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2. 发明公开

EP1281668A3 Fuel reforming apparatus and the method of starting it 有权
标题翻译：燃料重整和方法用于启动该重整
公开(公告)号：EP1281668A3
公开(公告)日：2004-02-04
申请号：EP02016374.7
申请日：2002-07-25
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd. , Honda Giken Kogyo Kabushiki Kaisha
发明人： Takimoto, Hidetoshi , Mizusawa, Minoru , Fukuchi, Yasuhiko , Kotani, Yasunori, K.K. Honda Gijutsu Kenkyusho
IPC分类号： C01B3/32 , C01B3/38 , B01J8/04 , H01M8/06
CPC分类号： C01B3/386 , B01B1/005 , B01J8/0438 , B01J19/0013 , B01J2208/0053 , B01J2208/00548 , B01J2208/00716 , B01J2208/025 , B01J2219/00063 , B01J2219/00069 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B60L11/1885 , B60L11/1892 , B60L11/1894 , C01B2203/0244 , C01B2203/047 , C01B2203/066 , C01B2203/0844 , C01B2203/1005 , C01B2203/1076 , C01B2203/143 , C01B2203/1604 , C01B2203/82 , Y02P20/129 , Y02T90/34
摘要： A combustion/reforming catalyst 15 is composed of a plurality of catalyst layers 15a, 15b, 15c arranged in series with intervals between them, and when a fuel reforming apparatus is started from a low temperature, while the supply of the fuel gas is stopped, air preheated in a preheater is supplied in parallel to a point upstream of each catalyst layer, thereby the catalyst in each catalyst layer is self-heated at the same time so that the entire catalyst is heated. After the whole catalyst is heated up to a temperature at which a combustion/reforming reaction can take place, the feed of air is temporarily stopped, the supply of fuel gas is started, next air is supplied while controlling the flow rate thereof so that temperatures in the catalyst do not exceed the temperature that the catalyst can withstand. Thus, no other special equipment or utilities are needed, and the apparatus can be started quickly (cold start), the reforming catalyst and the fuel cell can be protected from poisoning, and the apparatus can be made compact enough to install it in a electric vehicle.

3. 发明公开

EP1281668A2 Fuel reforming apparatus and the method of starting it 有权
标题翻译： Brennstoffreformer und Methode zum Starten死于改革者
公开(公告)号：EP1281668A2
公开(公告)日：2003-02-05
申请号：EP02016374.7
申请日：2002-07-25
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd. , Honda Giken Kogyo Kabushiki Kaisha
发明人： Takimoto, Hidetoshi , Mizusawa, Minoru , Fukuchi, Yasuhiko , Kotani, Yasunori, K.K. Honda Gijutsu Kenkyusho
IPC分类号： C01B3/32 , C01B3/38 , B01J8/04 , H01M8/06
CPC分类号： C01B3/386 , B01B1/005 , B01J8/0438 , B01J19/0013 , B01J2208/0053 , B01J2208/00548 , B01J2208/00716 , B01J2208/025 , B01J2219/00063 , B01J2219/00069 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B60L11/1885 , B60L11/1892 , B60L11/1894 , C01B2203/0244 , C01B2203/047 , C01B2203/066 , C01B2203/0844 , C01B2203/1005 , C01B2203/1076 , C01B2203/143 , C01B2203/1604 , C01B2203/82 , Y02P20/129 , Y02T90/34
摘要： A combustion/reforming catalyst 15 is composed of a plurality of catalyst layers 15a, 15b, 15c arranged in series with intervals between them, and when a fuel reforming apparatus is started from a low temperature, while the supply of the fuel gas is stopped, air preheated in a preheater is supplied in parallel to a point upstream of each catalyst layer, thereby the catalyst in each catalyst layer is self-heated at the same time so that the entire catalyst is heated. After the whole catalyst is heated up to a temperature at which a combustion/reforming reaction can take place, the feed of air is temporarily stopped, the supply of fuel gas is started, next air is supplied while controlling the flow rate thereof so that temperatures in the catalyst do not exceed the temperature that the catalyst can withstand. Thus, no other special equipment or utilities are needed, and the apparatus can be started quickly (cold start), the reforming catalyst and the fuel cell can be protected from poisoning, and the apparatus can be made compact enough to install it in a electric vehicle.
摘要翻译：燃烧/重整催化剂15由与它们之间的间隔串联排列的多个催化剂层15a，15b，15c组成，并且当燃料重整装置从低温启动时，在燃料气体的供给停止的同时，在预热器中预热的空气与每个催化剂层上游的点平行地供应，从而催化剂层中的催化剂同时自加热，从而加热整个催化剂。在将整个催化剂加热到可以发生燃烧/重整反应的温度之后，暂时停止空气的供给，开始供应燃料气体，同时控制下一个空气，同时控制其流量，使得温度在催化剂中不超过催化剂可承受的温度。因此，不需要其他专用设备或设备，并且可以快速启动设备（冷起动），可以防止重整催化剂和燃料电池中毒，并且该设备可以制造得足够紧凑以将其安装在电车辆。

