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    • 6. 发明公开
    • ELECTROCHEMICAL DEVICE AND NONAQUEOUS ELECTROLYTE SOLUTION FOR ELECTROCHEMICAL DEVICE
    • 电化学设备和非水电解质溶液的电化学设备
    • EP2693557A1
    • 2014-02-05
    • EP12764813.7
    • 2012-03-30
    • Daikin Industries, Ltd.
    • SAKATA, HideoKOH , MeitenYAMAUCHI , AkiyoshiNAKAZAWA , HitomiSANAGI ,TomoyoNAKAZONO , AoiADACHI, YukiSAWAKI, KyouheiTANI AkinoriTOMITA, MasahiroTAEDA , Mayuko
    • H01M10/0569H01G9/038H01M10/052H01M10/0567H01M10/0568
    • H01M10/0525H01G11/54H01M10/052H01M10/0567H01M10/0568H01M10/0569Y02E60/122Y02E60/13
    • The present invention aims to provide an electrochemical device excellent in high temperature storage characteristics and cycling characteristics at high voltages, and a nonaqueous electrolyte for the electrochemical device. The present invention relates to an electrochemical device including: a positive electrode; a negative electrode; and a nonaqueous electrolyte containing a nonaqueous solvent and an electrolyte salt, wherein the nonaqueous solvent contains a fluorinated linear carbonate represented by the formula (1):

              RfOCOOR     (1)

      (wherein Rf represents a C1-4 fluorinated alkyl group and R represents a C1-4 alkyl group), and further contains following compounds of (I) to (III) in a total amount of not more than 5000 ppm relative to the fluorinated linear carbonate: (I) a compound represented by the formula (2)

              RfOH     (2)

      (wherein Rf is defined as above); (II) a compound represented by the formula (3)

              ROH     (3)

      (wherein R is defined as above); and (III) a compound represented by the formula (4)

              ROCOCl     (4)

      (wherein R is defined as above).
    • 本发明旨在提供一种在高温下的储存特性的电化学装置和优良在高电压循环特性,以及用于电化学装置中的非水电解质。 本发明涉及在电化学装置,包括:一个正电极; 负电极; 和非水电解质含有非水溶剂的电解质盐,worin非水溶剂包含由下式表示的氟化的直链碳​​酸酯和(1):€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRfOCOOR€ƒ€ƒ €ƒ€ƒ€ƒ(1)(worin RF darstellt一个C 1-4氟代烷基和R darstellt C 1-4烷基),和进一步包含以下至(I)的化合物(III)在不总量 大于5000ppm相对于氟化的直链碳​​酸酯:(I)由式(2)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRfOH€ƒ€ƒ€ƒ€ƒ€ƒ(表示的化合物 2)(式中,Rf的定义如上); (II)由下式表示的化合物(3)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒROH€ƒ€ƒ€ƒ€ƒ€ƒ(3)(worin R定义如上); 和(III)由下式表示的化合物(4)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒROCOCl€ƒ€ƒ€ƒ€ƒ€ƒ(4)(worin R定义如上) ,