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1. 发明公开

EP1452516A3 Process for producing allyl-containing compounds 审中-公开
标题翻译：生产含烯丙基化合物的方法
公开(公告)号：EP1452516A3
公开(公告)日：2004-09-08
申请号：EP04004385.3
申请日：2004-02-26
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C41/16 , C07C67/10 , C07C43/15 , C07C319/14 , C07C43/188 , C07C43/205 , C07C43/164 , C07C69/007 , C07B41/04
CPC分类号： C07C41/16 , C07C67/10 , C07C319/14 , C07C2603/74 , C07C69/78 , C07C321/18 , C07C43/15 , C07C43/178 , C07C43/188 , C07C43/215 , C07C43/166
摘要： An allyl-containing compound represented by following Formula (3): wherein R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R 7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1): wherein R 1 represents hydrogen atom or an organic group; and R 2 , R 3 , R 4 , R 5 and R 6 are as defined above, with a compound represented by following Formula (2):R 7 -Y-H wherein R 7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.
摘要翻译：（3）表示的含烯丙基的化合物：其中R2，R3，R4，R5和R6可以彼此相同或不同，并且各自表示氢原子或有机基团; R7代表有机基团; Y表示氧原子或硫原子，通过使下述式（1）所示的烯丙基酯化合物反应而制造，式中，R 1表示氢原子或有机基团。（2）表示的化合物：R7-Y-H其中R7为有机基团; R2，R3，R4，R5和R6如上所定义。 Y如上定义，在至少一种过渡元素化合物存在下进行。

2. 发明授权

EP2161248B1 Aromatic vinyl ether compounds 有权
标题翻译： aromatische Vinyletherverbindungen
公开(公告)号：EP2161248B1
公开(公告)日：2015-01-07
申请号：EP09012466.0
申请日：2003-10-24
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C43/23 , C07C43/20
CPC分类号： C07C317/22 , C07C43/202 , C07C43/23

3. 发明公开

EP1967505A1 Process for the preparation of substituted phenols 审中-公开
标题翻译：维也纳灭火器取代器苯酚
公开(公告)号：EP1967505A1
公开(公告)日：2008-09-10
申请号：EP08002869.9
申请日：2008-02-15
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Iwahama, Takahiro
IPC分类号： C07C37/50 , C07C39/07 , C07C39/08
CPC分类号： C07C37/50 , C07C41/26 , Y02P20/52 , Y02P20/55 , C07C39/07 , C07C43/23
摘要： A substituted phenolic compound is prepared by oxidizing a substituted diarylethane compound with oxygen in the presence of a nitrogen-containing cyclic compound, and treating the oxidized product with an acid. The nitrogen-containing cyclic compound includes, as a constituent of its ring, a skeleton represented by following Formula (I):

wherein X is oxygen atom or an -OR group, where R is hydrogen atom or a hydroxyl-protecting group. The substituted diarylethane compound is represented by following Formula (1):

wherein each of Ring Ar 1 and Ring Ar 2 is independently a monocyclic or polycyclic aromatic carbocyclic ring; Y 1 is an electron-donating group; Y 2 is an electron-withdrawing group; "p" is an integer of 1 or more; and "q" is an integer of 0 or more. The substituted phenolic compound is represented by following Formula (2):

wherein Ring Ar 1 , Y 1 , and "p" are as defined above.
摘要翻译：通过在含氮环状化合物的存在下用氧氧化取代的二芳基乙烷化合物，并用酸处理氧化产物来制备取代的酚类化合物。含氮环状化合物作为其环的成分包括由下式（I）表示的骨架：其中X是氧原子或-OR基团，其中R是氢原子或羟基保护基团。取代的二芳基乙烷化合物由下式（1）表示：其中环Ar 1和环Ar 2各自独立地为单环或多环芳族碳环; Y 1是给电子基团; Y 2是吸电子基团; “p”为1以上的整数， “q”为0以上的整数。取代的酚类化合物由下式（2）表示：其中环Ar 1，Y 1和“p”如上所定义。

