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1. 发明授权

EP2161248B1 Aromatic vinyl ether compounds 有权
标题翻译： aromatische Vinyletherverbindungen
公开(公告)号：EP2161248B1
公开(公告)日：2015-01-07
申请号：EP09012466.0
申请日：2003-10-24
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C43/23 , C07C43/20
CPC分类号： C07C317/22 , C07C43/202 , C07C43/23

2. 发明公开

EP1452516A2 Process for producing allyl-containing compounds 审中-公开
标题翻译：一种烯丙基的制备方法
公开(公告)号：EP1452516A2
公开(公告)日：2004-09-01
申请号：EP04004385.3
申请日：2004-02-26
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C41/16 , C07C67/10 , C07C43/15 , C07C319/14 , C07C43/188 , C07C43/205 , C07C43/164 , C07C69/007 , C07B41/04
CPC分类号： C07C41/16 , C07C67/10 , C07C319/14 , C07C2603/74 , C07C69/78 , C07C321/18 , C07C43/15 , C07C43/178 , C07C43/188 , C07C43/215 , C07C43/166
摘要： An allyl-containing compound represented by following Formula (3):
wherein R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R 7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1):
wherein R 1 represents hydrogen atom or an organic group; and R 2 , R 3 , R 4 , R 5 and R 6 are as defined above, with a compound represented by following Formula (2):

R 7 -Y-H (2)

wherein R 7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.

3. 发明公开

EP0926134A3 Processes for producing alpha-cyanohydrin esters and alpha-hydroxy acids 有权
标题翻译：生产α-氰醇酯和α-羟基酸的方法
公开(公告)号：EP0926134A3
公开(公告)日：1999-08-18
申请号：EP98123461.0
申请日：1998-12-11
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Nakano, Tatsuya
IPC分类号： C07C253/08
CPC分类号： C07C253/00 , C07C51/08 , C07C59/01 , C07C59/48 , C07C255/14
摘要： The present invention relates to a process for the preparation of compounds of formula (4) wherein a carbonyl compound of the formula (3) is reacted in the presence of a cyanogenation agent with an enol ester of the formula (1) or with an oxime ester of the formula (2):
wherein R 1 through R 8 have meanings given in the application. The compound of formula (4) can be hydrolysed to obtain the corresponding compound of formula (5):
摘要翻译：本发明涉及制备式（4）化合物的方法，其中式（3）的羰基化合物在氰化剂存在下与式（1）的烯醇酯或与肟式（2）的酯：其中R1至R8具有本申请中给出的含义。式（4）化合物可以水解得到相应的式（5）化合物：

4. 发明公开

EP0926135A3 Processes for producing alpha-aminonitrile derivatives and alpha-amino acids 有权
标题翻译：生产α-氨基腈衍生物和α-氨基酸的方法
公开(公告)号：EP0926135A3
公开(公告)日：1999-07-07
申请号：EP98123771.2
申请日：1998-12-14
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Nakano, Tatsuya
IPC分类号： C07C253/08 , C07C227/20
CPC分类号： C07C253/08 , C07C227/20 , C07C229/48 , C07C255/46
摘要： In the presence of a metal catalyst such as a samarium compound, an oxime ester compound shown by the formula (1):
wherein R 1 , R 2 , and R 3 are the same or different from each other, and each represents a non-reactive atom or a non-reactive organic group; and R 2 and R 3 , together with the adjacent carbon atom, may bond together to form a ring
is reacted with a cyanogenation agent such as an α-cyanohydrin compound (e.g., acetone cyanohydrin) to form an α-aminonitrile derivative. By hydrolyzing the α-aminonitrile derivative, the corresponding α-amino acid or a salt thereof can be obtained. According to the above processes, an α-aminonitrile derivative and an α-amino acid can be obtained in high yields.
摘要翻译：在金属催化剂如钐化合物存在下，式（1）所示的肟酯化合物：其中R1，R2和R3彼此相同或不同，并且各自代表非反应性原子或非反应性有机基团; 并且R2和R3与相邻碳原子一起可以连接在一起形成环，与氰化剂如α-氰醇化合物（例如丙酮氰醇）反应形成α-氨基腈衍生物。通过水解α-氨基腈衍生物，可以获得相应的α-氨基酸或其盐。根据上述方法，可以以高收率获得α-氨基腈衍生物和α-氨基酸。

