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1. 发明公开

EP0302824A2 Moisture activated agricultural composition and method 失效
标题翻译： Durch Feuchtigkeit aktivierte agrochemische Zusammensetzung und Verfahren。
公开(公告)号：EP0302824A2
公开(公告)日：1989-02-08
申请号：EP88810515.2
申请日：1988-07-26
申请人： CIBA-GEIGY AG
发明人： Goldenberg, Merril S. , Kleiner, Eduard K. , Burkhard, Niklaus , Nevill, John David, Dr.
IPC分类号： A01N25/10 , A01C1/06
CPC分类号： A01N25/10 , A01C1/06
摘要： A method for the moisture activated release and transport in soil of a substantially non-volatile, lipophilic biologically active agent having a solubility in water of less than about 0.1% by weight, comprising contacting said soil with a composition containing a biologically effective amount of said active agent entrapped within an association complex of a polycarboxylate polymer and a poly (lower) alkoxylated surfactant, such that upon application of moisture the rate of release and transport of said active agent from said composition is dependent upon (i) the rate of moisture activated dissociation of, and resultant release of said surfactant from, the complex, and (ii) the rate of diffusion of the released surfactant through the moist soil; and compositions for use in said method.
摘要翻译：一种在土壤中水分活化的释放和运输的方法，该方法是在水中的溶解度小于约0.1％（重量）的基本上非挥发性的亲脂性生物活性剂，包括使所述土壤与含有生物有效量的所述聚羧酸酯聚合物和聚（低级）烷氧基化表面活性剂的缔合络合物中的活性剂，使得在施用水分时，所述活性剂从所述组合物的释放和转运速率取决于（i）水分活化速率所述表面活性剂从复合物的解离和最终释放，和（ii）释放的表面活性剂通过湿土的扩散速率; 和用于所述方法的组合物。

2. 发明公开

EP0138748A1 Fluoroaliphatic -thio, -sulfinyl or -sulfonyl substituted bicycloaliphatic amic acid amine salts and compositions and use thereof 失效
标题翻译：氟代脂族硫代，亚硫酰基或磺酰基取代的双环酰胺酸 - 胺盐以及它们的组合物和使用。
公开(公告)号：EP0138748A1
公开(公告)日：1985-04-24
申请号：EP84810280.2
申请日：1984-06-07
申请人： CIBA-GEIGY AG
发明人： Kaschig, Jürgen, Dr. , Kleiner, Eduard K. , Mueller, Karl Friedrich , Cooke, Thomas W.
IPC分类号： C07C149/26 , C07C147/00 , C07D493/08 , D06M13/34 , D21H3/12
CPC分类号： C07D307/77 , C07D307/93
摘要： Fluoroaliphatic-thio, -sulfinyl and -sulfonyl substituted bicycloaliphatic amic amine salts of the formula
where R f is perfluoroalkyl, R' is alkylene optionally interrupted by -O-, -S- or
where R a is hydrogen or alkyl, Y is lower alkylene or - 0 -, n is 0-2, R, and R z are independently hydrogen, lower alkyl,hydroxy-lower alky or together with the nitrogen atom to which they are attached, represent morpholino, R 3 , R 4 and R, are independently hydrogen, lower alkyl, or hydroxy-lower alkyl, R 6 is lower alkyl, carboxy- lower alkyl, sulfo-lower alkyl, hydroxy-lower alkyl, benzyl or together with R, and the nitrogen atom to which they are attached represent morpholino, and R is hydrogen or methyl are provided. These salts applied in the form of aqueous solutions, dispersions or emulsions are useful in rendering cellulosic and natural and synthetic polyamide materials oil and water repellent.

3. 发明授权

EP0002004B1 Process for the manufacture of fluorinated cationic compounds and their use as surfactants 失效
标题翻译：氟化阳离子化合物的制造方法及其作为表面活性剂的用途
公开(公告)号：EP0002004B1
公开(公告)日：1982-03-24
申请号：EP78101284.4
申请日：1978-11-02
申请人： CIBA-GEIGY AG
发明人： Cooke, Thomas W. , Kleiner, Eduard K. , Dear, Robert Ernest Arthur
IPC分类号： C07C149/24 , C07D213/20 , C07D295/08 , C11D1/62
CPC分类号： G03C11/16 , B01F17/0057 , B41N1/003 , C07D213/20 , C11D1/004 , G03C1/385

4. 发明公开

EP0573393A1 Perfluoroalkyl substituted hydroxyphenylalkanoic ester antioxidants 失效
标题翻译：全氟烷基基团羟基苯基链烷醇酯抗氧化剂。
公开(公告)号：EP0573393A1
公开(公告)日：1993-12-08
申请号：EP93810383.5
申请日：1993-05-25
申请人： CIBA-GEIGY AG
发明人： Falk, Robert A. , Kleiner, Eduard K.
IPC分类号： C07C323/12 , C08K5/37
CPC分类号： C08K5/375 , C07C323/12 , C08K5/136
摘要： Perfluoroalkyl substituted alcohols can be reacted with substituted hydroxyphenylalkanoic esters to form perfluoroalkyl containing hydroxyphenylalkanoic ester antioxidants of the formula I, II or III

