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1. 发明公开

EP1209173A1 BRANCHED OLEFINIC MACROMONOMER, OLEFIN GRAFT COPOLYMER, AND OLEFIN RESIN COMPOSITION 审中-公开
标题翻译： VERZWEIGTE OLEFINISCHE MAKROMONOMERE，OLEFINISCHES PFROPFPOLYMER UND POLYOLEFINMISCHUNG
公开(公告)号：EP1209173A1
公开(公告)日：2002-05-29
申请号：EP00946378.7
申请日：2000-07-18
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： MACHIDA, Shuji , SATO, Kazuo , TATSUMI, Tomio , GOTO, Yasuhiro
IPC分类号： C08F10/00 , C08F290/04 , C08L101/00
CPC分类号： C08F290/04 , C08F290/042 , C08F290/14 , C08F290/141
摘要： The invention relates to olefin branched macromonomers, olefin graft copolymers and olefin resin compositions having the advantages of good compatibility with polyolefin resins and good moldability and workability. The olefin branched macromonomer satisfies the following (a) and (b):

(a) its weight-average molecular weight (Mw) measured through gel permeation chromatography (GPC) falls between 400 and 200000;
(b) its vinyl content is at least 70 mol% of all the unsaturated groups in the macromonomer.
摘要翻译：本发明涉及烯烃支化大分子单体，烯烃接枝共聚物和烯烃树脂组合物，其具有与聚烯烃树脂的良好相容性和良好的成型性和可加工性。烯烃支化大分子单体满足以下（a）和（b）：（a）通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为400〜200000; （b）其乙烯基含量为大分子单体中所有不饱和基团的至少70摩尔％。

2. 发明公开

EP1477498A1 PROCESS FOR PRODUCING MODIFIED BUTENE-1 POLYMER AND MODIFIED BUTENE-1 POLYMER OBTAINED BY THE PROCESS 有权
标题翻译：丹麦赫尔辛基（ZER）HERSTELLUNG VON MODIFIZIERTEM BUTEN-1-POLYMER UND DANACH ERHALTENES BUTEN-1-POLYMER
公开(公告)号：EP1477498A1
公开(公告)日：2004-11-17
申请号：EP03705328.7
申请日：2003-02-19
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： KANAMARU, Masami , MINAMI, Yutaka , ABURATANI, Ryo , TATSUMI, Tomio
IPC分类号： C08F8/46 , C08F255/10 , C09J123/30 , C09J151/06
CPC分类号： C09J151/003 , C08F255/00 , C08F255/10 , C08F257/02 , C08L23/20 , C08L51/003 , C08L51/06 , C08L2666/02 , C08L2666/24 , C09J123/20 , C09J151/06 , Y10S526/943 , C08F222/06 , C08F220/06 , C08F212/08
摘要： The present invention relates to a process for producing a buten-1-based polymer satisfying the following requirements (a), (b) and (c): (a) a crystalline resin having a melting point (Tm -D) of 0 to 100°C, the melting point being defined as a top of a peak observed on a highest-temperature side in a melting endothermic curve obtained by a differential scanning calorimeter (DSC) when a sample is held in a nitrogen atmosphere at -10°C for 5 min and then heated at a temperature rise rate of 10°C/min; (b) a stereoregularity index represented by (mmmm)/(mmrr + rmmr) of 20 or less; and (c) a weight-average molecular weight (Mw) of 10,000 to 1,000,000 and a ratio (Mw/Mn) of weight-average molecular weight to number-average molecular weight of 4.0 or less; a modified buten-1-based polymer produced by modifying the buten-1-based polymer with a radical polymerization initiator and an organic acid; and an adhesive composition containing the modified buten-1-based polymer. The modified buten-1-based polymer of the present invention is capable of imparting a high adhesiveness, a high strength and a good softness to polyolefins, and providing sealants having a high adhesiveness, or polyolefins having an improved compatibility to inorganic fillers, etc., in particular, is useful as resins for hot-melt adhesives.
摘要翻译：本发明涉及一种满足以下（a），（b）和（c）要求的丁烯-1系聚合物的制造方法：（a）熔点（Tm-D）为0〜在将样品保持在-10℃的氮气气氛下，通过差示扫描量热计（DSC）获得的熔融吸热曲线中，熔点定义为在最高温度侧观察到的峰的顶部 5分钟，然后以10℃/ min的升温速率加热; （b）由（mmmm）/（mmrr + rmmr）表示的立构规整性指数为20以下; 和（c）重均分子量（Mw）为10,000〜1,000,000，重均分子量与数均分子量的比（Mw / Mn）为4.0以下; 通过用自由基聚合引发剂和有机酸改性丁烯-1-基聚合物制备的改性丁烯-1基聚合物; 和含有改性丁烯-1的聚合物的粘合剂组合物。本发明的改性丁烯-1类聚合物能够赋予聚烯烃高粘合性，高强度和良好的柔软性，并提供具有高粘合性的密封剂，或具有改善的与无机填料相容性的聚烯烃等。特别是用作热熔粘合剂的树脂。

