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    • 8. 发明公开
    • HETERODIAMONDOIDS
    • EP1542983A1
    • 2005-06-22
    • EP03765723.6
    • 2003-07-17
    • Chevron U.S.A. Inc.
    • LIU, ShenggaoCARLSON, Robert, M.DAHL, Jeremy, E.
    • C07D311/78C07D313/06C07D335/04C07D221/18
    • C07C49/617C07C23/20C07C49/423C07C49/613C07C61/29C07D221/22C07D311/96C07D313/06C07D335/04C07D471/10C07F9/65683
    • This invention is related to heteroatom containing diamondoids (i.e., 'heterodiamondoids' ) which are compounds having a diamondoid nucleus in which one or more of the diamondoid nucleus carbons has been substitutionally replaced with a noncarbon atom. These heteroatom substituents impart desirable properties to the diamondoid. In addition, the heterodiamondoids are functionalized affording compounds carrying one or more functional groups covalently pendant therefrom. This invention is further related to polymerizable functionalized heterodiamondoids. In a preferred aspect of this invention the diamondoid nuclei are triamantane and higher diamondoid nuclei. In another preferred aspect, the heteroatoms are selected to give rise to diamondoid materials which can serve as n- and p-type materials in electronic devices can serve as optically active materials.
    • 本发明涉及含杂原子的菱形(即“杂二芳族化合物”),它是具有菱形核的化合物,其中一个或多个菱形核碳已经被非碳原子取代取代。 这些杂原子取代基赋予金刚石结构所需的性质。 此外,杂二芳族化合物被官能化以提供携带一个或多个共价连接于其上的官能团的化合物。 本发明进一步涉及可聚合官能化的杂二芳族化合物。 在本发明的一个优选方面,菱形晶核是三金刚烷和更高的菱形晶核。 在另一个优选的方面,选择杂原子以产生可用作电子器件中的n-型和p-型材料的菱形材料,可以用作光学活性材料。