4. 发明公开

EP1452516A2 Process for producing allyl-containing compounds 审中-公开
标题翻译：一种烯丙基的制备方法
公开(公告)号：EP1452516A2
公开(公告)日：2004-09-01
申请号：EP04004385.3
申请日：2004-02-26
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C41/16 , C07C67/10 , C07C43/15 , C07C319/14 , C07C43/188 , C07C43/205 , C07C43/164 , C07C69/007 , C07B41/04
CPC分类号： C07C41/16 , C07C67/10 , C07C319/14 , C07C2603/74 , C07C69/78 , C07C321/18 , C07C43/15 , C07C43/178 , C07C43/188 , C07C43/215 , C07C43/166
摘要： An allyl-containing compound represented by following Formula (3):
wherein R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R 7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1):
wherein R 1 represents hydrogen atom or an organic group; and R 2 , R 3 , R 4 , R 5 and R 6 are as defined above, with a compound represented by following Formula (2):

R 7 -Y-H (2)

wherein R 7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.

5. 发明公开

EP2233475A1 Epoxycyclohexane vinyl ether compounds and their use in polymerizable compositions 审中-公开
标题翻译：环氧环己烷 - Vinyletherverbindungen und ihre Verwendung在聚合物Zusammensetzungen
公开(公告)号：EP2233475A1
公开(公告)日：2010-09-29
申请号：EP10005647.2
申请日：2008-03-17
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya , Inoue, Keizo , Miyake, Hiroto , Yoshida, Tsukasa , Ohno, Mitsuru , Funaki, Yoshinori
IPC分类号： C07D303/22 , C07D305/06 , C08F24/00
CPC分类号： C07D303/22 , C07D305/06 , C08F24/00
摘要： Disclosed is an alicyclic epoxy-containing vinyl ether compound represented by following Formula (3c) or (3d):

wherein R b represents a substituted or unsubstituted vinyl group represented by following Formula (4):

wherein each of R 4 , R 5 and R 6 independently represents a hydrogen atom or an alkyl group containing one to four carbon atoms; These vinyl ether compunds are useful as polymerizable compounds that will polymerize or cure by the application of light and/or heat.
摘要翻译：公开了由下式（3c）或（3d）表示的含脂环族环氧基的乙烯基醚化合物：其中R b表示由下式（4）表示的取代或未取代的乙烯基：其中R 4，R 5和R 6独立地表示氢原子或含有1至4个碳原子的烷基; 这些乙烯基醚化合物可用作通过施加光和/或热而聚合或固化的可聚合化合物。

6. 发明公开

EP1972622A3 Vinyl ether compounds and polymerizable compositions 审中-公开
标题翻译：乙烯基醚化合物和可聚合的化合物
公开(公告)号：EP1972622A3
公开(公告)日：2009-07-01
申请号：EP08004955.4
申请日：2008-03-17
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya , Inoue, Keizo , Miyake, Hiroto , Yoshida, Tsukasa , Ohno, Mitsuru , Funaki, Yoshinori
IPC分类号： C07D303/22 , C07D305/06 , C08F24/00
CPC分类号： C07D303/22 , C07D305/06 , C08F24/00
摘要： Disclosed is an oxetane-containing vinyl ether compound including one or more aromatic or non-aromatic carbocycles and/or two or more vinyl ether structures, such as a compound of Formula:

wherein Ring Z 1 is non-aromatic carbocycle; R a is vinyl group of Formula:

wherein each of R 1 , R 2 , and R 3 is hydrogen or C1-C4 alkyl; W a is single bond or organic group having a valence of (m+1); X 1 is, for example, hydrocarbon; "m" and "q" are each 1 or 2; and "p" is 0 to 5. Also disclosed is an alicyclic epoxy-containing vinyl ether compound of Formula:

wherein Ring Z 2 is non-aromatic carbocycle; R b is vinyl group of Formula:

wherein R 4 , R 5 and R 6 are each hydrogen or C1-C4 alkyl; W b is single bond or organic group having a valence of (r+1); R c and R d are hydrogen or alkyl; and "r" and "s" are 1 or 2.