5. 发明公开

EP0878234A2 Oxygenation catalyst and process for producing a ketone using the same 失效
标题翻译： Oxygenierungskatalysator和Verfahren zur Herstellung einer Ketone damit
公开(公告)号：EP0878234A2
公开(公告)日：1998-11-18
申请号：EP98108532.7
申请日：1998-05-11
申请人： Daicel Chemical Industries, Ltd. , Ishii, Yasutaka
发明人： Ishii, Yasutaka , Nakano, Tatsuya
IPC分类号： B01J31/02
CPC分类号： B01J31/34 , B01J31/006 , B01J31/0247 , B01J31/2208 , B01J31/36 , B01J2231/70 , B01J2531/56 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07C49/453 , C07C2603/74 , C07C35/37
摘要： A substrate is contacted with oxygen in the presence of the imide compound shown by the following formula (1) (N-hydroxyphthalimide) and a strong acid, or the imide compound, the strong acid and a co-catalyst (e.g., a transition metal compound) to oxygenate the substrate with high conversion and selectivity:
wherein R 1 and R 2 represent a substituent such as a hydrogen atom or a halogen atom, an alkyl group, an aryl group or a cycloalkyl group, or R 1 and R 2 may bond together to form a double bond or an aromatic or nonaromatic ring, X is O or OH, and n is 1 to 3.
The substrate comprises, for example, at least one compound selected from (a) a compound having a methyl group or a methylene group at an adjacent site of an unsaturated bond, (b) a homo- or hetero cyclic compound having a methylene group, (c) a compound having a methine carbon atom, (d) a compound having a methyl group or a methylene group at an adjacent site of an aromatic ring and (e) a compound having a methyl group or a methylene group at an adjacent site of a carbonyl group.
摘要翻译：存在下式（1）所示的酰亚胺化合物（N-羟基邻苯二甲酰亚胺）和强酸或酰亚胺化合物，强酸和助催化剂（例如过渡金属化合物）以高转化率和选择性对底物进行含氧化：其中R 1和R 2表示取代基如氢原子或卤素原子，烷基，芳基或环烷基，或R 1和R 2可以键合在一起形成双键或芳族或非芳族环，X为O或OH，n为1至3.基材包含例如至少一种选自（a）在不饱和键的相邻位置具有甲基或亚甲基的化合物，（b）具有亚甲基的均聚或杂环化合物，（c）具有次甲基碳原子的化合物，（ d）在芳环的相邻位置具有甲基或亚甲基的化合物和（e）具有甲基的化合物基团或在羰基的相邻位置的亚甲基。

6. 发明公开

EP0858835A1 Oxidation catalytic system and oxidation process 失效
标题翻译： Oxydationkatalysator系统和Oxydationsverfahren
公开(公告)号：EP0858835A1
公开(公告)日：1998-08-19
申请号：EP98102728.7
申请日：1998-02-17
申请人： Daicel Chemical Industries, Ltd. , Ishii, Yasutaka
发明人： Nakano, Tatsuya , Ishii, Yasutaka
IPC分类号： B01J31/02
CPC分类号： C07C49/675 , B01J31/006 , B01J31/0247 , B01J31/223 , B01J2231/70 , B01J2531/16 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/822 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/33 , C07C45/34 , C07C45/36 , C07C49/403 , C07C47/542
摘要： A substrate (e.g., a cycloalkane, a polycyclic hydrocarbon, an aromatic compound having a methyl group) is oxidized with oxygen in the presence of an oxidation catalytic system comprising an imide compound of the following formula (1) (e.g. N-hydroxyphthalimide) and a co-catalyst containing a element selected from Group 3 to 12 elements (in particular, Group 4 to 11 elements) of the Periodic Table of Elements. The co-catalyst comprises a compound contains plural elements (except heteropolyacid and a combination of Group 7 and 8 elements of the Periodic Table of Elements), and is useful for the formation of an oxide (e.g., a ketone, an alcohol, a carboxylic acid):
wherein R 1 and R 2 represent a substituent such as a hydrogen atom or a halogen atom, or R 1 and R 2 may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.
摘要翻译：在包含下式（1）的酰亚胺化合物（例如N-羟基邻苯二甲酰亚胺）的氧化催化体系存在下，用氧氧化底物（例如环烷烃，多环烃，具有甲基的芳族化合物）和含有选自元素周期表第3〜12族元素（特别是第4〜11族元素）的元素的助催化剂。助催化剂包含含有多种元素的化合物（杂多酸除外，元素周期表第7族和第8族元素的组合），并且可用于形成氧化物（例如酮，醇，羧酸酸）：其中R 1和R 2表示取代基如氢原子或卤素原子，或者R 1和R 2可以一起形成双键或芳族或非芳族 5-至12元环，X为O或OH，n为1至3。

7. 发明公开

EP1754693A1 Process for the production of esters or lactones, and process for the production of peroxides 有权
标题翻译： Verfahren zur Herstellung von Estern und Lactonen
公开(公告)号：EP1754693A1
公开(公告)日：2007-02-21
申请号：EP06023080.2
申请日：1999-03-23
申请人： DAICEL CHEMICAL INDUSTRIES, LTD.
发明人： Ishii, Yasutaka , Nakano, Tatsuya
IPC分类号： C07B41/00 , C07B33/00 , C07D301/06 , C07D303/04 , C07D303/14 , C07D303/16 , B01J31/02 , C07D315/00
CPC分类号： C07B41/12 , B01J31/006 , B01J31/0231 , B01J31/0247 , B01J31/0271 , B01J31/20 , B01J31/2208 , B01J2231/70 , B01J2231/72 , B01J2531/64 , B01J2531/845 , C07D315/00
摘要： The present invention relates to a process for the production of esters or lactones, and to a process for the production of peroxides.
摘要翻译：本发明涉及一种生产酯或内酯的方法，以及一种生产过氧化物的方法。

