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    • 2. 发明公开
    • ETHYLENE-BASED POLYMERS AND PROCESSES TO MAKE THE SAME
    • 乙烯基聚合物VERFAHREN ZUR HERSTELLUNG DAVON
    • EP2900704A1
    • 2015-08-05
    • EP13716496.8
    • 2013-03-13
    • Dow Global Technologies LLC
    • KARJALA, Teresa P.KARDOS, Lori L.YAU, Wallace W.ORTEGA, JoseVIGIL, Alfred E.
    • C08F10/02
    • An ethylene-based polymer, which is a low density polyethylene (LDPE), obtained by free radical polymerization of ethylene, and wherein the LDPE has a GPC parameter “LSP” less than 1.60. An ethylene-based polymer that comprises the following features: a) at least 0.1 amyl groups per 1000 total carbon atoms; b) a melt index of 0.01 to 0.3; c) a z-average molecular weight of Mz (conv.) of greater than 350,000 g/mol and less than 425,000 g/mol; d) a gpcBR value from 1.50 to 2.05, and e) a MWD(conv) [Mw(conv)/Mn(conv)] from 6 to 9. An ethylene-based polymer that comprises the following features: a) at least 0.1 amyl groups per 1000 total carbon atoms; b) a melt viscosity ratio (V0.1/V100), at 190° C., greater than, or equal to, 58; c) a melt viscosity at 0.1 rad/s, 190° C., greater than, or equal to, 40,000 Pa·s, and d) a gpcBR value from 1.50 to 2.25.
    • 通过乙烯的自由基聚合获得的低密度聚乙烯(LDPE)的乙烯类聚合物,其中LDPE具有小于1.60的GPC参数“LSP”。 一种乙烯基聚合物,其包含以下特征:a)每1000个总碳原子至少0.1个戊基; b)熔体指数为0.01〜0.3; c)Mz(转化)的Z-平均分子量大于350,000g / mol且小于425,000g / mol; d)gpcBR值为1.50至2.05,e)MWD(conv)[Mw(conv)/ Mn(conv)]为6至9.一种乙烯基聚合物,其包含以下特征:a)至少0.1 每1000个总碳原子的戊基; b)熔体粘度比(V0.1 / V100),在190℃,大于或等于58; c)0.1rad / s,190℃,大于或等于40,000Pa·s的熔体粘度,和d)gpcBR值为1.50-2.25。
    • 3. 发明公开
    • LDPE FOR USE AS A BLEND COMPONENT IN SHRINKAGE FILM APPLICATIONS
    • LDPE ZUR VERWENDUNG ALS MISCHBESTANDTEILFÜRSCHRUMPFFOLIENANWENDUNGEN
    • EP2464672A1
    • 2012-06-20
    • EP10740819.7
    • 2010-08-04
    • Dow Global Technologies LLC
    • KARJALA, Teresa, P.TICE, Colleen, M.KARDOS, Lori, L.ORTEGA, JoseYAU, Wallace, W.WANG, Jian
    • C08F10/02C08L23/04C08J5/18
    • An ethylene-based polymer characterized as having a density from about 0.9 to about 0.94 grams per cubic centimeter, a molecular weight distribution (Mw/Mn) from about 4 to about 10, a melt index (I2) from about 0.05 to about 2 grams per 10 minutes, a gpcBR value greater than 0.05 as determined by a gpcBR Branching Index and a Y value greater than 0.4 is disclosed. This ethylene-based polymer is especially useful for blending with other polymers such as LLDPE. When converting the blends into film, especially shrink film, the film shows good optics, good shrink tension, high stiffness, high tensile modulus, and tensile strength. When this resin is blended at with a LLDPE on a blown film line, improvements are seen in haze, gloss, clarity, and MD and CD tear as compared to a comparative LDPE.
    • 特征在于具有约0.9至约0.94克/立方厘米的密度,约4至约10的分子量分布(Mw / Mn),约0.05至约2克的熔体指数(I 2) 每10分钟,公开了通过gpcBR分支指数测定的大于0.05的gpcBR值和大于0.4的Y值。 该乙烯类聚合物特别适用于与其它聚合物如LLDPE共混。 当将共混物转化成膜,特别是收缩膜时,该膜显示出良好的光学性能,良好的收缩张力,高刚度,高拉伸模量和拉伸强度。 当将该树脂与吹塑薄膜生产线上的LLDPE共混时,与比较的LDPE相比,在雾度,光泽,透明度以及MD和CD撕裂方面都有改善。