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1. 发明公开

EP1819651A2 DIRECT ONE-STEP SYNTHESIS FROM CF3-I 有权
标题翻译： CF3-I的直接一步法合成
公开(公告)号：EP1819651A2
公开(公告)日：2007-08-22
申请号：EP05853536.0
申请日：2005-12-09
申请人： Honeywell International Inc.
发明人： MUKHOPADHYAY, Sudip , HSUEHSUNG, Tung
IPC分类号： C07C17/158 , C07C17/20 , C07C17/361 , C07C19/16
CPC分类号： C07C17/093 , C07C17/158 , C07C17/204 , C07C19/16
摘要： The present invention provides a process for the preparation of trifluoromethyl iodide. The process includes the step of: contacting in a reactor a compound represented by the formula: CF3-W and a compound represented by the formula: Z-I wherein W is selected from CF3, hydrogen and bromine; Z is selected from hydrogen, iodine and chlorine. The step of contacting is carried out, optionally in the presence of a catalyst and further optionally in the presence of air, at a temperature, pressure and for a length of time sufficient to produce the trifluoromethyl iodide.

2. 发明授权

EP1819651B1 DIRECT ONE-STEP SYNTHESIS FROM CF3-I 有权
标题翻译： CF3-I的直接一步法合成
公开(公告)号：EP1819651B1
公开(公告)日：2011-09-07
申请号：EP05853536.0
申请日：2005-12-09
申请人： Honeywell International Inc.
发明人： MUKHOPADHYAY, Sudip , HSUEHSUNG, Tung
IPC分类号： C07C17/158 , C07C17/20 , C07C17/361 , C07C19/16
CPC分类号： C07C17/093 , C07C17/158 , C07C17/204 , C07C19/16
摘要： The present invention provides a process for the preparation of trifluoromethyl iodide. The process includes the step of: contacting in a reactor a compound represented by the formula: CF3-W and a compound represented by the formula: Z-I wherein W is selected from CF3, hydrogen and bromine; Z is selected from hydrogen, iodine and chlorine. The step of contacting is carried out, optionally in the presence of a catalyst and further optionally in the presence of air, at a temperature, pressure and for a length of time sufficient to produce the trifluoromethyl iodide.

3. 发明授权

EP1879841B1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权
公开(公告)号：EP1879841B1
公开(公告)日：2012-05-16
申请号：EP06752329.0
申请日：2006-05-05
申请人： Honeywell International Inc.
发明人： MUKHOPADHYAY, Sudip , JINGJI, Ma , NAIR, Haridasan K. , HSUEHSUNG, Tung
IPC分类号： C07C17/278 , C07C19/08 , C07C21/18
CPC分类号： B01J27/125 , B01J27/10 , B01J27/12 , C07C17/00 , C07C17/278 , C07C21/18 , C07C19/08
摘要： A method for preparing fjuorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.

4. 发明公开

EP1945599A2 1,1,1,3,3,3-HEXAFLUOROPROPANE PURIFICATION WITH PHOTOCHLORINATION EQUIPMENT 审中-公开
标题翻译：光氯化设备1,1,1,3,3,3-六氟丙烷净化
公开(公告)号：EP1945599A2
公开(公告)日：2008-07-23
申请号：EP06837117.8
申请日：2006-11-08
申请人： Honeywell International Inc.
发明人： CHIU, Yuon , DAVID, Merkel , HSUEHSUNG, Tung
IPC分类号： C07C17/395 , C07C19/08
CPC分类号： C07C17/38 , C07C17/395 , C07C19/08
摘要： A continuous, vapor phase method for purifying a crude mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds, the process comprising: a) providing a photochlorinator vessel comprising : 1) a UV lamp unit comprising a UV lamp located in a transparent inner well, the transparent inner well being located within a transparent outer well, the outer well being provided with material for cooling walls of the inner and outer wells; the inner well and the outer well defining separate chambers isolated from each other; and 2) a reaction vessel into which the UV lamp unit has been inserted; b) introducing into the reaction vessel a gaseous mixture of Cb and a distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compdunds; c) reacting, in the gaseous state and in the presence of UV light from the photochlorinator, the mixture with CI2 with the distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated compounds to saturate unsaturated fluorocarbons into a reacted mixture, and d) separating a purified 1, 1,1, 3,3, 3-hexafluoroporpane product containing less than 1000 ppm, most preferably less than 100 ppm unsaturated fluorocarbons.
摘要翻译：一种用于纯化1,1,1,3,3,3-六氟丙烷和一种或多种不饱和氟碳化合物的粗混合物的连续气相法，该方法包括：a）提供光氯化器容器，该容器包括：1）UV灯包括位于透明内井中的UV灯，所述透明内井位于透明外井内，所述外井设置有用于冷却所述内井和外井的壁的材料; 内井和外井限定了彼此隔离的分隔室; 和2）其中已经插入UV灯单元的反应容器; b）将Cb和1,1,1,3,3,3-六氟丙烷和一种或多种不饱和碳氟化合物组分的蒸馏不可分离混合物的气体混合物引入反应器中; c）在气态和来自光氯化器的UV光存在下，使混合物与Cl 2与1,1,1,3,3,3-六氟丙烷和一种或多种不饱和化合物的蒸馏不可分离的混合物反应以饱和将不饱和碳氟化合物引入反应混合物中，和d）分离含有少于1000ppm，最优选少于100ppm不饱和碳氟化合物的纯化1,1,1,3,3,3-六氟丙烷产物。