3. 发明公开

EP1375585A1 PROPYLENE POLYMER COMPOSITION, MOLDED OBJECT, AND POLYOLEFIN COPOLYMER 有权
标题翻译：丙烯酸树脂，丙烯腈聚合物，聚对苯二甲酸乙二醇酯
公开(公告)号：EP1375585A1
公开(公告)日：2004-01-02
申请号：EP02708707.1
申请日：2002-03-28
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： GOTO, Yasuhiro , NAKAGAWA, Masaru , TATSUMI, Tomio , MACHIDA, Shuji
IPC分类号： C08L23/10 , C08L53/00 , C08F255/00 , C08F210/16
CPC分类号： C08L23/10 , C08F210/06 , C08F297/08 , C08F297/083 , C08L23/02 , C08L23/16 , C08L53/00 , C08L2666/06 , C08L2666/04 , C08L2666/24 , C08L2666/02 , C08F210/16 , C08F2500/03 , C08F2500/17
摘要： The present invention provides a propylene polymer composition containing a component (A) which is either a propylene block copolymer or a composition containing a propylene polymer and a rubber ingredient; and a component (B) which is a polyolefin copolymer that contains a fraction eluting at 101°C or higher through temperature rising elution fractionation chromatography, the fraction exhibiting a 13 C-NMR peak attributed to an ethylene chain, the polyolefin copolymer having an intrinsic viscosity falling within a range of 0.5 to 10.0 deciliter/g as measured at 135°C in decalin; a molded product formed from the composition; and a polyolefin copolymer formed of the component (B) in which a propylene polymer segment and an ethylene copolymer segment are chemically linked. According to the invention, a propylene block copolymer or a composition containing a propylene polymer and a rubber ingredient that are excellent in impact strength and tensile strength, while maintaining high rigidity thereof can be produced.
摘要翻译：本发明提供了含有作为丙烯嵌段共聚物的组分（A）或含有丙烯聚合物和橡胶组分的组合物的丙烯聚合物组合物; 以及作为聚烯烃共聚物的成分（B），其含有通过升温洗脱分级分离色谱法在101℃以上洗脱的部分，所述馏分呈现归因于乙烯链的13 C-NMR峰，所述聚烯烃共聚物具有在135℃下在十氢化萘中测定的特性粘度在0.5至10.0分升/克的范围内; 由该组合物形成的模制品; 和由丙烯聚合物链段和乙烯共聚物链段化学连接的组分（B）形成的聚烯烃共聚物。根据本发明，可以制造出具有优异冲击强度和拉伸强度同时保持其高刚性的丙烯嵌段共聚物或含有丙烯聚合物和橡胶成分的组合物。

