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    • 4. 发明公开
    • ELECTRIC DOUBLE-LAYER CAPACITOR AND NON-AQUEOUS ELECTROLYTE FOR ELECTRIC DOUBLE-LAYER CAPACITOR
    • 双电层电容器和非水电解质双电层电容器
    • EP2693455A1
    • 2014-02-05
    • EP12763500.1
    • 2012-03-29
    • Daikin Industries, Ltd.
    • TAKAHASHI, KenzouKOH, MeitenSAKATA, HideoYAMAMOTO, Emi
    • H01G9/038C07C31/38C07C43/17
    • H01G11/60H01G11/54Y02E60/13
    • Provided is an electric double-layer capacitor excellent in long-term reliability, particularly in suppressing its expansion, and a non-aqueous electrolytic solution for the electric double-layer capacitor. The present invention relates to an electric double-layer capacitor, comprising: a positive electrode; a negative electrode; and a non-aqueous electrolytic solution that includes a non-aqueous solvent and an electrolyte salt, the non-aqueous solvent including: a fluorine-containing ether; a fluorine-containing unsaturated compound (I); and a hydroxyl group-containing compound (II), the fluorine-containing ether being represented by the formula (1):

              Rf 1 -O-Rf 2      (1)

      wherein Rf 1 and Rf 2 are the same as or different from each other, and are each a C1-C10 alkyl group or a C1-C10 fluoro-alkyl group, provided that at least one of Rf 1 and Rf 2 is a fluoro-alkyl group, the hydroxyl group-containing compound (II) being represented by the formula (2):

              Rf 1 OH     (2)

      wherein Rf 1 is as defined above, the total amount of the compounds (I) and (II) being 5,000 ppm or less based on the amount of the fluorine-containing ether.
    • 本发明提供一种双电层电容器具有优良的长期可靠性,特别是在抑制其膨胀,并为双电层电容器的非水电解液。 本发明涉及到双电层电容器,包括:正极; 负电极; 和非水电解液没有包括非水溶剂和电解质在盐,非水溶剂包括:含氟醚; 含氟的不饱和化合物(I); €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRf1 -O-RF 2€ƒ€:和含羟基的化合物(II),所述含氟醚由式(1)表示 ƒ€ƒ€ƒ€ƒ(1)式中,Rf 1和Rf 2相同或不同彼此,且各自为C1-C10烷基或C1-C10氟代烷基,确实提供了至少一个 Rf 1和Rf 2是氟代烷基时,作为含羟基的化合物(II)由式(2)所代表:€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRf1 OH€ ƒ€ƒ€ƒ€ƒ€ƒ(2)worin中,Rf 1是如上面所定义,所述化合物的(I)和(II)为5000ppm以下基于该含氟醚的量的总量。