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1. 发明公开

EP2818241A1 PROCESSING APPARATUS EQUIPPED WITH CATALYST-SUPPORTING HONEYCOMB STRUCTURE, AND METHOD FOR MANUFACTURING SAME 有权
标题翻译：与催化剂处理设备负载蜂窝结构与方法及其生产
公开(公告)号：EP2818241A1
公开(公告)日：2014-12-31
申请号：EP12869477.5
申请日：2012-12-04
申请人： Hitachi Zosen Corporation
发明人： HIKAZUDANI, Susumu , HINO, Naoe , YAMAMOTO, Seigo , SHIMIZU, Kana
IPC分类号： B01J23/22 , B01D53/94 , B01J23/30 , B01J33/00 , B01J35/04 , F01N3/28
摘要： [Problem] To form a catalyst-supporting honeycomb structure using a commercially available, inexpensive glass fiber paper as a base material. To provide a processing apparatus equipped with a catalyst-supporting honeycomb structure, as well as a method for manufacturing the same, in which the manufacturing cost is low without requiring large-scale equipment such as a dipping tank, a drying device, etc. as conventionally used for a catalyst-supporting honeycomb structure; for example, in an exhaust gas cleaning process or the like, even if a solid content in a gas to be processed clogs in cells of the catalyst-supporting honeycomb structure, this can be easily regenerated; and a lowering of a contact area of the gas to be processed or an increase of a pressure loss can be prevented from occurring.[Solution] In a processing apparatus (10) equipped with a catalyst-supporting honeycomb structure, a corrugated plate-like glass fiber paper (2) having a functional catalyst supported thereon and a flat plate-like glass fiber paper (3) having the same functional catalyst supported thereon are alternately laminated without being bonded to each other, to form a catalyst-supporting honeycomb structure (1), and this catalyst-supporting honeycomb structure (1) is packed in a casing (4).
摘要翻译： [问题]为了使用市售的，廉价的玻璃纤维纸作为基材形成催化剂负载蜂窝结构体。提供一种配备有催化剂负载蜂窝结构体的处理装置，以及用于制造它的方法，其中，制造成本，而不需要大型设备低：例如，浸渍槽，干燥装置等，如常规用于催化剂负载蜂窝结构体; 对于实施例，在上废气净化处理等，即使在气体中的固体含量在催化剂负载蜂窝结构体的细胞加工木屐，这可以容易地再生; 并且降低要被处理或以增加的压力损失的可防止发生的气体的接触面积的。具备催化剂负载蜂窝结构，波纹板状的[方法]在一个处理装置（10）（2）具有功能性催化剂支撑在其上;（3）具有相同的功能性催化剂负载在其上的平板状的玻璃纤维纸玻璃纤维纸交替层叠而不被相互结合，以形成催化剂负载蜂窝结构体（ 1），并且该催化剂负载蜂窝结构体（1）被装在一个壳体（4）。

2. 发明授权

EP2933020B1 PROCESSS FOR PRODUCING A TREATMENT DEVICE EQUIPPED WITH CATALYST-SUPPORTING HONEYCOMB STRUCTURE 有权转让
标题翻译：生产配有催化剂支撑蜂窝结构的处理装置的方法
公开(公告)号：EP2933020B1
公开(公告)日：2017-08-09
申请号：EP13864890.2
申请日：2013-09-24
申请人： Hitachi Zosen Corporation
发明人： YAMAMOTO, Seigo , HIKAZUDANI, Susumu , HINO, Naoe , TUBO, Fumiya , KODAMA, Tetsuo , HIRAIWA, Shunsuke , KOUMARU, Ryoichi
IPC分类号： B01J35/04 , B01D53/86 , B01J23/22 , B05D7/00 , B05D7/24
CPC分类号： F01N3/28 , B01D46/2418 , B01D53/885 , B01J23/22 , B01J35/04 , B01J37/0234 , C04B38/0006 , C04B2111/0081 , F01N3/2066 , F01N2310/02 , F01N2330/101 , Y02T10/24 , Y10T29/49346 , C04B35/46 , C04B35/6316 , C04B38/0083