5. 发明授权

EP1819650B1 DIRECT ONE-STEP SYNTHESIS OF TRIFLUOROMETHYL IODIDE 有权
标题翻译： TRIFLUOROMETHYLIODID一步到位直接合成
公开(公告)号：EP1819650B1
公开(公告)日：2008-10-01
申请号：EP05853437.1
申请日：2005-12-07
申请人： Honeywell International Inc.
发明人： MUKHOPADHAY, Sudip , HSUEHSUNG, Tung
IPC分类号： C07C17/093 , C07C19/16
CPC分类号： C07C19/16 , C07C17/093 , C07C17/361
摘要： A catalytic one-step process for the production of CF3I by reacting, preferably in the presence of a source of oxygen, a source of iodine with a reactant of the formula: CF3R where R is -SH, -S-S-CF3, -S-phenyl, or -S-Si-(CH3)3. The catalyst may be a metal salt such as salts of Cu, Hg, Pt, Pd, Co, Mn, Rh, Ni, V, TI, Ba, Cs, Ca, K and Ge and mixtures thereof, preferably on a support. such as MgO, BaO and CaO, BaCO3, CsNO3, Ba (NO3)2, activated carbon, basic alumina, and ZrO2.

6. 发明公开

EP1868974A2 METHANE AND METHYL CHLORIDE AS SELECTIVE REDUCING AGENT IN THE TRANSFORMATION OF HYDROCHLOROFLUOROCARBONS OR CHLOROFLUORCARBONS TO HYDROCHLOROFLUOROCARBONS 审中-公开
标题翻译：甲烷和一氯甲烷AS选择还原HYDRO氯氟烃或氯氟烃在水文氯氟烃的转换手段
公开(公告)号：EP1868974A2
公开(公告)日：2007-12-26
申请号：EP06738971.8
申请日：2006-03-16
申请人： Honeywell International Inc.
发明人： MUKHOPADHYAY, Sudip , MERKEL, David, C. , HSUEHSUNG, Tung
IPC分类号： C07C17/23 , C07C19/08
CPC分类号： B01J23/04 , B01J23/02 , B01J37/0201 , C07C17/23 , C07C19/08
摘要： A gas phase reaction process for producing a hydrofluorocarbon from a hydrochlorofluorocarbon or chlorofluorocarbon reactant by contacting, in the presence of a catalyst, the hydrochlorofluorocarbon or chlorofluorocarbon reactant with a reducing agent selected from methane, methyl chloride and mixtures thereof, to produce the hydrofluorocarbon.

7. 发明公开

EP1879841A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权
标题翻译：生产氟化有机化合物的方法
公开(公告)号：EP1879841A1
公开(公告)日：2008-01-23
申请号：EP06752329.0
申请日：2006-05-05
申请人： Honeywell International, Inc.
发明人： MUKHOPADHYAY, Sudip , JINGJI, Ma , NAIR, Haridasan K. , HSUEHSUNG, Tung
IPC分类号： C07C17/278 , C07C19/08 , C07C21/18
CPC分类号： B01J27/125 , B01J27/10 , B01J27/12 , C07C17/00 , C07C17/278 , C07C21/18 , C07C19/08
摘要： A method for preparing fjuorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.
摘要翻译：制备富含氟的有机化合物的方法，其中至少一种氟化烯烃与气相中的氟甲烷和路易斯酸催化剂存在下反应形成至少一种具有至少3个碳原子的产物。

8. 发明公开

EP1819650A2 DIRECT ONE-STEP SYNTHESIS OF TRIFLUOROMETHYL IODIDE 有权
标题翻译： TRIFLUOROMETHYLIODID一步到位直接合成
公开(公告)号：EP1819650A2
公开(公告)日：2007-08-22
申请号：EP05853437.1
申请日：2005-12-07
申请人： Honeywell International Inc.
发明人： MUKHOPADHAY, Sudip , HSUEHSUNG, Tung
IPC分类号： C07C17/093 , C07C19/16
CPC分类号： C07C19/16 , C07C17/093 , C07C17/361
摘要： A catalytic one-step process for the production of CF3I by reacting, preferably in the presence of a source of oxygen, a source of iodine with a reactant of the formula: CF3R where R is -SH, -S-S-CF3, -S-phenyl, or -S-Si-(CH3)3. The catalyst may be a metal salt such as salts of Cu, Hg, Pt, Pd, Co, Mn, Rh, Ni, V, TI, Ba, Cs, Ca, K and Ge and mixtures thereof, preferably on a support. such as MgO, BaO and CaO, BaCO3, CsNO3, Ba (NO3)2, activated carbon, basic alumina, and ZrO2.

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