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1. 发明公开

EP1701372A3 Black electrodes and methods of forming them 审中-公开
标题翻译：黑色电极和它们的制备方法
公开(公告)号：EP1701372A3
公开(公告)日：2008-12-03
申请号：EP06251262.9
申请日：2006-03-09
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Barker, Michael, F. , Matsuno, Hisashi , Hayakawa, Keiichiro
IPC分类号： H01J9/02 , H01J17/49
CPC分类号： H01J9/02 , C03C8/14 , C03C8/16 , C03C8/18 , C03C8/22 , C03C17/04 , H01J2211/225
摘要： The present invention provides a method for forming a black electrode by performing sintering at a temperature in the range of 500-600°C after applying a lead-free black conductive composition to a substrate. The aforementioned black electrode comprises a binder comprising a crystallized glass component. The aforementioned black conductive composition comprises conductive particles of black RuO 2 , lead-free black ruthenium-based polyoxide, and mixtures thereof in an amount of 4-30 wt%, based on the total weight of the composition, a lead-free non-conductive black oxide in an amount of 0-30 wt%, based on the total weight of the composition, and a lead-free bismuth-based glass binder in an amount of 10-50 wt%, based on the total weight of the composition.

2. 发明公开

EP0548865A2 Thick film resistor composition 失效
标题翻译： ZusammensetzungfürDickschicht-Widerstand。
公开(公告)号：EP0548865A2
公开(公告)日：1993-06-30
申请号：EP92121673.5
申请日：1992-12-19
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Borland, William , Hayakawa, Keiichiro , Matsuno, Hisashi , Sato, Takeshi , Smith, Jerome David
IPC分类号： H01C17/06 , H01B1/08 , H01B1/14
CPC分类号： H01C17/0658 , C03C3/07 , C03C3/072 , C03C3/074 , C03C3/091 , C03C3/093 , C03C3/108 , C03C8/10 , C03C8/12 , C03C8/14 , C03C8/22 , H01C17/0654
摘要： To provide a thick film resistor composition which gives a small length effect on the TCR and also small variations in the resistance values and the TCR on firing the overcoat glass.
A thick film resistor composition comprising an electrically conducting component, ruthenium oxide and/or glass binder comprising a mixture of a first glass comprising 30-60% by weight of SiO₂, 5-30% by weight of CaO, 1-40% by weight of B₂O₃, 0-50% by weight of PbO and 0-20% by weight of Al₂O₃ in which the total of SiO₂, CaO, B₂O₃, PbO and Al₂O₃ amounts to at least 95% by weight thereof; and a second glass comprising a PbO-SiO₂ type glass with the PbO amounting to at least 50% by weight thereof, wherein the ratio of said electrically conducting component of said thick film resistor composition is 10-50% by weight, that of the first glass is 5-35% by weight and that of the second glass is 5-40% by weight.
摘要翻译：提供一种对TCR具有小长度效应的厚膜电阻器组合物，以及在烧制该外涂层玻璃时电阻值和TCR的小变化。一种厚膜电阻组合物，其包含导电组分，氧化钌和/或玻璃粘合剂，其包含第一玻璃的混合物，所述第一玻璃包含30-60重量％的SiO 2，5-30重量％的CaO，1-40重量％的B 2 O 3，0-50重量％的PbO和0〜20重量％的Al 2 O 3，其中SiO 2，CaO，B 2 O 3，PbO和Al 2 O 3的总量为至少95重量％以及包含PbO的PbO-SiO 2型玻璃的至少50重量％的第二玻璃，其中所述厚膜电阻组合物的所述导电组分的比例为10-50重量％玻璃为5-35重量％，第二玻璃为5-40重量％。