4. 发明公开

EP0529329A2 Plate type shift converter 失效
标题翻译：板式转换器
公开(公告)号：EP0529329A2
公开(公告)日：1993-03-03
申请号：EP92112854.2
申请日：1992-07-28
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Kawakami, Souichirou , Mizusawa, Minoru
IPC分类号： H01M8/06 , C01B3/48 , B01J8/02
CPC分类号： F28D9/0062 , B01J8/0207 , B01J19/249 , B01J2208/00106 , B01J2208/021 , B01J2219/0002 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2474 , B01J2219/2481 , B01J2219/2493 , B01J2219/2498 , C01B3/16 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1241 , C01B2203/82 , F28F2250/104 , H01M8/0625
摘要： A plate type shift converter (30) comprises a stack (52) of alternately piled shift reactor plates (31) and cooling plates (32) and various gas intake and exhaust manifolds (53, 55, 54, 56) mounted on lateral faces of the stack (52). Each shift reactor plate (31) includes a plate member (33), a masking frame (34) provided along the periphery of the plate member (33), a gas entrance (35) formed in the masking frame (34), a gas exit (36) formed at a location opposite the gas entrance (35) in the masking frame (34) and a shift catalyst (42) located in the masking frame (34). Each cooling plate (32) includes a plate member (33), a masking frame (44) provided along the periphery of the plate member (33), a gas entrance (45) formed in the masking frame (44), a gas exit (46) formed at a location opposite the second gas entrance (45) in the masking frame (44) and a fin plate (47) located in the masking frame (44). When gases are introduced to the shift reactor plate (31), the gases undergo the CO shift reaction (exothermic reaction) as they flow contacting the shift catalyst (42). At the same time, the gases are cooled by the cooling plates (32) which sandwich the flow of the gases or sandwich the shift reactor plate (31).
摘要翻译：一种板式变换器（30），包括交替堆积的变换反应器板（31）和冷却板（32）的堆叠（52）以及安装在所述板式换热器的侧面上的各种进气和排气歧管（53,55,54,56）堆（52）。每个变换反应器板31包括板构件33，沿着板构件33的周边设置的掩模框架34，形成在掩模框架34中的气体入口35，在掩蔽框架（34）中与气体入口（35）相对的位置处形成的出口（36）和位于掩蔽框架（34）中的变换催化剂（42）。冷却板32包括板状部件33，沿着板状部件33的周围设置的掩模框44，形成在掩模框44上的气体入口45，（44）中的与第二气体入口（45）相对的位置处形成的隔板（46）以及位于掩模框架（44）中的翅片板（47）。当气体被引入变换反应器板（31）时，气体在与变换催化剂（42）接触时经历CO变换反应（放热反应）。同时，气体被夹着气体流动的冷却板（32）冷却或夹在变换反应器板（31）之间。