3. 发明公开

EP2933020A1 TREATMENT DEVICE EQUIPPED WITH CATALYST-SUPPORTING HONEYCOMB STRUCTURE AND PROCESS FOR PRODUCING SAME 有权转让
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER BEHANDLUNGSVORRICHTUNG麻醉师KATALYSATORSTÜTZENDERWABENSTRUKTUR
公开(公告)号：EP2933020A1
公开(公告)日：2015-10-21
申请号：EP13864890.2
申请日：2013-09-24
申请人： Hitachi Zosen Corporation
发明人： YAMAMOTO, Seigo , HIKAZUDANI, Susumu , HINO, Naoe , TUBO, Fumiya , KODAMA, Tetsuo , HIRAIWA, Shunsuke , KOUMARU, Ryoichi
IPC分类号： B01J35/04 , B01D53/86 , B01J23/22 , B05D7/00 , B05D7/24
CPC分类号： F01N3/28 , B01D46/2418 , B01D53/885 , B01J23/22 , B01J35/04 , B01J37/0234 , C04B38/0006 , C04B2111/0081 , F01N3/2066 , F01N2310/02 , F01N2330/101 , Y02T10/24 , Y10T29/49346 , C04B35/46 , C04B35/6316 , C04B38/0083
摘要： [Problem] To provide a treatment device equipped with a catalyst-supporting honeycomb structure, the device being for use in, for example, an exhaust gas purification treatment, hydrogen production by ammonia decomposition or the like, and a method for producing the same. The catalyst-supporting honeycomb structure is produced by forming the inorganic binder-containing functional catalyst-supporting corrugated glass paper without removing an organic binder originally contained in the glass paper and by using the corrugated glass paper in combination with the inorganic binder-containing functional catalyst-supporting flat glass paper. Thus, a production process of the treatment device equipped with a catalyst-supporting honeycomb structure is greatly shortened and the production cost is lowered.
[Solution] In the treatment device equipped with a catalyst-supporting honeycomb structure, a corrugated glass paper having an inorganic binder-containing functional catalyst supported thereon and a flat glass paper having the same inorganic binder-containing functional catalyst supported thereon are alternately stacked to form the catalyst-supporting honeycomb structure (1), and this catalyst-supporting honeycomb structure (1) is packed in a casing (4).
摘要翻译：本发明提供一种配备有催化剂负载蜂窝结构体的处理装置及其制造方法，该装置用于例如废气净化处理，氨分解等的氢产生等。催化剂负载蜂窝结构体是通过在不除去玻璃纸中最初含有的有机粘合剂的基础上形成含有无机粘结剂的功能性催化剂负载型波纹状玻璃纸，通过使用波纹状玻璃纸与无机粘合剂功能催化剂支持平板玻璃纸。因此，具有催化剂负载蜂窝结构体的处理装置的制造工序大大缩短，制造成本降低。 [解决方案]在配备有催化剂负载型蜂窝结构体的处理装置中，载持有无机粘合剂的功能性催化剂的波纹玻璃纸和负载有与其相同的含无机粘合剂的功能性催化剂的平板玻璃纸交替堆叠形成催化剂负载型蜂窝结构体（1），将该催化剂负载蜂窝结构体（1）包装在壳体（4）中。

4. 发明授权

EP2818241B1 METHOD FOR MANUFACTURING PROCESSING APPARATUS EQUIPPED WITH CATALYST-SUPPORTING HONEYCOMB STRUCTURE 有权
公开(公告)号：EP2818241B1
公开(公告)日：2020-01-22
申请号：EP12869477.5
申请日：2012-12-04
申请人： Hitachi Zosen Corporation
发明人： HIKAZUDANI, Susumu , HINO, Naoe , YAMAMOTO, Seigo , SHIMIZU, Kana
IPC分类号： B01J23/22 , B01J23/30 , B01J33/00 , B01J35/04 , F01N3/28 , B32B29/08 , B01D53/86

5. 发明公开

EP3524346A1 CATALYST SUPPORT STRUCTURE AND METHOD FOR MANUFACTURING SAME 无效
公开(公告)号：EP3524346A1
公开(公告)日：2019-08-14
申请号：EP17858495.9
申请日：2017-10-05
申请人： Hitachi Zosen Corporation
发明人： NISHI, Tsugumi , SHONO, Emi , HIKAZUDANI, Susumu , HINO, Naoe
IPC分类号： B01J23/22 , B01D53/86 , B01J23/30 , B01J35/04 , B01J35/06 , B01J37/02
摘要： Provided are a mercury oxidation catalyst support structure with which a mercury oxidation reaction can be carried out while inhibiting the oxidation reaction for SO 2 included in exhaust gas and a method for manufacturing the same. This mercury oxidation catalyst structure is characterized by vanadium being unevenly supported on the surface of the support structure. The method for manufacturing the mercury oxidation catalyst structure includes a step of incorporating an inactive support throughout from the inside to the surface of the structure using an inactive support-containing liquid and a step of immersing the structure having been subjected to the step in a liquid containing vanadium or applying the same liquid to the surface of the same structure, followed by drying and calcinating, thereby supporting vanadium on the inactive support present in the surface of the structure.

