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    • 2. 发明公开
    • PROCESS FOR THE PREPARATION OF CYCLOHEXANONE OXIME
    • 制备环己酮肟的方法
    • EP1299353A1
    • 2003-04-09
    • EP01938833.9
    • 2001-05-31
    • DSM N.V.
    • BLAAUW, MarcSIMONS, Antonius, Jacobus, FranciscusOEVERING, Henk
    • C07C251/44C07C249/08
    • C01B21/1418C07C249/08C07C2601/14C07C251/44
    • The invention relates to a process for the production of cyclohexanone oxime in which a phosphate-containing aqueous reaction medium is cycled from a hydroxylammonium synthesis zone to a cyclohexanone oxime synthesis zone and back to the hydroxylammonium synthesis zone, in which hydroxylammonium synthesis zone hydroxylammonium is formed by catalytic reduction of nitrate with hydrogen, and in which cyclohexanone oxime synthesis zone hydroxylammonium is reacted with cyclohexanone to form xyclohexanone oxime, the cyclohexanone and an organic solvent being fed into the cyclohexanone oxime synthesis zone, an organic medium comprising the organic solvent and cyclohexanone oxime being withdrawn from the cyclohexanone oxime synthesis zone, charaterized in that the ratio fh/fc
    • 本发明涉及一种生产环己酮肟的方法,其中将含磷酸盐的含水反应介质从羟基铵合成区循环到环己酮肟合成区并返回到羟铵合成区,其中形成羟铵合成区羟基铵 通过用氢将硝酸盐催化还原,并且其中将环己酮肟合成区羟胺与环己酮反应形成环己酮肟,将环己酮和有机溶剂加入到环己酮肟合成区中,将包含有机溶剂和环己酮肟的有机介质 从环己酮肟合成区取出,其特征在于比值fh / fc <1.00,其中fh表示每单位时间供入环己酮肟合成区的羟铵的摩尔量(摩尔/秒),fc表示摩尔量 加入到环己酮中的环己酮的量 肟合成区每单位时间(摩尔/秒)。