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    • 1. 发明公开
    • ETHYLENE-BASED POLYMERS AND PROCESSES TO MAKE THE SAME
    • 乙烯基聚合物VERFAHREN ZUR HERSTELLUNG DAVON
    • EP2900704A1
    • 2015-08-05
    • EP13716496.8
    • 2013-03-13
    • Dow Global Technologies LLC
    • KARJALA, Teresa P.KARDOS, Lori L.YAU, Wallace W.ORTEGA, JoseVIGIL, Alfred E.
    • C08F10/02
    • An ethylene-based polymer, which is a low density polyethylene (LDPE), obtained by free radical polymerization of ethylene, and wherein the LDPE has a GPC parameter “LSP” less than 1.60. An ethylene-based polymer that comprises the following features: a) at least 0.1 amyl groups per 1000 total carbon atoms; b) a melt index of 0.01 to 0.3; c) a z-average molecular weight of Mz (conv.) of greater than 350,000 g/mol and less than 425,000 g/mol; d) a gpcBR value from 1.50 to 2.05, and e) a MWD(conv) [Mw(conv)/Mn(conv)] from 6 to 9. An ethylene-based polymer that comprises the following features: a) at least 0.1 amyl groups per 1000 total carbon atoms; b) a melt viscosity ratio (V0.1/V100), at 190° C., greater than, or equal to, 58; c) a melt viscosity at 0.1 rad/s, 190° C., greater than, or equal to, 40,000 Pa·s, and d) a gpcBR value from 1.50 to 2.25.
    • 通过乙烯的自由基聚合获得的低密度聚乙烯(LDPE)的乙烯类聚合物,其中LDPE具有小于1.60的GPC参数“LSP”。 一种乙烯基聚合物,其包含以下特征:a)每1000个总碳原子至少0.1个戊基; b)熔体指数为0.01〜0.3; c)Mz(转化)的Z-平均分子量大于350,000g / mol且小于425,000g / mol; d)gpcBR值为1.50至2.05,e)MWD(conv)[Mw(conv)/ Mn(conv)]为6至9.一种乙烯基聚合物,其包含以下特征:a)至少0.1 每1000个总碳原子的戊基; b)熔体粘度比(V0.1 / V100),在190℃,大于或等于58; c)0.1rad / s,190℃,大于或等于40,000Pa·s的熔体粘度,和d)gpcBR值为1.50-2.25。