5. 发明公开

EP0529329A3 Plate type shift converter 失效
标题翻译：板式转换器
公开(公告)号：EP0529329A3
公开(公告)日：1993-08-04
申请号：EP92112854.2
申请日：1992-07-28
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Kawakami, Souichirou , Mizusawa, Minoru
IPC分类号： H01M8/06 , C01B3/48 , B01J8/02
CPC分类号： F28D9/0062 , B01J8/0207 , B01J19/249 , B01J2208/00106 , B01J2208/021 , B01J2219/0002 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2474 , B01J2219/2481 , B01J2219/2493 , B01J2219/2498 , C01B3/16 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1241 , C01B2203/82 , F28F2250/104 , H01M8/0625
摘要： A plate type shift converter (30) comprises a stack (52) of alternately piled shift reactor plates (31) and cooling plates (32) and various gas intake and exhaust manifolds (53, 55, 54, 56) mounted on lateral faces of the stack (52). Each shift reactor plate (31) includes a plate member (33), a masking frame (34) provided along the periphery of the plate member (33), a gas entrance (35) formed in the masking frame (34), a gas exit (36) formed at a location opposite the gas entrance (35) in the masking frame (34) and a shift catalyst (42) located in the masking frame (34). Each cooling plate (32) includes a plate member (33), a masking frame (44) provided along the periphery of the plate member (33), a gas entrance (45) formed in the masking frame (44), a gas exit (46) formed at a location opposite the second gas entrance (45) in the masking frame (44) and a fin plate (47) located in the masking frame (44). When gases are introduced to the shift reactor plate (31), the gases undergo the CO shift reaction (exothermic reaction) as they flow contacting the shift catalyst (42). At the same time, the gases are cooled by the cooling plates (32) which sandwich the flow of the gases or sandwich the shift reactor plate (31).

6. 发明授权

EP0529329B1 Plate type shift converter 失效
标题翻译：板式转换器
公开(公告)号：EP0529329B1
公开(公告)日：1997-03-26
申请号：EP92112854.2
申请日：1992-07-28
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Kawakami, Souichirou , Mizusawa, Minoru
IPC分类号： H01M8/06 , C01B3/48 , B01J8/02
CPC分类号： F28D9/0062 , B01J8/0207 , B01J19/249 , B01J2208/00106 , B01J2208/021 , B01J2219/0002 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2474 , B01J2219/2481 , B01J2219/2493 , B01J2219/2498 , C01B3/16 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1241 , C01B2203/82 , F28F2250/104 , H01M8/0625