7. 发明公开

EP1413568A3 Aromatic vinyl ether compounds 有权
标题翻译：芳香族乙烯基醚化合物
公开(公告)号：EP1413568A3
公开(公告)日：2004-11-17
申请号：EP03024369.5
申请日：2003-10-24
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C43/166 , C07C43/178 , C07C43/215 , C07C43/23 , C07C49/84 , C07C317/22
CPC分类号： C07C317/22 , C07C43/202 , C07C43/23
摘要： Novel aromatic vinyl ether compounds are represented by following Formula (1) or (2): wherein R and R' are each a hydrogen atom or a group represented by following Formula (3): wherein R a , R b , and R c are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are each a hydrogen atom or a substituted or unsubstituted hydrocarbon group; W is a single bond or a linkage group; m, n, p, q, r, s, t, u, v, and x are integers in specific ranges, at least one of pRs in Formula (1) is the group of Formula (3) , and at least one of uRs in Formula (2) is the group of Formula (3) . These aromatic vinyl ether compounds are useful as, e.g., curing agents for cationic polymerization.
摘要翻译：新型芳族乙烯基醚化合物由下式（1）或（2）表示：其中R和R'各自为氢原子或由下式（3）表示的基团：其中Ra，Rb和Rc各自为氢原子或具有1至4个碳原子的烷基; R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自为氢原子或取代或未取代的烃基; W是单键或连接基团; m，n，p，q，r，s，t，u，v和x是特定范围内的整数，式（1）中的至少一个pR为式（3）的基团，式（2）中的uR是式（3）的组。这些芳族乙烯基醚化合物可用作例如用于阳离子聚合的固化剂。

8. 发明公开

EP1972622A2 Vinyl ether compounds and polymerizable compositions 审中-公开
标题翻译： Vinylether-Verbindungen und Polymerisierbare Verbindungen
公开(公告)号：EP1972622A2
公开(公告)日：2008-09-24
申请号：EP08004955.4
申请日：2008-03-17
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya , Inoue, Keizo , Miyake, Hiroto , Yoshida, Tsukasa , Ohno, Mitsuru , Funaki, Yoshinori
IPC分类号： C07D303/22 , C07D305/06 , C08F24/00
CPC分类号： C07D303/22 , C07D305/06 , C08F24/00
摘要： Disclosed is an oxetane-containing vinyl ether compound including one or more aromatic or non-aromatic carbocycles and/or two or more vinyl ether structures, such as a compound of Formula:

wherein Ring Z 1 is non-aromatic carbocycle; R a is vinyl group of Formula:

wherein each of R 1 , R 2 , and R 3 is hydrogen or C1-C4 alkyl; W a is single bond or organic group having a valence of (m+1); X 1 is, for example, hydrocarbon; "m" and "q" are each 1 or 2; and "p" is 0 to 5. Also disclosed is an alicyclic epoxy-containing vinyl ether compound of Formula:

wherein Ring Z 2 is non-aromatic carbocycle; R b is vinyl group of Formula:

wherein R 4 , R 5 and R 6 are each hydrogen or C1-C4 alkyl; W b is single bond or organic group having a valence of (r+1); R c and R d are hydrogen or alkyl; and "r" and "s" are 1 or 2.
摘要翻译：公开了包含一种或多种芳族或非芳族碳环和/或两个或多个乙烯基醚结构的含氧杂环丁烷的乙烯基醚化合物，例如下式的化合物：其中环Z 1是非芳族碳环; R a是下式的乙烯基：其中R 1，R 2和R 3各自为氢或C 1 -C 4烷基; W a是单键或化合价（m + 1）的有机基团; X 1例如是烃; “m”和“q”分别为1或2; 和“p”为0〜5。还公开了下式的脂环式环氧基乙烯基醚化合物：其中环Z 2为非芳香族碳环; R b是下式的乙烯基：其中R 4，R 5和R 6各自为氢或C 1 -C 4烷基; W b是单键或化合价（r + 1）的有机基团。 R c和R d是氢或烷基; “r”和“s”为1或2。