8. 发明公开

EP1452516A3 Process for producing allyl-containing compounds 审中-公开
标题翻译：生产含烯丙基化合物的方法
公开(公告)号：EP1452516A3
公开(公告)日：2004-09-08
申请号：EP04004385.3
申请日：2004-02-26
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C41/16 , C07C67/10 , C07C43/15 , C07C319/14 , C07C43/188 , C07C43/205 , C07C43/164 , C07C69/007 , C07B41/04
CPC分类号： C07C41/16 , C07C67/10 , C07C319/14 , C07C2603/74 , C07C69/78 , C07C321/18 , C07C43/15 , C07C43/178 , C07C43/188 , C07C43/215 , C07C43/166
摘要： An allyl-containing compound represented by following Formula (3): wherein R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R 7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1): wherein R 1 represents hydrogen atom or an organic group; and R 2 , R 3 , R 4 , R 5 and R 6 are as defined above, with a compound represented by following Formula (2):R 7 -Y-H wherein R 7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.
摘要翻译：（3）表示的含烯丙基的化合物：其中R2，R3，R4，R5和R6可以彼此相同或不同，并且各自表示氢原子或有机基团; R7代表有机基团; Y表示氧原子或硫原子，通过使下述式（1）所示的烯丙基酯化合物反应而制造，式中，R 1表示氢原子或有机基团。（2）表示的化合物：R7-Y-H其中R7为有机基团; R2，R3，R4，R5和R6如上所定义。 Y如上定义，在至少一种过渡元素化合物存在下进行。

9. 发明公开

EP1452517A1 Process for producing aromatic carboxylic acids 有权
标题翻译：梵蒂冈
公开(公告)号：EP1452517A1
公开(公告)日：2004-09-01
申请号：EP04004386.1
申请日：2004-02-26
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Nakano, Tatsuya
IPC分类号： C07C51/14 , C07C51/145 , C07C63/00 , C07C63/15 , C07C63/04 , C07C63/307 , C07C63/313 , B01J23/44 , B01J21/08 , B01J23/22 , B01J23/28 , B01J23/30 , B01J27/182 , B01J27/19 , B01J27/198 , B01J27/199
CPC分类号： C07C51/145 , B01J23/002 , B01J23/44 , B01J27/199 , B01J2523/00 , C07C65/21 , C07C63/04 , B01J2523/51 , B01J2523/55 , B01J2523/68 , B01J2523/824
摘要： An aromatic compound (C) is reacted with carbon monoxide (D) and molecular oxygen (E) in the presence of a palladium compound catalyst (A) and a catalyst (B) and thereby yields a aromatic carboxylic acid corresponding to the aromatic compound (C) except with one or more carboxyl groups bonded to its aromatic ring. The catalyst (B) contains a heteropolyacid or a salt thereof (B1) or a mixture of oxo acids and/or salts thereof (B2), and the mixture (B2) contains, as a whole, one of P and Si and at least one selected from V, Mo and W.
摘要翻译：在钯化合物催化剂（A）和催化剂（B）的存在下，芳香族化合物（C）与一氧化碳（D）和分子氧（E）反应，得到对应于芳香族化合物的芳香族羧酸 C），除了一个或多个与其芳香环键合的羧基。催化剂（B）含有杂多酸或其盐（B1）或其含氧酸和/或其盐的混合物（B2），并且混合物（B2）总体上包含P和Si中的一种，并且至少一个选自V，Mo和W.

10. 发明公开

EP1443363A2 Compounds for photoresist and resin composition for photoresist 有权
标题翻译： Photoresistzusammensetzung
公开(公告)号：EP1443363A2
公开(公告)日：2004-08-04
申请号：EP04010473.9
申请日：1999-05-20
申请人： Daicel Chemical Industries, Ltd.
发明人： Nakano, Tatsuya , Funaki, Yoshinori
IPC分类号： G03F7/039 , H01L21/30 , C07C69/54 , C07C69/753 , C07C69/757
CPC分类号： G03F7/0045 , G03F7/039 , G03F7/0397
摘要： A photoresist adamantane-series monomer represented by the following formula (1b):
wherein R 11 represents a hydrogen atom or a methyl group; R 12 , R 13 , and R 14 are the same or different from each other, each representing a hydrogen atom, an alkyl group, or a hydroxyl group and at least one of the substituents R 12 to R 14 is a hydroxyl group; X represents a connecting group; and m and n individually represent 0 or 1.
摘要翻译：由下式（1b）表示的光致抗蚀剂金刚烷系单体：ƒ€ƒ其中R 11表示氢原子或甲基; R 12，R 13和R 14彼此相同或不同，各自表示氢原子，烷基或羟基，并且至少一个取代基R 12至R 14为羟基; X表示连接组; m和n分别表示0或1。

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