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1. 发明授权

EP1966288B1 FILM DE POLYMERE RETICULE PORTANT DES GROUPEMENTS IONIQUES 有权
标题翻译：电影从离子基团的交联聚合物
公开(公告)号：EP1966288B1
公开(公告)日：2014-05-28
申请号：EP06831150.5
申请日：2006-11-21
申请人： Institut Polytechnique de Grenoble , Eras-Labo , Centre National de la Recherche Scientifique , Blue Solutions , SOLVAY SA
发明人： SANCHEZ, Jean-Yves , IOJOIU, Cristina , MERCIER, Régis , EL KISSI, Nadia , CHABERT, France , SALOMON, Jérémie
IPC分类号： B01J47/12 , B01D67/00 , C08J7/12 , H01G11/56 , B01J39/18 , C08J3/24 , H01G9/022
CPC分类号： H01G9/038 , B01D67/0006 , B01D2323/38 , B01D2323/42 , B01D2325/14 , B01J39/19 , B01J47/12 , C08J3/246 , C08J7/12 , H01G11/56 , H01M10/052 , H01M10/0565 , Y02E60/13

3. 发明公开

EP1858631A1 EXTRUSION D'UN POLYMERE THERMOPLASTIQUE PORTANT DES GROUPEMENTS IONIQUES ACIDES 有权
标题翻译：与酸性离子基团挤出热塑性聚合物
公开(公告)号：EP1858631A1
公开(公告)日：2007-11-28
申请号：EP06726057.0
申请日：2006-03-09
申请人： Institut National Polytechnique de Grenoble , Eras-Labo , COMMISSARIAT A L'ENERGIE ATOMIQUE ( CEA) , Centre National de la Recherche Scientifique
发明人： SANCHEZ, Jean-Yves , IOJOIU, Cristina , PIFFARD, Yves , EL KISSI, Nadia , CHABERT, France
IPC分类号： B01D67/00 , B01D71/68 , B01D71/52 , B01D71/82 , C08J5/22 , H01M8/10 , C08L71/00
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/02 , B01D2323/08 , B01D2323/20 , B01D2323/21 , B01D2325/24 , C08J5/2256 , C08J2371/12 , C08J2379/06 , C08L71/00 , C08L81/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a method for the extrusion of thermoplastic polymers comprising acid ionic groupings. The inventive method consists in: preparing a mixture comprising (i) a thermoplastic polymer bearing acid ionic groupings and (ii) a plasticiser; extruding the mixture thus obtained in order to form a film; and, subsequently, washing the film obtained in an aqueous medium in order to eliminate said plasticiser(s). The aforementioned plasticiser is selected from among non-volatile compounds which are stable in relation to the ionic groupings of the polymer and which are soluble in water or in water-miscible solvents, said plasticisers being selected from among the compounds that act with the ionic grouping of the polymer with the formation of a weak hydrogen-bond-type binding and the compounds that act with the ionic grouping of the polymer with the formation of an strong ionic-bond-type binding.

5. 发明公开

EP1858630A1 PREPARATION D'UNE MEMBRANE PAR EXTRUSION D'UN POLYMERE THERMOPLASTIQUE PORTANT DES GROUPEMENTS IONIQUES ALCALINS. 有权
标题翻译：与碱性离子基团MEBRANHERSTELLUNGSVERFAHREN与挤出热塑性聚合物
公开(公告)号：EP1858630A1
公开(公告)日：2007-11-28
申请号：EP06726056.2
申请日：2006-03-09
申请人： INSTITUT NATIONAL POLYTECHNIQUE DE GRENOBLE , Eras-Labo , COMMISSARIAT A L'ENERGIE ATOMIQUE , Centre National de la Recherche Scientifique
发明人： SANCHEZ, Jean-Yves , IOJOIU, Cristina , MERCIER, Régis , MARECHAL, Manuel , EL KISSI, Nadia , GALIANO, Hervé , CHABERT, France
IPC分类号： B01D67/00 , B01D71/68 , B01D71/52 , B01D71/82 , H01M8/10
CPC分类号： B01D67/0025 , B01D67/002 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/12 , B01D2325/32 , C08J5/2256 , C08J2371/12 , C08L71/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a method for the extrusion of thermoplastic polymers comprising alkaline ionic groupings. The inventive method consists in: preparing a mixture comprising (i) a thermoplastic polymer bearing alkaline ionic groupings and (ii) a plasticiser; extruding the mixture thus obtained in order to form a film; and, subsequently, washing the film obtained in an aqueous medium in order to eliminate said plasticiser(s). The aforementioned plasticiser is selected from among non-volatile compounds which are stable in relation to the ionic groupings of the polymer and which are soluble in water or in water-miscible solvents, said plasticiser(s) being selected from among the compounds that act with the ionic grouping of the polymer with the formation of a weak hydrogen-bond-type binding and the compounds that act with the ionic grouping of the polymer with the formation of a strong ionic-bond-type binding.

