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1. 发明公开

EP0432827A1 Improved process for preparing modified poly-(2,6-dimethyl-p-oxyphenylene) 失效
标题翻译： Verbutyles Verfahren zur Herstellung von Poly（2,6-二甲基 - 对 - 氧苯基）。
公开(公告)号：EP0432827A1
公开(公告)日：1991-06-19
申请号：EP90203149.1
申请日：1990-11-29
申请人： SNAM S.p.A. , ENIRICERCHE S.p.A. , AGIP PETROLI S.p.A.
发明人： Pedretti, Ugo , Gandini, Alberto , Roggero, Arnaldo , Sisto, Rafaello , Valentini, Claudio , Assogna, Amalia , Stopponi, Alessandro
IPC分类号： C08G65/48 , B01D71/52
CPC分类号： C08G65/485
摘要： A process for preparing a modified, amorphous poly-(2,6-dimetyl-p-oxyphenylene) (PPO) comprises:

* metallating PPO by a metallating agent, and
* functionalizing such a metallated PPO by the reaction with a trialkylsilyl halide and/or ethylene oxide;
and is characterized in that the reaction of metallation is carried out in an inert liquid vehicle which contains PPO in an at least partially suspended solid form, by operating under metallating conditions and gradually adding said metallating agent to such a suspension, either continuously or as discrete portions.
Dependently on the functionalizing agents used, and on the sequence of addition thereof, the process makes it possible PPO polymers to be obtained, which are modified with trialkyl-silyl, hydroxyethylene and/or ethyleneoxy-trialkyl-silyl functional groups. They are particularly suitable for preparing flat membranes, including asymmetrical membranes, for the separation of gas mixtures.
摘要翻译：制备改性的无定形聚（2,6-二甲基 - 对 - 氧亚苯基）（PPO）的方法包括：通过金属化剂对PPO进行金属化，并通过与三烷基甲硅烷基卤化物和/或乙烯的反应使这种金属化的PPO官能化氧化物; 并且其特征在于金属化的反应在包含至少部分悬浮固体形式的PPO的惰性液体载体中进行，通过在金属化条件下操作并逐渐地将所述金属化剂连续地或者以离散的方式加入到这种悬浮液中部分。依赖于所使用的官能化剂，并且根据其加入顺序，该方法使得可以获得PPO聚合物，其被三烷基 - 甲硅烷基，羟基亚乙基和/或亚乙基氧基 - 三烷基 - 甲硅烷基官能团改性。它们特别适用于制备用于分离气体混合物的平膜，包括不对称膜。

2. 发明公开

EP0521544A1 Hollow fibres of modified poly-(2,6-dimethyl-p-oxy-phenylene) 失效
标题翻译：聚（2,6-二甲基 - 对 - 邻苯二酚）聚合物（Hohlfasern auf der Basis von modifizierten）。
公开(公告)号：EP0521544A1
公开(公告)日：1993-01-07
申请号：EP92201699.3
申请日：1992-06-11
申请人： ENIRICERCHE S.p.A.
发明人： Stopponi, Alessandro , Demofonti, Claudio , Valentini, Claudio , Sisto, Raffaello , Pedretti, Ugo
IPC分类号： C08G65/48 , B01D71/52 , B01D69/08
CPC分类号： B01D71/52 , B01D69/08 , C08G65/485
摘要： A hollow fiber of amorphous, hydroxy-ethylated poly-(2,6-dimethyl-p-oxyphenylene) (PPO-OH) with a glass transition temperature (Tg) of from 180 to 200°C is disclosed, which is formed by a high-density, microporous layer on a macroporous backing, and having an outer diameter comprised within the range of from 450 to 550 µm and an inner diameter comprised within the range of from 250 to 400 µm.
The process for preparing the hollow fibre and the use of said fibre in the processes of separation of gas mixtures are disclosed as well.
摘要翻译：公开了玻璃化转变温度（Tg）为180〜200℃的无定形羟基乙基化聚（2,6-二甲基 - 对亚氧苯基）（PPO-OH））的中空纤维，其由大孔背衬上的高密度，微孔层，外径为450-550μm，内径在250-400μm范围内。还公开了在分离气体混合物的过程中制备中空纤维的方法和所述纤维的用途。

3. 发明授权

EP0202710B1 Zirconium phosphate and method for its preparation 失效
标题翻译：磷酸三钙及其制备方法
公开(公告)号：EP0202710B1
公开(公告)日：1992-02-05
申请号：EP86200806.7
申请日：1986-05-09
申请人： ENIRICERCHE S.p.A.
发明人： Alberti, Giulio , Bartoli, Francesco , Costantino, Umberto , Di Gregorio, Francesco , Valentini, Claudio
IPC分类号： C01B25/37 , B01J39/12 , B01J27/18
CPC分类号： C01B25/372 , B01J39/09 , C07D453/04