3. 发明公开

EP1701211A2 Black conductive thick film compositons, electrodes, and methods of forming thereof 审中-公开
标题翻译： SchwarzeleitfähigeDickfilmzusammensetzungen，Elektroden und Verfahren zu deren Herstellung
公开(公告)号：EP1701211A2
公开(公告)日：2006-09-13
申请号：EP06251261.1
申请日：2006-03-09
申请人： E.I. du Pont de Nemours and Company
发明人： Barker, Michael F. , Hayakawa, Keiichiro , Noda, Hiroaki , Matsuno, Hisashi
IPC分类号： G03F7/004
CPC分类号： H01J9/02 , C03C3/064 , C03C3/066 , C03C3/072 , C03C3/074 , C03C3/122 , C03C8/04 , C03C8/10 , C03C8/14 , C03C8/18 , C03C8/22 , C03C17/008 , C03C17/3405 , C03C2217/452 , C03C2217/475 , C03C2217/479 , C03C2217/48 , C03C2217/485 , G03F7/0047 , H01B1/16 , H01B1/22 , H01J17/04 , H01J2211/225
摘要： This invention is directed to black conductive compositions, black electrodes made from such compositions and methods of forming such electrodes.
摘要翻译：本发明涉及黑色导电组合物，由这种组合物制成的黑色电极和形成这种电极的方法。根据本发明的黑色导电组合物基于总组合物的重量包含3-50重量％的选自RuO 2，钌聚氧化物及其混合物的导电金属氧化物颗粒; 25-85重量％有机物质，包括有机聚合物粘合剂和有机溶剂; 和5-70重量％的一种或多种无铅铋玻璃粘合剂，其中所述玻璃粘合剂包含基于玻璃粘合剂的总重量：55-85％Bi 2 O 3，0-20％SiO 2，0- 5％Al 2 O 3，2-20％B 2 O 3，0-20％ZnO，0-15％的一种或多种选自BaO，CaO和SrO的氧化物; 和0-3％的一种或多种选自Na 2 O，K 2 O，Cs 2 O，Li 2 O的氧化物及其混合物; 并且其中所述玻璃粘合剂的软化点在400-600℃的范围内; 并且其中所述组合物是无铅或基本无铅的。

4. 发明公开

EP0548865A3 Thick film resistor composition 失效
标题翻译：厚膜电阻器组成
公开(公告)号：EP0548865A3
公开(公告)日：1994-02-09
申请号：EP92121673.5
申请日：1992-12-19
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Borland, William , Hayakawa, Keiichiro , Matsuno, Hisashi , Sato, Takeshi , Smith, Jerome David
IPC分类号： H01C17/06 , H01B1/08 , H01B1/14
CPC分类号： H01C17/0658 , C03C3/07 , C03C3/072 , C03C3/074 , C03C3/091 , C03C3/093 , C03C3/108 , C03C8/10 , C03C8/12 , C03C8/14 , C03C8/22 , H01C17/0654
摘要： To provide a thick film resistor composition which gives a small length effect on the TCR and also small variations in the resistance values and the TCR on firing the overcoat glass. A thick film resistor composition comprising an electrically conducting component, ruthenium oxide and/or glass binder comprising a mixture of a first glass comprising 30-60% by weight of SiO₂, 5-30% by weight of CaO, 1-40% by weight of B₂O₃, 0-50% by weight of PbO and 0-20% by weight of Al₂O₃ in which the total of SiO₂, CaO, B₂O₃, PbO and Al₂O₃ amounts to at least 95% by weight thereof; and a second glass comprising a PbO-SiO₂ type glass with the PbO amounting to at least 50% by weight thereof, wherein the ratio of said electrically conducting component of said thick film resistor composition is 10-50% by weight, that of the first glass is 5-35% by weight and that of the second glass is 5-40% by weight.
摘要翻译：为了提供对TCR具有小长度效应的厚膜电阻器组合物，以及在对保护层玻璃进行焙烧时电阻值和TCR的小变化。包含导电组分，氧化钌和/或玻璃粘合剂的厚膜电阻组合物，其包含第一种玻璃和第二种玻璃的混合物，所述第一种玻璃包含30-60重量％的SiO 2，5-30重量％的CaO，1-40重量％的B 2 O 3，0-50％重量的PbO和0-20％重量的Al 2 O 3，其中SiO 2，CaO，B 2 O 3，PbO和Al 2 O 3的总量占其重量的至少95％以及第二种玻璃，该第二种玻璃包含PbO-SiO 2型玻璃，PbO的含量至少为50重量％，其中所述厚膜电阻组合物的所述导电成分的比例为10-50重量％，第一玻璃玻璃是5-35重量％，第二玻璃的重量是5-40重量％。

