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    • 7. 发明公开
    • TEXTILWEICHMACHENDE ZUSAMMENSETZUNG
    • EP2563889A1
    • 2013-03-06
    • EP11721249.8
    • 2011-04-19
    • Evonik Degussa GmbH
    • KÖHLE, Hans-JürgenKOTTKE, UlrikeWENK, Hans HenningJAKOB, Harald
    • C11D1/62C11D1/835C11D3/20C07C213/00
    • C11D1/835C07C213/06C07C219/06C11D1/62C11D1/667C11D3/001C11D3/0015C11D3/2013C11D3/2079
    • The invention relates to a textile softening composition, comprising, as component A, a tertiary or quaternary ammonia salt of formula (I) or (II): R
      1 R
      2 R
      3 N
      + CH
      2 CHR
      4 OC (=0) R
      5 X
      - (I) R
      1 R
      2 R
      3 N
      + (CH
      2 )
      3 NHC (=0) R
      5 X
      - (II), where R
      1 is hydrogen, methyl, or ethyl, R
      2 and R
      3 independently of each other are C
      1-4 -alkyl or C
      2-4 -hydroxyalkyl, R
      4 is hydrogen or methyl, R
      5 is a linear C
      15-21- alkyl- or -alkenyl radical, and X
      - is a monovalent Anion, and as component B a non-ionic softening agent having only one long-chain hydrocarbon radical bonded to a polar radical having at least one free hydroxy group, wherein fatty alcohol alkoxylate or fatty acid alkoxylate are excepted as component B, demonstrating good softening effect and forming shelf-stable dispersions if the molar ratio of component A to component B is in the range from 2:1 to 1:3, the difference between the average chain length of the long-chain hydrocarbon radicals of components A and B is no greater than 2 carbon atoms, and the hydrocarbon radicals of components A and B comprise on average no greater than 0.5 double bonds per hydrocarbon radical. Such a composition can be produced by converting a fatty acid, a C
      2-6 -diole or C
      3-9 -polyol, and a tertiary alkanol amine or a diamine having tertiary and primary amino groups at a suitable molar ratio while removing water and carrying out subsequent alkylation or protonation.
    • 包含作为组分A的式(I)或(II)的叔胺盐或季铵盐的织物柔软组合物:R1R2R3N + CH2CHR4OC(= O)R5X-(I)R1R2R3N +(CH2)3NHR(= O)R5X-(II )其中R1是氢,甲基或乙基,R2和R3彼此独立地是C1-4烷基或C2-4羟烷基,R4是氢或甲基,R5是直链C15-21烷基或烯基,X是 - 是一价阴离子,并且作为组分B,作为组分B排除了仅具有一个长链烃基与具有至少一个游离羟基的极性基团键合的非离子软化剂,其中排除脂肪醇烷氧基化物或脂肪酸烷氧基化物作为组分B, 如果组分A与组分B的摩尔比在2:1至1:3的范围内,组分A的长链烃基的平均链长与组分A的长链烃基的平均链长与 B是至多2个碳原子和组分A和C的烃基 B在每种情况下平均每个烃基最多0.5个双键。 这样的组合物可以通过使脂肪酸,C 2-6二醇或C 3-9多元醇与叔链烷醇胺或具有叔胺和伯氨基的二胺以合适的摩尔比与水的去除和随后的烷基化反应来制备 或质子化。