4. 发明公开

EP0432826A1 Modified poly-(2,6-dimethyl-p-oxyphenylene), process for preparing it and its use in membranes for separating gas mixtures 失效
标题翻译：改性的聚（2,6-二甲基 - 对 - oxyphenylene），其制备及其作为气体混合物的分离的膜使用过程。
公开(公告)号：EP0432826A1
公开(公告)日：1991-06-19
申请号：EP90203148.3
申请日：1990-11-29
申请人： SNAM S.p.A. , ENIRICERCHE S.p.A. , AGIP PETROLI S.p.A.
发明人： Pedretti, Ugo , Gandini, Alberto , Roggero, Arnaldo , Sisto, Raffaello , Valentini, Claudio , Assogna; Amalia , Farias, Otello
IPC分类号： C08G65/48 , B01D71/52
CPC分类号： C08G65/485 , B01D71/52
摘要： A modified, amorphous poly-(2,6-dimethyl-p-oxyphenylene) (PPO) having a glass transition temperature (Tg) comprised within the range of temperatures of from 170 to 220°C, contains in its macromolecule:

* units functionalized with ethyleneoxy-trialkyl-silyl moieties

* units functionalized with trialkyl-silyl moieties

* units functionalized with hydroxy-ethylene moieties

* together with unaltered 2,6-dimethyl-p-oxymethylene units:

Such a modified PPO is prepared by metallating PPO with a metallating agent and causing such a metallated PPO to react with ethylene oxide and a trialkyl-silyl-halide in the stated sequence.
The use of modified PPO for the preparation of flat, also asymmetrical, membranes, useful in the processes of separation of gas mixtures, is disclosed.
摘要翻译：从170至220℃的温度范围内由改性的无定形聚（2,6-二甲基 - 对 - oxyphenylene），其具有玻璃化转变温度（PPO）（Tg）的，包含在其大分子：与官能化单元搜索：与三烷基甲硅烷基部分单位羟基的亚乙基部分连同未改变的2,6-二甲基 - 对 - 氧亚甲基单元官能化官能化乙烯三烷基甲硅烷基部分单元改性PPO被金属化与金属化试剂PPO以及使得寻求金属迟来PPO到与环氧乙烷和所陈述的序列中的三烷基甲硅烷基卤反应制备。用于制备的扁平的，所以非对称，膜，在气体混合物的分离过程是有用的，使用改性PPO的是游离缺失盘。

5. 发明公开

EP0202710A2 Zirconium phosphate and method for its preparation 失效
标题翻译： Zirkon磷酸盐母猪Verfahren zu dessen Herstellung。
公开(公告)号：EP0202710A2
公开(公告)日：1986-11-26
申请号：EP86200806.7
申请日：1986-05-09
申请人： ENIRICERCHE S.p.A.
发明人： Alberti, Giulio , Bartoli, Francesco , Costantino, Umberto , Di Gregorio, Francesco , Valentini, Claudio
IPC分类号： C01B25/37 , B01J39/12 , B01J27/18
CPC分类号： C01B25/372 , B01J39/09 , C07D453/04
摘要： The invention relates to a zirconium phosphate in particles having sizes comprised within the range of from 1 to 100 µm, a lamellar structure with interlayer distance, in the anhydrous state, comprised within the range of from 7.9 to 8.2 A and a , surface area comprised within the range of from 9 to 20 m2/ g.
The method consists in altering the lamellar structure of a zirconium phosphate with layer structure of alpha type by intercalating into it an organic substance containing a proton-acceptor group and water and by a treatment with ultrasounds, in regenerating the hydrogen form of said zirconium phosphate by an acid and in washing the same with diluted acids and/or water.
摘要翻译：本发明涉及一种粒径在1至100μm范围内的颗粒状磷酸锆，层间距离为无水状态的层状结构在7.9至8.2之间的范围内，包括表面积在9至20m2 / g的范围内。该方法包括通过将含有质子 - 受体基团和水的有机物质插入其中的α型层结构来改变磷酸锆的层状结构，并且通过用超声波处理，通过以下步骤再生氢形式的所述磷酸锆：酸，并用稀酸和/或水洗涤。

