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    • 1. 发明公开
    • Process for producing highly purified acetic acid
    • Verfahren zur Herstellung von hochreinerEssigsäure。
    • EP0645362A1
    • 1995-03-29
    • EP94114218.4
    • 1994-09-09
    • DAICEL CHEMICAL INDUSTRIES, LTD.
    • Harano, YoshiyukiMorimoto, Yoshiaki
    • C07C53/08C07C51/487C07C53/12C07C51/573
    • C07B63/00C07C51/487C07C53/08
    • The present invention relates to a process for producing a highly purified acetic acid, which contains reducing substances in trace amounts and exhibits a satisfactory result in the permanganate reducing substance test, comprising the step of continuously reacting an aqueous solution of methanol and/or methyl acetate with carbon monoxide in a reactor, the step of continuously withdrawing a reaction fluid from the reactor and the step of evaporating the withdrawn reaction fluid in an evaporator to thereby obtain vaporous components containing acetic acid and distilling the vaporous components in a distillation column while withdrawing an overhead from the distillation column at its top, characterized in that the overhead is treated with ozone.
    • 本发明涉及一种生产高纯度乙酸的方法,其含有微量的还原物质,并且在高锰酸盐还原物质试验中表现出令人满意的结果,包括使甲醇和/或乙酸甲酯的水溶液连续反应的步骤 与反应器中的一氧化碳反应,从反应器中连续排出反应流体的步骤和在蒸发器中蒸发所提取的反应流体的步骤,从而获得含有乙酸的蒸汽组分并蒸馏蒸馏塔中的蒸汽组分,同时取出 顶部馏出塔顶馏出物,其特征在于塔顶馏出物用臭氧处理。
    • 5. 发明公开
    • Epoxidised compositions
    • 环氧化组合物
    • EP0859021A2
    • 1998-08-19
    • EP98106076.7
    • 1992-10-30
    • DAICEL CHEMICAL INDUSTRIES, LTD.
    • Harano, YoshiyukiNamai, SozoMaeda, KatsuyukiMurai, Takaaki
    • C08G65/14C08G65/26C08G65/32C08G59/32C08G59/34
    • C08G59/027C08G59/68C08G63/58C08G63/918C08G65/14C08G65/2615C09D163/00C09D167/00Y10S525/922C08L63/00C08L2666/18
    • Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), are disclosed.
      (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom.
      Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof.
      The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.
    • 包含具有乙烯基作为侧链的化合物和其环氧化组合物(XI),(XII)和(XIII)的组合物(I),(II)和(III),其可以通过 (b)或(b)+(c)。 (a)是至少一种分子中具有至少一个乙烯基和一个环氧基的化合物; (b)是多元酸化合物,其酸酐,在末端具有羧基的聚合物和具有羧基作为侧链的聚合物中的至少一种; (c)是至少一种具有至少一个活性氢原子的有机化合物。 可以制备热固化组合物和环氧树脂组合物,其包含上述组合物和自由基引发剂或固化剂,通过自由基(共)聚合组合物(III)或其环氧化组合物(XIII)而获得的聚合物组合物。 环氧化组合物(XI)和(XII)可以提供具有优异特性例如耐热性,户外耐久性和其它电性能的涂层或成型制品。
    • 6. 发明公开
    • Compositions, expoxidized compositions, a heat-curable resin composition, an epoxy resin composition, radically polymerized composition, a curable resin composition and a polymer having epoxy groups
    • 组合物,经氧化的组合物,热固性树脂组合物,环氧树脂组合物,自由基聚合组合物,可固化树脂组合物和具有环氧基的聚合物
    • EP0540027A3
    • 1995-06-07
    • EP92118618.5
    • 1992-10-30
    • DAICEL CHEMICAL INDUSTRIES, LTD.
    • Harano, YoshiyukiNamai, SozoMaeda, KatsuyukiMurai, Takaaki
    • C08L63/00C08G59/17C08G65/26C08G65/14C08G65/32C08G59/14C08G59/34
    • C08G59/027C08G59/68C08G63/58C08G63/918C08G65/14C08G65/2615C09D163/00C09D167/00Y10S525/922C08L63/00C08L2666/18
    • Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), are disclosed.
      (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at least one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group. Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof. The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.
    • 包含具有乙烯基作为侧链的化合物和其环氧化组合物(XI),(XII)和(XIII)的组合物(I),(II)和(III),其可以通过 (b)或(b)+(c)和/或(d)。 (a)是至少一种分子中具有至少一个乙烯基和一个环氧基的化合物; (b)是多元酸化合物,其酸酐,在末端具有羧基的聚合物和具有羧基作为侧链的聚合物中的至少一种; (c)为至少一种具有至少一个活性氢原子的有机化合物; 和(d)是具有羟基的不饱和一元羧酸化合物或不饱和一元羧酸酯中的至少一种。 可以制备热固化组合物和环氧树脂组合物,其包含上述组合物和自由基引发剂或固化剂,通过自由基(共)聚合组合物(III)或其环氧化组合物(XIII)而获得的聚合物组合物。 环氧化组合物(XI)和(XII)可以提供具有优异特性例如耐热性,户外耐久性和其它电性能的涂层或成型制品。