4. 发明公开

EP1498434A1 PROCESS FOR PRODUCTION OF MODIFIED PROPYLENE POLYMERS AND MODIFIED PROPYLENE POLYMERS PRODUCED BY THE PROCESS 有权
标题翻译：用于生产改性丙烯聚合物并生产改性丙烯聚合物
公开(公告)号：EP1498434A1
公开(公告)日：2005-01-19
申请号：EP03746459.1
申请日：2003-04-11
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： KANAMARU, Masami , MINAMI, Yutaka , ABURATANI, Ryo , TATSUMI, Tomio , FUJIMURA, Takenori
IPC分类号： C08F8/46 , C08F255/02 , C09J123/26 , C09J151/06
CPC分类号： C09J123/12 , C08L2023/42 , C08L2666/02 , C09J123/10
摘要： The present invention relates to a method for producing a modified propylene-based polymer containing modifying a propylene-based polymer by a radical initiator and an organic acid, a modified propylene-based polymer obtained by the method, and an adhesive composition containing the modified propylene-based polymer. The propylene-based polymer is a propylene homopolymer satisfying the conditions of (a) mmmm = 20 to 60 mol%, (b) [rrrr/(1-mmmm)] ≦ 0.1, (c) rmrm > 2.5 mol%, (d) mm×rr/(mr) 2 ≦ 2.0, and (e) the weight ratio (W25) of components eluted at 25°C or lower in a temperature programmed chromatography is 20 to 100% by weight, or a propylene copolymer satisfying the condition of (h) the stereoregularity index (P) obtained by 13 C-NMR measurement is 55 to 90 mol%.
The modified propylene-based polymer of the invention can make a polyolefin, etc. more adhesive, stronger, or flexible, to be useful for a high-adhesive sealant or an polyolefin with increased compatibility to an inorganic filler, etc., particularly as a resin for a hot-melt adhesive.
摘要翻译：本发明涉及一种用于生产含有由自由基引发剂和有机的酸，由该方法得到的改性丙烯类聚合物的改性的基于丙烯的聚合物的改性基于丙烯的聚合物，以及粘合剂组合物含有该改性丙烯系聚合物。基于丙烯的聚合物是满足的条件的丙烯均聚物（A）MMMM = 20〜60摩尔％，（B）Ärrrr/（1-MMMM）U 2.5％（摩尔）（ D）mmxrr /（MR）<2> C-NMR测定得到的（h）中的立构规整指数（P）的条件是共聚物55〜90摩尔％。本发明的经修饰的基于丙烯的聚合物可以使聚烯烃，等多个粘合剂，更强，或柔性的，是对于高粘性密封剂或用在无机填料等相容性增加聚烯烃有用，特别是作为热熔粘合剂的树脂。

5. 发明公开

EP1312620A1 PROPYLENE HOMOPOLYMER AND PROPYLENE COPOLYMER 有权
标题翻译：丙烯均和共聚
公开(公告)号：EP1312620A1
公开(公告)日：2003-05-21
申请号：EP01951943.8
申请日：2001-07-19
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： MACHIDA, Shuji , SAEKI, Takashi , TATSUMI, Tomio
IPC分类号： C08F10/06 , C08L23/10 , C08J5/00
CPC分类号： C08F110/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L2666/04 , C08F2500/11 , C08F2500/12
摘要： Provided are a propylene homopolymer in which a melt tension (MT), a Z average molecular weight (Mz) and a melt index (MI) (g/10 minutes) are specifically related and in which a difference in eluting temperatures and a maximum eluting temperature in programmed temperature fractional chromatography and a propylene copolymer in which a comonomer is specific α-olefin and a content thereof falls in a specific range and in which a melt tension (MT), a Z average molecular weight (Mz) and a melt index (MI) (g/10 minutes) are specifically related.
The propylene homopolymer or the propylene copolymer of the present invention has physical properties equivalent to or not lower than those of conventional propylene polymers, and it can be controlled in a melt tension and is suited to foaming molding, sheet molding and blow molding. Further, it is excellent in melt-processing characteristics, molding stability and a recycling property and can be applied to molding methods which are restricted in use in conventional propylene polymers, for example, large size blow molding and extrusion foaming molding.

6. 发明公开

EP0987279A1 OLEFINIC POLYMER 失效
标题翻译： VERZWEIGTES POLYPROPYLEN
公开(公告)号：EP0987279A1
公开(公告)日：2000-03-22
申请号：EP98923126.1
申请日：1998-06-04
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： TATSUMI, Tomio , MACHIDA, Shuji , KANZAWA, Mitsugu , MINAMI, Yutaka , GOTO, Yasuhiro , KIJIMA, Masato
IPC分类号： C08F10/06 , C08F255/02 , C08L23/10
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F290/042 , C08L2205/08 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/12 , C08F2500/09 , C08F210/14 , C08F210/16
摘要： Long-chain, branched, propylene-based polymers, of which the melt index and the molecular weight distribution and the melt tension and the limiting viscosity both satisfy specific requirements, have good physical properties that are comparable to or better than those of conventional propylene-based polymers. They have good melt workability and are favorable to large-size blow molding and extrusion foaming. They are favorably used as miscibility improvers for propylene homopolymers and propylene-based copolymers.
摘要翻译：长链，支链，丙烯基聚合物，其熔体指数和分子量分布以及熔体张力和极限粘度都满足特定要求，具有与常规丙烯类聚合物相当或更好的物理性能，基聚合物。它们具有良好的熔融加工性，并且有利于大型吹塑和挤出发泡。它们有利地用作丙烯均聚物和丙烯基共聚物的混溶性改进剂。

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