6. 发明公开

EP2952255A1 CATALYST FOR DECOMPOSING AMMONIA 无效
标题翻译： KATALYSATOR ZUR ZERSETZUNG VON AMMONIAK
公开(公告)号：EP2952255A1
公开(公告)日：2015-12-09
申请号：EP13873998.2
申请日：2013-10-31
申请人： Hitachi Zosen Corporation
发明人： HIKAZUDANI, Susumu , HINO, Naoe
IPC分类号： B01J27/199 , B01D53/86 , B01J27/198
CPC分类号： B01J27/198 , B01D53/9418 , B01D53/9436 , B01D53/9477 , B01D2251/2062 , B01D2255/2045 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/20792 , B01D2258/012 , B01D2259/4575 , B01J23/30 , B01J35/04 , B01J37/28 , Y02T10/24
摘要： [Problem] Provided is a catalyst for decomposing ammonia, which has stable ammonia decomposition performance even for exhaust gas containing SOx (SO 2 and SO 3 ) at a high concentration caused subsequent to the denitration catalyst system using an ammonia-based reducing agent in a purification treatment of, e.g., exhaust gas from an internal combustion engine, such as a marine diesel engine.
[Solution] A catalyst for decomposing ammonia in exhaust gas has as a catalyst base a denitration catalyst having supported thereon titanium oxide and vanadium oxide, or as a catalyst base a denitration catalyst having supported thereon titanium oxide, vanadium oxide, and tungsten oxide, and further having supported thereon zinc, calcium, and phosphorus as catalytically active components. The exhaust gas is exhaust gas containing ammonia and sulfur oxides from an internal combustion engine, such as a marine diesel engine.
摘要翻译： [问题]提供了一种分解氨的催化剂，即使在使用氨基还原剂的脱硝催化剂体系之后，即使在高浓度下含有SO x（SO 2和SO 3）的废气也具有稳定的氨分解性能净化处理，例如来自诸如船用柴油发动机的内燃机的废气。 [解决方案]废气中分解氨的催化剂具有负载有氧化钛和氧化钒的脱硝催化剂或作为催化剂基体的催化剂基体，其上负载有氧化钛，氧化钒和氧化钨的脱硝催化剂，以及进一步在其上负载有锌，钙和磷作为催化活性成分。废气是含有来自诸如船用柴油发动机的内燃机的氨和硫氧化物的废气。

7. 发明授权

EP2818243B1 END-TREATING METHOD FOR CATALYST-CARRYING HONEYCOMB STRUCTURE IN EXHAUST GAS DENITRATION SYSTEM 失效
公开(公告)号：EP2818243B1
公开(公告)日：2019-02-20
申请号：EP12869182.1
申请日：2012-12-17
申请人： Hitachi Zosen Corporation
发明人： YAMAMOTO, Seigo , HIKAZUDANI, Susumu , HINO, Naoe , SHIMIZU, Kana
IPC分类号： B01J37/02 , B01J21/16 , B01J23/30 , B01J35/04 , B01D53/86 , B01J35/00

8. 发明公开

EP3072585A1 DENITRATION CATALYST AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：脱硝催化剂及其生产方法
公开(公告)号：EP3072585A1
公开(公告)日：2016-09-28
申请号：EP14861599.0
申请日：2014-11-17
申请人： Hitachi Zosen Corporation
发明人： HIKAZUDANI, Susumu , HINO, Naoe , YAMAMOTO, Seigo
IPC分类号： B01J23/30 , B01D53/94 , B01J23/22 , B01J37/02
CPC分类号： B01J23/22 , B01D53/8628 , B01D2251/2062 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/20776 , B01J23/30 , B01J23/92 , B01J35/04 , B01J35/06 , B01J37/0215 , B01J37/0219 , B01J37/0236 , B01J37/08 , B01J38/64 , B01J2523/00 , B01J2523/47 , B01J2523/48 , B01J2523/55 , B01J2523/69 , B01J2523/41
摘要： For a denitration catalyst used for a denitration treatment of a combustion exhaust gas, for example, from a coal-fired boiler or the like, such a denitration catalyst is provided that has a sufficient mechanical strength capable of retaining the catalyst shape, has a better catalyst performance than the ordinary denitration catalyst containing crystals of zirconium oxide, is low in production cost. In the denitration catalyst comprising, as a base material, a honeycomb structure consisting of an inorganic fiber sheet, titania, vanadium oxide and/or tungsten oxide, and a zirconium compound (except for crystalline zirconium dioxide) as a shape-retaining binder are supported on the honeycomb structure.
摘要翻译：对于用于燃烧废气的脱硝处理的脱硝催化剂，例如来自燃煤锅炉等的脱硝催化剂，提供具有能够保持催化剂形状的足够机械强度的脱硝催化剂，具有更好催化剂性能比普通的含氧化锆晶体的脱硝催化剂低，生产成本低。在以由无机纤维片材，二氧化钛，氧化钒和/或氧化钨和作为形状保持粘合剂的锆化合物（结晶性二氧化锆除外）构成的蜂窝结构体作为基材的脱硝催化剂中，在蜂窝结构上。

