻译：焦磷酸钛酸加合物和一种使用这样的加合物的粉碎的填料的方法。
公开(公告)号：EP0024899A1
公开(公告)日：1981-03-11
申请号：EP80302921.4
申请日：1980-08-22
申请人： KENRICH PETROCHEMICALS, INC.
发明人： Monte, Salvatore J. , Sugarman, Gerald
IPC分类号： C07F9/09 , C07F9/141 , C08K5/51 , C08K9/04 , B01J27/18
CPC分类号： B01J31/1805 , B01J27/18 , B01J31/185 , B01J31/223 , B01J2531/46 , C07F9/02 , C07F9/098 , C08K5/51 , C08K9/04
摘要： Adducts of tetrasubstituted pyrophosphato titanates and/oramines, havetheformula
wherein c is 1 or 2; d is 0, 1 or 2; e is 0,1 or 2; with the proviso that d plus e must be 1 or 2; with the proviso that if c is 1, X must be RO-; and with the proviso that when c is 2, X is either RO- or a group which taken together with the Ti to which it is attached forms a ring having theformula
wherein each of f, g, h and i is 0 or 1, with the proviso that at least one of g, h, and i is 1 and that the sum of f, g, h and i is or 3; and wherein each R is independently selected from C, to C, o alkyl, C 3 to C, o alkenyl, C 7 to C, o dioxyalkylene; R', R2, R 4 , R 7 , each R 10 and each R" are independently selected from hydrogen, C 6 to C 10 aryl, C 7 to C 20 aralkyl, C 1 to C 20 alkyl, C 3 to C 20 alkenyl, C 2 to C 20 oxyalkylene and C 3 to C 20 oligooxyalkylene, with the proviso that one and only one of R' and R 2 is hydrogen; R 5 , R 6 , R 8 and R 9 are independently selected from the same groups as are R 1 , R 2 , R 4 , R', each R 10 and each R", except that R 5 , R 6 , R 8 and R 9 may not be hydrogen, and, in addition, R 5 and R 6 are independently selected from C, to C, alkanol, C 2 to C 6 alkadiol, C 7 to C 10 aralkanol, substituted and unsubstituted C, to C 10 alkyl, substituted and unsubstituted C 3 to C 10 aralkyl, these last four groups being optionally substituted with 1 to 3 carboxylate groups or from 1 to 3 carboxamide groups, each such carboxylate group and each such carboxamide group being saturated or unsaturated and having from 1 to 5 carbon atoms; with the proviso that when aromatic carbons are present in any one of R, R 2 , R 4 , R 7 , R 10 or R", each of said carbons is optionally substituted with 1 or 2 independently selected halogen atoms.
The adducts are useful for improving the physical and chemical properties of many filled resins.
There is also described a method of catalyzing a chemical reaction that is susceptible to catalysis by a Lewis Acid catalyst, a method of improving the dispersability of an inorganic solid and a method of improving the conductivity of a metal filled polymer, all these methods involving the use of the above adducts.
Water solubility may be conferred on a pyrophosphato titanate of the formula X c Ti[OP(O) (OR') OP (O) (OR 2 ) (OR 3 )]4-c wherein X, c, R 1 , R 2 and R 3 are as defined above by converting said titanate to an adduct of the invention.

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