9. 发明公开

EP1413568A2 Aromatic vinyl ether compounds 有权
标题翻译： Aromatische Vinyletherverbindungen
公开(公告)号：EP1413568A2
公开(公告)日：2004-04-28
申请号：EP03024369.5
申请日：2003-10-24
申请人： Daicel Chemical Industries, Ltd.
发明人： Iwahama, Takahiro , Nakano, Tatsuya
IPC分类号： C07C43/166 , C07C43/178 , C07C43/215 , C07C43/23 , C07C49/84 , C07C317/22
CPC分类号： C07C317/22 , C07C43/202 , C07C43/23
摘要： Novel aromatic vinyl ether compounds are represented by following Formula (1) or (2):

wherein R and R' are each a hydrogen atom or a group represented by following Formula (3):
wherein R a , R b , and R c are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are each a hydrogen atom or a substituted or unsubstituted hydrocarbon group; W is a single bond or a linkage group; m, n, p, q, r, s, t, u, v, and x are integers in specific ranges, at least one of pRs in Formula (1) is the group of Formula (3) , and at least one of uRs in Formula (2) is the group of Formula (3) . These aromatic vinyl ether compounds are useful as, e.g., curing agents for cationic polymerization.
摘要翻译：新型芳族乙烯基醚化合物由下式（1）或（2）表示：其中R和R'各自为氢原子或由下式（3）表示的基团：其中R R a，R b和R c各自为氢原子或碳原子数为1〜4的烷基; R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自为氢原子或取代或未取代的烃基; W是单键或连接基团; m，n，p，q，r，s，t，u，v和x是特定范围的整数，式（1）中的至少一个pR是式（3）的基团，式（2）中的uRs是式（3）的基团。这些芳族乙烯基醚化合物可用作例如阳离子聚合用固化剂。

10. 发明公开

EP1342715A3 Process for producing oximes using nitirites 有权
标题翻译： Verfahren zur Herstellung von Oximen手套Nitriten
公开(公告)号：EP1342715A3
公开(公告)日：2003-11-26
申请号：EP03004912.6
申请日：2003-03-06
申请人： Daicel Chemical Industries, Ltd.
发明人： Ishii, Yasutaka , Nakano, Tatsuya , Iwahama, Takahiro
IPC分类号： C07C249/06 , C07B47/00
CPC分类号： C07C201/00 , C07B47/00 , C07C249/06 , C07C2601/08 , C07C2601/14 , C07C2601/18 , C07C2601/20 , Y02P20/55 , C07C251/44 , C07C251/48 , C07C207/02
摘要： A process produces an organic compound by allowing (A) a compound capable of generating a free radical to react with (B) at least one of esters and salts of nitrous acid in the presence of a nitrogen-containing cyclic compound constitutively having a skeleton represented by following Formula (i) in its ring: wherein X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group. Examples of the nitrogen-containing cyclic compound are cyclic imide compounds having a cyclic imide skeleton represented by following Formula (I): wherein n is 0 or 1; X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group.
摘要翻译：一种方法通过使（A）能够产生自由基的化合物在（B）至少一种亚硝酸的酯和盐的存在下，在组成性地具有骨架的含氮环状化合物的存在下生成有机化合物在其环中通过下式（i）：其中X是氧原子或-OR基团，其中R是氢原子或羟基保护基团。含氮环状化合物的实例是具有由下式（I）表示的环状酰亚胺骨架的环状酰亚胺化合物：其中n为0或1的 X是氧原子或-OR基团，其中R是氢原子或羟基保护基团。方法通过使（A）能够产生自由基的化合物与（B）反应而产生有机化合物，在其环中组成具有由下式（i）表示的骨架的含氮环状化合物存在下，亚硝酸的酯和盐中的至少一种：其中X是氧原子或-OR基团，并且其中R是氢原子或羟基保护基团。含氮环状化合物的实例是具有由下式（I）表示的环状酰亚胺骨架的环状酰亚胺化合物：其中n为0或1的 X是氧原子或-OR基团，其中R是氢原子或羟基保护基团。

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