9. 发明公开

EP2818243A1 END-TREATING METHOD FOR CATALYST-CARRYING HONEYCOMB STRUCTURE IN EXHAUST GAS DENITRATION SYSTEM 失效
标题翻译： EINEM ABGASENTSTICKUNGSSYSTEM的ENDBEHANDLUNGSVERFAHRENFÜRKATALYSATORTRAGENDE WABENSTRUKTUR
公开(公告)号：EP2818243A1
公开(公告)日：2014-12-31
申请号：EP12869182.1
申请日：2012-12-17
申请人： Hitachi Zosen Corporation
发明人： YAMAMOTO, Seigo , HIKAZUDANI, Susumu , HINO, Naoe , SHIMIZU, Kana
IPC分类号： B01J37/02 , B01D53/94 , B01J21/16 , B01J23/30 , B01J35/04
CPC分类号： B01J21/16 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/9022 , B01D2257/404 , B01J23/30 , B01J27/24 , B01J35/0006 , B01J35/04 , B01J37/0215
摘要： [Problem] To provide a method for processing (an) edge(s) of a catalyst-supporting honeycomb structure in an exhaust gas denitration apparatus, the method being capable of filling fine cracks on a surface of the catalyst layer which will become a cause of abrasion of an edge of the catalyst-supporting honeycomb structure by solid particles such as dust particles, coal ashes, etc. in an exhaust gas and sufficiently compensating abrasion resistant strength of the edge of the honeycomb structure. [Solution] In a catalyst-carrying honeycomb structure in an exhaust gas denitration apparatus, a corrugated plate-like inorganic fiber sheet and a flat plate-like inorganic fiber sheet, each supporting thereon a denitration catalyst containing a silica sol, titania particles, and ammonium metavanadate as a whole primary denitration catalyst layer, are alternately laminated. In a method for processing (an) edge(s) of a catalyst-supporting honeycomb structure, at least the edge of gas inlet side among the gas inlet side and the gas outlet side of the denitration catalyst-supporting honeycomb structure having the whole primary denitration catalyst layer is(are) dipped in a denitration catalyst-containing slurry for edge processing composed of a silica sol, titania particles or kaolin particles, and ammonium metatungstate to form (a) coating layer(s) of the denitration catalyst-containing slurry in the edge(s) of the honeycomb structure, and this(these) is(are) dried and then calcinated to form (an) edge secondary denitration catalyst layer(s).
摘要翻译： [问题]为了提供一种在废气脱硝装置中处理（a）催化剂负载蜂窝结构体的边缘的方法，该方法能够在催化剂层的表面上填充细小的裂纹，这将成为原因通过废气中的固体颗粒如灰尘颗粒，灰渣等对催化剂负载的蜂窝结构体的边缘进行磨损，并充分补偿蜂窝结构的边缘的耐磨强度。 [解决方案]在废气脱硝装置中的催化剂载体的蜂窝结构体中，分别在其上负载有含有二氧化硅溶胶，二氧化钛颗粒和二氧化硅颗粒的脱硝催化剂的波纹板状无机纤维片材和平板状无机纤维片材偏钒酸铵作为整个初级脱硝催化剂层交替层压。在催化剂负载型蜂窝结构体的边缘加工方法中，至少具有全部初级的脱硝催化剂负载型蜂窝结构体的气体入口侧和气体出口侧的气体入口侧的边缘将脱硝催化剂层浸渍在由硅溶胶，二氧化钛颗粒或高岭土颗粒和偏钨酸铵组成的用于边缘处理的含脱硝催化剂的浆料中，以形成（a）含脱硝催化剂的浆料的涂层在蜂窝结构的边缘中，并且（这些）被干燥，然后煅烧以形成（一个）边缘二次脱硝催化剂层。

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