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    • 1. 发明公开
    • PHOTOELECTRIC CONVERSION ELEMENT, AND SOLAR BATTERY USING SAME
    • 光电转换元件和使用该元件的太阳能电池
    • EP3319137A1
    • 2018-05-09
    • EP16817752.5
    • 2016-06-17
    • FUJI-FILM Corporation
    • SATOU, HirotakaHANAKI, NaoyukiISE, ToshihiroSHIROKANE, Kenji
    • H01L51/46H01L51/44
    • H01G9/2059H01G9/2027H01G9/2077H01L51/44Y02E10/549
    • Provided is a photoelectric conversion element including a first electrode that includes a photosensitive layer, which includes a light absorbing agent, on a conductive support, and a second electrode that is opposite to the first electrode. The light absorbing agent includes a compound having a perovskite-type crystal structure that includes a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than the element of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X. A hole transport layer, which includes an organic hole transporting material, is provided between the first electrode and the second electrode. The organic hole transporting material has a molecular weight of 6,000 or less and includes halogen, a halogenated alkyl group, or a group represented by R A -X-* (Formula 1). In Formula 1, X represents S, NR B , or O, R A and R B represent a halogenated alkyl group, and * represents a bonding position.
    • 提供一种光电转换元件,其包括:第一电极,其在导电性支撑体上具有包含光吸收剂的感光层;以及第二电极,其与第一电极相对。 光吸收剂包括具有钙钛矿型晶体结构的化合物,所述钙钛矿型晶体结构包括元素周期表第1族元素的阳离子或阳离子有机基团A,第1族元素以外的金属原子M的阳离子 元素周期表和阴离子原子或原子团X的阴离子。在第一电极和第二电极之间提供包含有机空穴传输材料的空穴传输层。 有机空穴输送材料的分子量为6,000以下,并且包括卤素,卤代烷基或由RA-X- *表示的基团(式1)。 式1中,X表示S,NRB或O,RA和RB表示卤代烷基,并且*表示键合位置。