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    • 2. 发明公开
    • ORGANIC ELECTROLUMINESCENCE DEVICE
    • 有机电致发光装置
    • EP3104428A1
    • 2016-12-14
    • EP16178014.3
    • 2010-06-10
    • Idemitsu Kosan Co., Ltd
    • NISHIMURA, KazukiKAWAMURA, YuichiroOGIWARA, ToshinariKUMA, HitoshiFUKUOKA, KenichiHOSOKAWA, Chishio
    • H01L51/50H01L51/00H01L27/32
    • An organic electroluminescence device is disclosed comprising opposite anode and cathode, and a hole-transporting region, an emitting layer and an electron-transporting region in sequential order from the anode between the anode and the cathode,
      wherein the emitting layer comprises a red emitting portion, a green emitting portion, and a blue emitting portion;
      the blue emitting portion comprises a host BH and a fluorescent dopant FBD;
      the triplet energy E T fbd of the fluorescent dopant FBD is larger than the triplet energy E T bh of the host BH;
      the green emitting portion comprises a host GH and a phosphorescent dopant PGD;
      the electron-transporting region comprises a common electron-transporting layer adjacent to the red emitting portion, the green emitting portion and the blue emitting portion;
      the common electron-transporting layer comprises a material represented by the following formula (20); and
      the material constituting the common electron-transporting layer has a triplet energy E T el larger than E T bh ;

              HAr-L 1 -Ar 1 -Ar 2      (20)

      wherein HAr is a substituted or unsubstituted nitrogen-containing heterocycle having 3 to 40 carbon atoms; L1 is a single bond, a substituted or unsubstituted arylene group having 6 to 40 carbon atoms or a substituted or unsubstituted heteroarylene group having 3 to 40 carbon atoms; Ar1 is a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 40 carbon atoms; and Ar2 is a substituted or unsubstituted aryl group having 6 to 40 carbon atoms or a substituted or unsubstituted heteroaryl group having 3 to 40 carbon atoms.
    • 公开了一种有机电致发光装置,其包括相对的阳极和阴极以及在阳极和阴极之间从阳极开始依次的空穴传输区域,发光层和电子传输区域,其中发光层包括红色发射部分 ,绿色发光部分和蓝色发光部分; 蓝色发光部分包括主体BH和荧光掺杂剂FBD; 荧光掺杂剂FBD的三重态能量ETfbd大于主体BH的三重态能量ETbh, 绿色发光部分包括主体GH和磷光掺杂剂PGD; 电子传输区域包括与红色发光部分,绿色发光部分和蓝色发光部分相邻的公共电子传输层; 普通电子传输层包含由下式(20)表示的材料; 构成共用电子传输层的材料的三重态能量ETel大于ETbh; HAr-L1-Ar1-Ar2(20)其中HAr是取代或未取代的具有3至40个碳原子的含氮杂环; L1为单键,取代或未取代的碳原子数6〜40的亚芳基或取代或未取代的碳原子数3〜40的亚杂芳基。 Ar 1是取代或未取代的碳原子数6〜40的2价芳香族烃基, 并且Ar 2是取代或未取代的具有6至40个碳原子的芳基或取代或未取代的具有3至40个碳原子的杂芳基。