7. 发明公开

EP0429958A2 Power generation system using molten carbonate fuel cell 失效
标题翻译：采用熔融碳酸盐燃料电池的发电系统
公开(公告)号：EP0429958A2
公开(公告)日：1991-06-05
申请号：EP90121804.0
申请日：1990-11-14
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Watanabe, Takenori , Kamata, Toshio , Morishima, Satoshi , Mizusawa, Minoru , Kobayashi, Kazunori
IPC分类号： H01M8/06
CPC分类号： H01M8/0612 , H01M8/0625 , H01M8/145 , Y02E60/526
摘要： A power generation system uses fuel cells (C, S) stacked via separators (31). Cooling plates (33) are provided in the fuel cell stack (S). Passages (34) are formed in each cooling plate (33) for allowing raw-material-gas-for-reformation (which also serves as stack-cooling-gas) to flow therethrough and the passages (34) are filled with reforming catalyst (61). An external reformer (37) which includes a combustion section (39) and a reforming section (38) is provided outside of the fuel cell stack (5). A stack-cooling-gas-line (45) is connected to the passages (34) of the cooling plates (33) for introducing the raw-materialgas-for-the-reformation (the stack-cooling-gas) into the passages (33). A line (50) for gas-for-processing is connected to the reforming section (38) of the external reformer (37) for feeding raw-material -gas-for-processing to the reforming section (38). An anode gas feed line (52) is provided for feeding to the anode (3) the reformed gas which has been reformed through the passages (34) of the cooling plates (33) and the reformed gas which has been reformed by the reforming section (38) of the external reformer (37). An anode exit gas line (53) is provided for feeding the anode exit gas to the combustion section (39) of the external reformer (37). A cathode gas feed line (55) is provided for feeding the combustion exhaust gas discharged from the combustion section (39) to the cathode (2) with air (A). A cathode exit gas line (56) is provided for discharging the cathode exit gas.
摘要翻译：发电系统使用经由分离器（31）堆叠的燃料电池（C，S）。在燃料电池堆（S）中设有冷却板（33）。在各冷却板33上形成用于使重整用原料气体（也兼作叠层冷却用气体）流通的通路34，在通路34中填充改性催化剂（ 61）。在燃料电池组（5）的外部设有具有燃烧部（39）和改性部（38）的外部改性器（37）。在冷却板（33）的通路（34）上连接有用于将重整用原料气体（电池组冷却用气体）导入到通路（34）内的电池组冷却气体管线（45） 33）。加工用气体管线（50）与外部改性器（37）的改性部（38）连接，向改性部（38）供给原料气体。设置阳极气体供给管线（52），用于将通过冷却板（33）的通路（34）重整的重整气体和通过重整部分重整的重整气体供给到阳极（3）（37）的外部重整器（38）。提供阳极出口气体管线（53），用于将阳极出口气体供给外部重整器（37）的燃烧部分（39）。设置阴极气体供给管线（55），用于将从燃烧部分（39）排出的燃烧废气与空气（A）一起供给到阴极（2）。提供阴极排出气体管线（56）用于排出阴极排出气体。

8. 发明公开

EP0691701A1 Plate reformer 失效
标题翻译： Platten重整
公开(公告)号：EP0691701A1
公开(公告)日：1996-01-10
申请号：EP95110504.8
申请日：1995-07-05
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Hamada, Kouki , Mizusawa, Minoru , Koga, Minoru
IPC分类号： H01M8/06 , B01J8/02
CPC分类号： H01M8/0631 , B01J8/0207 , B01J19/249 , B01J2208/022 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2481 , B01J2219/2497 , C01B3/384 , H01M8/0625 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： In the plate reformer, a reforming chamber (2) is sandwiched by combustion chambers (4) so that heat transfer plates (5) also be sandwiched between the reforming chamber and the combustion chambers, and these three plate-shaped components are again sandwiched with fuel introducing chambers (7) with a number of dispersion holes (6a), forming a unit a plurality of which is then vertically stacked up to form the reformer. The plate reformer includes:
entrance and exit of the reforming chamber (2) and entrance and exit of the combustion chamber (4), wherein the gas flows in the reforming chamber and in the combustion chamber are opposite to each other; and
a gas permeable partition wall for partitioning each of the reforming and the combustion chambers into entrance-side section and exit-side section according to the gas flow, as well as for passing gases through during reaction;
wherein the reforming chamber (2) includes:
a reforming reaction section (2a) which is the entrance-side section of the reforming chamber partitioned by the partition wall (8) filled with reforming catalyst (1); and
a heat exchange section (2b) which is the exit-side section of the partitioned reformer and filled with heat transfer component (10);
while the combustion chamber (4) includes:
a combustion reaction section (4a) which is the entrance-side section of the combustion chamber partitioned by the partition wall (9) and filled with combustion catalyst (3); and a heat exchange section (4b) which is the exit-side of the partitioned combustion chamber and filled with heat transfer component (10).
The invention allows the peak locations of temperature distribution profiles of reformed and combusted gases to coincide, achieving an adequate temperature of the reformed gas at the exit.
摘要翻译：在板式重整器中，重整室（2）被燃烧室（4）夹持，使得传热板（5）也夹在重整室和燃烧室之间，并且这三个板状部件再次夹在具有多个分散孔（6a）的燃料引入室（7），形成多个单元，然后将其垂直堆叠形成重整器。板式重整器包括：重整室（2）的入口和出口以及燃烧室（4）的入口和出口，其中在重整室和燃烧室中流动的气体彼此相对; 以及气体分离壁，用于根据气体流将每个重整燃烧室和燃烧室分隔成入口侧部分和出口侧部分，以及在反应期间使气体通过; 其特征在于，所述重整室包括：重整反应部（2a），其由被填充有重整催化剂（1）的分隔壁（8）分隔的重整室的入口侧部分; 和作为分隔重整器的出口侧部分并填充有传热部件（10）的热交换部分（2b）。而燃烧室（4）包括：燃烧反应部分（4a），其是由分隔壁（9）分隔并填充有燃烧催化剂（3）的燃烧室的入口侧部分; 和作为分隔燃烧室的出口侧并填充有传热部件（10）的热交换部（4b）。本发明允许重整和燃烧的气体的温度分布曲线的峰值位置重合，实现出口处重整气体的适当温度。