6. 发明公开

EP0408125A1 Modified poly(2,6-dimethyl-p-oxyphenylene), a process for its preparation and its use in gas mixture separation membranes 失效
标题翻译：改性聚（2,6-二甲基对氧苯基），Verfahren zu dessen Herstellung und Verwendung als Gastrennungsmembran。
公开(公告)号：EP0408125A1
公开(公告)日：1991-01-16
申请号：EP90201805.0
申请日：1990-07-05
申请人： ENIRICERCHE S.p.A. , SNAM S.p.A. , AGIP PETROLI S.p.A.
发明人： Assogna, Amalia , Gandini, Alberto , Roggero, Arnaldo , Sisto, Raffaello , Stopponi, Alessandro , Valentini, Claudio
IPC分类号： C08G65/48 , B01D71/52
CPC分类号： B01D71/52 , C08G65/485
摘要： An amorphous modified poly(2,6-dimethyl-p-oxyphenylene) (PPO) is described with a glass transition temperature (Tg) within the range of 170-220°C, of which the macromolecules contain units having trialkylsilyl groups bonded to the nucleus and/or to the methyl:
together with units having hydroxyethyl groups bonded to the nucleus and/or to the methyl:

This modified PPO is prepared by metalating PPO with a metalating agent and reacting the formed metalated PPO with a trialkylsilyl halide and with ethylene oxide in succession.
The use of the thus modified PPO for the preparation of flat, including asymmetric, membranes useful in gas mixture separation processes is described.
摘要翻译：描述了玻璃化转变温度（Tg）在170-220℃范围内的无定形改性聚（2,6-二甲基对氧亚苯基）（PPO），其中大分子含有具有三烷基甲硅烷基的单元与核和/或甲基：与具有与核结合的羟乙基的单元和/或与甲基结合的单元：＆lt; CHEM＆gt;该改性PPO通过用金属化剂金属化PPO并使形成的金属化PPO与三烷基甲硅烷基卤化物和环氧乙烷。描述了如此改性的PPO用于制备平坦的，包括用于气体混合物分离过程的不对称膜的膜。

7. 发明公开

EP0360318A1 Modified poly(2,6-dimethyl-p-oxyphenylene),a process for its preparation and its use in gas-separation membranes 失效
标题翻译：改性聚（2,6-二甲基对氧苯基），Verfahren zu dessen Herstellung und Verwendung als Gastrennungsmembran。
公开(公告)号：EP0360318A1
公开(公告)日：1990-03-28
申请号：EP89202195.7
申请日：1989-08-31
申请人： ENIRICERCHE S.p.A.
发明人： Farias, Otello , Gandini, Alberto , Monga, Raffaella , Roggero, Arnaldo , Sisto, Raffaello , Valentini, Claudio
IPC分类号： C08G65/48 , B01D71/52
CPC分类号： C08G65/485 , B01D71/52
摘要： A modified poly(2,6-dimethyl-p-oxyphenylene) with a glass transition temperature in the range of 180-220°C is described in which on the average between 10 and 60% of the macromolecules carry:

Said modified poly(2,6-dimethyl-p-oxyphenylene) is useful as a material in the preparation of flat membranes, in particular asymmetric membrane, for gas separation.
摘要翻译：描述了玻璃化转变温度在180-220℃范围内的改性聚（2,6-二甲基 - 对 - 氧亚苯基），其中平均10-60％的大分子携带：所述改性聚（2,6-二甲基 - 对 - 氧亚苯基）可用作制备用于气体分离的平膜，特别是不对称膜的材料。

8. 发明公开

EP0202710A3 Zirconium phosphate and method for its preparation 失效
标题翻译：磷酸三苯酯及其制备方法
公开(公告)号：EP0202710A3
公开(公告)日：1988-03-02
申请号：EP86200806
申请日：1986-05-09
申请人： ENIRICERCHE S.p.A.
发明人： Alberti, Giulio , Bartoli, Francesco , Costantino, Umberto , Di Gregorio, Francesco , Valentini, Claudio
IPC分类号： C01B25/37 , B01J39/12 , B01J27/18
CPC分类号： C01B25/372 , B01J39/09 , C07D453/04
摘要： The invention relates to a zirconium phosphate in particles having sizes comprised within the range of from 1 to 100 µm, a lamellar structure with interlayer distance, in the anhydrous state, comprised within the range of from 7.9 to 8.2 A and a , surface area comprised within the range of from 9 to 20 m2/ g. The method consists in altering the lamellar structure of a zirconium phosphate with layer structure of alpha type by intercalating into it an organic substance containing a proton-acceptor group and water and by a treatment with ultrasounds, in regenerating the hydrogen form of said zirconium phosphate by an acid and in washing the same with diluted acids and/or water.
摘要翻译：本发明涉及一种粒径在1至100μm范围内的颗粒状磷酸锆，层间距离为无水状态的层状结构在7.9至8.2之间的范围内，包括表面积在9至20m2 / g的范围内。该方法包括通过将含有质子 - 受体基团和水的有机物质插入其中的α型层结构来改变磷酸锆的层状结构，并且通过用超声波处理，通过以下步骤再生氢形式的所述磷酸锆：酸，并用稀酸和/或水洗涤。

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