5. 发明公开

EP1701211A3 Black conductive thick film compositons, electrodes, and methods of forming thereof 审中-公开
标题翻译：黑色导电厚膜组合物，电极和它们的制备方法
公开(公告)号：EP1701211A3
公开(公告)日：2008-12-10
申请号：EP06251261.1
申请日：2006-03-09
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Barker, Michael F. , Hayakawa, Keiichiro , Noda, Hiroaki , Matsuno, Hisashi
IPC分类号： H01J9/02 , H01J17/49 , G03F7/004
CPC分类号： H01J9/02 , C03C3/064 , C03C3/066 , C03C3/072 , C03C3/074 , C03C3/122 , C03C8/04 , C03C8/10 , C03C8/14 , C03C8/18 , C03C8/22 , C03C17/008 , C03C17/3405 , C03C2217/452 , C03C2217/475 , C03C2217/479 , C03C2217/48 , C03C2217/485 , G03F7/0047 , H01B1/16 , H01B1/22 , H01J17/04 , H01J2211/225
摘要： This invention is directed to black conductive compositions, black electrodes made from such compositions and methods of forming such electrodes. The black conductive compositions according to the invention comprise, based on the weight of the total composition:
3-50 weight percent of conductive metal oxide particles selected from RuO 2 , ruthenium polyoxide, and mixtures thereof;
25-85 weight percent organic matter comprising organic polymer binder and organic solvent; and
5-70 weight percent of one or more lead-free bismuth glass binders wherein said glass binder comprises, based on the total weight of the glass binder: 55-85% Bi 2 O 3 , 0-20% SiO 2 , 0-5% Al 2 O 3 , 2-20% B 2 O 3 , 0-20% ZnO, 0-15% of one or more of oxides selected from BaO, CaO, and SrO; and 0-3% of one or more of oxides selected from Na 2 O, K 2 O, Cs 2 O, Li 2 O and mixtures thereof; and
wherein the softening point of said glass binder is in the range 400- 600°C; and
wherein said composition is lead-free or substantially lead-free.

6. 发明公开

EP1701372A2 Black electrodes and methods of forming them 审中-公开
标题翻译： Schwarze Elektroden und deren Herstellungsverfahren
公开(公告)号：EP1701372A2
公开(公告)日：2006-09-13
申请号：EP06251262.9
申请日：2006-03-09
申请人： E.I. du Pont de Nemours and Company
发明人： Barker, Michael, F. , Matsuno, Hisashi , Hayakawa, Keiichiro
IPC分类号： H01J9/02
CPC分类号： H01J9/02 , C03C8/14 , C03C8/16 , C03C8/18 , C03C8/22 , C03C17/04 , H01J2211/225
摘要： The present invention provides a method for forming a black electrode by performing sintering at a temperature in the range of 500-600°C after applying a lead-free black conductive composition to a substrate. The aforementioned black electrode comprises a binder comprising a crystallized glass component. The aforementioned black conductive composition comprises conductive particles of black RuO 2 , lead-free black ruthenium-based polyoxide, and mixtures thereof in an amount of 4-30 wt%, based on the total weight of the composition, a lead-free non-conductive black oxide in an amount of 0-30 wt%, based on the total weight of the composition, and a lead-free bismuth-based glass binder in an amount of 10-50 wt%, based on the total weight of the composition.
摘要翻译：本发明提供一种通过在将无铅黑色导电组合物施加到基板上之后在500-600℃的温度下进行烧结来形成黑色电极的方法。上述黑色电极包括含有结晶化玻璃成分的粘合剂。上述黑色导电组合物包含基于组合物总重量的4-30重量％的黑色RuO 2，无铅黑色钌基聚氧化物及其混合物的导电颗粒，基于组合物的总重量，0-30重量％的导电黑色氧化物和基于组合物总重量的10-50重量％的无铅铋基玻璃粘合剂。

7. 发明授权

EP0548865B1 Thick film resistor composition 失效
标题翻译：组合物为厚膜电阻。
公开(公告)号：EP0548865B1
公开(公告)日：1995-10-18
申请号：EP92121673.5
申请日：1992-12-19
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Borland, William , Hayakawa, Keiichiro , Matsuno, Hisashi , Sato, Takeshi , Smith, Jerome David
IPC分类号： H01C17/06 , H01B1/08 , H01B1/14
CPC分类号： H01C17/0658 , C03C3/07 , C03C3/072 , C03C3/074 , C03C3/091 , C03C3/093 , C03C3/108 , C03C8/10 , C03C8/12 , C03C8/14 , C03C8/22 , H01C17/0654

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