9. 发明授权

EP0429958B1 Power generation system using molten carbonate fuel cell 失效
标题翻译：发电系统与使用熔融碳酸盐。
公开(公告)号：EP0429958B1
公开(公告)日：1994-02-02
申请号：EP90121804.0
申请日：1990-11-14
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Watanabe, Takenori , Kamata, Toshio , Morishima, Satoshi , Mizusawa, Minoru , Kobayashi, Kazunori
IPC分类号： H01M8/06
CPC分类号： H01M8/0612 , H01M8/0625 , H01M8/145 , Y02E60/526

10. 发明公开

EP0429958A3 Power generation system using molten carbonate fuel cell 失效
标题翻译：使用碳酸氢盐燃料电池的发电系统
公开(公告)号：EP0429958A3
公开(公告)日：1991-07-24
申请号：EP90121804.0
申请日：1990-11-14
申请人： Ishikawajima-Harima Heavy Industries Co., Ltd.
发明人： Koga, Minoru , Watanabe, Takenori , Kamata, Toshio , Morishima, Satoshi , Mizusawa, Minoru , Kobayashi, Kazunori
IPC分类号： H01M8/06
CPC分类号： H01M8/0612 , H01M8/0625 , H01M8/145 , Y02E60/526
摘要： A power generation system uses fuel cells (C, S) stacked via separators (31). Cooling plates (33) are provided in the fuel cell stack (S). Passages (34) are formed in each cooling plate (33) for allowing raw-material-gas-for-reformation (which also serves as stack-cooling-gas) to flow therethrough and the passages (34) are filled with reforming catalyst (61). An external reformer (37) which includes a combustion section (39) and a reforming section (38) is provided outside of the fuel cell stack (5). A stack-cooling-gas-line (45) is connected to the passages (34) of the cooling plates (33) for introducing the raw-materialgas-for-the-reformation (the stack-cooling-gas) into the passages (33). A line (50) for gas-for-processing is connected to the reforming section (38) of the external reformer (37) for feeding raw-material -gas-for-processing to the reforming section (38). An anode gas feed line (52) is provided for feeding to the anode (3) the reformed gas which has been reformed through the passages (34) of the cooling plates (33) and the reformed gas which has been reformed by the reforming section (38) of the external reformer (37). An anode exit gas line (53) is provided for feeding the anode exit gas to the combustion section (39) of the external reformer (37). A cathode gas feed line (55) is provided for feeding the combustion exhaust gas discharged from the combustion section (39) to the cathode (2) with air (A). A cathode exit gas line (56) is provided for discharging the cathode exit gas.

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