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    • 8. 发明授权
    • PROCESS FOR PREPARING 1,1,1,3,3-PENTAFLUOROPROPANE
    • 制备1,1,1,3,3-五氟丙烷的方法
    • EP0812814B1
    • 2001-12-12
    • EP96901967.8
    • 1996-02-08
    • DAIKIN INDUSTRIES, LTD.
    • AOYAMA, HirokazuSHIBATA, NoriakiYAMAMOTO, Akinori
    • C07C19/08C07C17/23C07B61/00B01J23/44C07C17/38
    • C07C19/08C07C17/23
    • A process for preparing 1,1,1,3,3-pentafluoropropane comprising the step (A) of reducing 2,3-dichloro-1,1,1,3,3-pentafluoropropane with hydrogen in the presence of a hydrogenation catalyst under an atmospheric or elevated pressure by a vapor-phase reaction, the step (B) of introducing all of the products of the step (A) into a condenser to obtain a non-condensed component comprising hydrogen and hydrogen chloride and a condensed component comprising 1,1,1,3,3-pentafluoropropane or a non-condensed component comprising hydrogen and a condensed component comprising hydrogen chloride and 1,1,1,3,3-pentafluoropropane, the step (C) of separating hydrogen from the non-condensed component of the step (B) and recycling the hydrogen to the above step (A), and the step (D) of separating 1,1,1,3,3-pentafluoropropane from the condensed component of the step (B). This process makes it possible to prepare 1,1,1,3,3-pentafluoropropane industrially efficiently and economically.
    • 一种制备1,1,1,3,3-五氟丙烷的方法,包括在氢化催化剂存在下用氢气还原2,3-二氯-1,1,1,3,3-五氟丙烷的步骤(A) 通过气相反应在常压或升高的压力下,将步骤(A)的所有产物引入冷凝器以获得包含氢和氯化氢的非冷凝组分和包含1 ,1,1,3,3-五氟丙烷或含有氢的非缩合成分和含有氯化氢和1,1,1,3,3-五氟丙烷的缩合成分的工序(C) 步骤(B)的浓缩组分并将氢气再循环至上述步骤(A),和从步骤(B)的浓缩组分分离1,1,1,3,3-五氟丙烷的步骤(D)。 该工艺可以在工业上有效且经济地制备1,1,1,3,3-五氟丙烷。