6. 发明公开

EP1966288A1 FILM DE POLYMERE RETICULE PORTANT DES GROUPEMENTS IONIQUES. 有权
标题翻译： FILM AUS VERNETZTEM POLYMER MIT IONISCHEN GRUPPIERUNGEN
公开(公告)号：EP1966288A1
公开(公告)日：2008-09-10
申请号：EP06831150.5
申请日：2006-11-21
申请人： INSTITUT NATIONAL POLYTECHNIQUE DE GRENOBLE , Eras-Labo , Centre National de la Recherche Scientifique , Batscap
发明人： SANCHEZ, Jean-Yves , IOJOIU, Cristina , MERCIER, Régis , EL KISSI, Nadia , CHABERT, France , SALOMON, Jérémie
IPC分类号： C08J5/22 , C08J3/24 , C08L81/06 , B01D61/44 , B01J39/18 , H01G4/14
CPC分类号： H01G9/038 , B01D67/0006 , B01D2323/38 , B01D2323/42 , B01D2325/14 , B01J39/19 , B01J47/12 , C08J3/246 , C08J7/12 , H01G11/56 , H01M10/052 , H01M10/0565 , Y02E60/13
摘要： The invention relates to the preparation of a crosslinked polymer film bearing ionic groupings. The inventive method consists in: extruding a material containing at least one prepolymer, polymerising the material after extrusion, and subjecting the extruded material to a chemical reaction in order to graft ionic groupings. The prepolymer includes repeating units, each consisting of at least one aromatic group (GA) and at least one functional group (GF). In addition, the prepolymer bears at least one group (GP) which can be polymerised thermally at a temperature above the extrusion temperature or photochemically, as well as at least one reactive group (GR) that enables the grafting of ionic groupings. The films can be used as a membrane for fuel cells or for electrodialysis, as an electrolyte of a lithium battery, a super-capacitor or an electrochrome device or as an ion exchange membrane.
摘要翻译：制备具有阳离子的离子基团的交联聚合物膜质子和有机离子，例如咪唑鎓离子包括挤出具有至少预聚物的聚合物材料，聚合挤出的聚合物并接枝离子基团，其中预聚物具有具有芳族基团，官能团和反应性基团的重复单元，其中官能团在温度下可热聚合大于挤出温度或光化学反应，并且反应性基团允许离子基团的接枝。制备具有离子基团的交联聚合物膜，其中式M（p +）的阳离子或质子和有机离子是铵，咪唑鎓，吡唑鎓，四唑鎓，吡啶鎓或胍盐离子包括挤出具有至少一个预聚物，聚合挤出的聚合物和接枝离子基团，其中预聚物具有具有芳族 - 官能团和反应基团的重复单元，其中官能团在大于挤出温度或光化学可聚合基团的温度下可热聚合，并且反应基团允许离子基团的接枝。 M：金属离子和p：1-3氧化数。独立权利要求包括：（1）通过该过程获得的电影; （2）可用作式（I）的预聚物的聚苯基化合物; （3）制备（I）的方法，其包括通过4,4'-二氯二苯砜，4,4'-二羟基联苯单体和1,4（双）（对羟基苯氧基）苯的缩聚制备式（Ia）的遥爪聚砜单体，在非质子极性溶剂和弱碱的M +阳离子存在下，用式（Ib）的单官能单体改性所得预聚物。 R 5>连接基或芳基醚; 和R 7>卤素。 [图像] [图像] [图像]。

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