wherein R₁ and R₂ are independently e.g. alkyl of 1 to 4 carbon atoms, R₃ is e.g. hydrogen, A is e.g. ethylene, m is e.g. 2 or 3, n is 1 or 0, R f is e.g. perfluoroalkyl of 6 to 12 carbon atoms, E is e.g. alkylene of 2 to 6 carbon atoms and X is e.g. -S-.
These perfluoroalkyl substituted hindered hydroxyphenyl alkanoates are stabilizers which confer superior processing stability to polymers processed at elevated temperatures such as polypropylene, as well as protecting said polymers from thermal and oxidative degradation.
摘要翻译：全氟烷基取代的醇可以与取代的羟基苯基链烷酸酯反应形成式I，II或III的全氟烷基羟基苯基链烷酸酯抗氧化剂，其中R 1和R 2独立地为例如。 1至4个碳原子的烷基，氢，A是例如。乙烯，m是例如。 2或3，n为1或0，Rf为例如。 6至12个碳原子的全氟烷基，E是例如。 2至6个碳原子的亚烷基，X是例如。 -S-。这些全氟烷基取代的受阻羟基苯基链烷酸酯是对在高温下加工的聚合物（如聚丙烯）具有优异的加工稳定性的稳定剂，以及保护所述聚合物免受热和氧化降解。

5. 发明授权

EP0138748B1 Fluoroaliphatic -thio, -sulfinyl or -sulfonyl substituted bicycloaliphatic amic acid amine salts and compositions and use thereof 失效
标题翻译：氟代二硫代，磺酰基或磺基取代的双环氨基酸酰胺盐及其组合物及其用途
公开(公告)号：EP0138748B1
公开(公告)日：1987-01-21
申请号：EP84810280.2
申请日：1984-06-07
申请人： CIBA-GEIGY AG
发明人： Kaschig, Jürgen, Dr. , Kleiner, Eduard K. , Mueller, Karl Friedrich , Cooke, Thomas W.
IPC分类号： C07C149/26 , C07C147/00 , C07D493/08 , D06M13/34 , D21H3/12
CPC分类号： C07D307/77 , C07D307/93

6. 发明公开

EP0083312A1 Aqueous based fire foam compositions containing hydrocarbyl sulfide terminated oligomer stabilizers 失效
标题翻译：包含用于灭火，用稳定的低聚物Kohlenwasserstoffsulfidendgruppen水基泡沫的组合物。
公开(公告)号：EP0083312A1
公开(公告)日：1983-07-06
申请号：EP82810563.5
申请日：1982-12-22
申请人： CIBA-GEIGY AG
发明人： Kleiner, Eduard K. , Falk, Robert A.
IPC分类号： A62D1/04
CPC分类号： A62D1/0071
摘要： This invention relates to aqueous based fire fighting foams containing a stabilizing amount of an oligomer of the formula
wherein R 1 is an oleophilic aryl, araliphatic, aliphatic or cyclo-aliphatic group having up to 25 carbon atoms; E is a direct bond, or an organic covalently bonded divalent linking group, n is 0, 1 or 2, [M 1 ] is a hydrophilic acrylamido monomer unit, [M 2] is a copolymerizable non-acrylamido hydrophilic monomer unit, [M 3] is a copolymerizable hydrophobic monomer unit, the average of the sum of x, y and z is between about 3 and about 500, and is between 1 and about 0.5. These stabilizing oligomer additives in aqueous based fire fighting foams improve foam expansion, foam drainage and fire extinguishing times.

7. 发明授权

EP0573393B1 Perfluoroalkyl substituted hydroxyphenylalkanoic ester antioxidants 失效
标题翻译：全氟烷基取代的羟基苯基链烷酸酯抗氧化剂
公开(公告)号：EP0573393B1
公开(公告)日：1995-12-06
申请号：EP93810383.5
申请日：1993-05-25
申请人： CIBA-GEIGY AG
发明人： Falk, Robert A. , Kleiner, Eduard K.
IPC分类号： C07C323/12 , C08K5/37
CPC分类号： C08K5/375 , C07C323/12 , C08K5/136

8. 发明公开

EP0302824A3 Moisture activated agricultural composition and method 失效
标题翻译：水分活化农业组合物和方法
公开(公告)号：EP0302824A3
公开(公告)日：1990-01-24
申请号：EP88810515.2
申请日：1988-07-26
申请人： CIBA-GEIGY AG
发明人： Goldenberg, Merril S. , Kleiner, Eduard K. , Burkhard, Niklaus , Nevill, John David, Dr.
IPC分类号： A01N25/10 , A01C1/06
CPC分类号： A01N25/10 , A01C1/06
摘要： A method for the moisture activated release and transport in soil of a substantially non-volatile, lipophilic biologically active agent having a solubility in water of less than about 0.1% by weight, comprising contacting said soil with a composition containing a biologically effective amount of said active agent entrapped within an association complex of a polycarboxylate polymer and a poly (lower) alkoxylated surfactant, such that upon application of moisture the rate of release and transport of said active agent from said composition is dependent upon (i) the rate of moisture activated dissociation of, and resultant release of said surfactant from, the complex, and (ii) the rate of diffusion of the released surfactant through the moist soil; and compositions for use in said method.

9. 发明授权

EP0083312B1 Aqueous based fire foam compositions containing hydrocarbyl sulfide terminated oligomer stabilizers 失效
标题翻译：含有烃类硫化物终止的低聚物稳定剂的基于水的火焰组合物
公开(公告)号：EP0083312B1
公开(公告)日：1986-03-05
申请号：EP82810563.5
申请日：1982-12-22
申请人： CIBA-GEIGY AG
发明人： Kleiner, Eduard K. , Falk, Robert A.
IPC分类号： A62D1/04
CPC分类号： A62D1/0071

10. 发明公开

EP0002004A1 Process for the manufacture of fluorinated cationic compounds and their use as surfactants 失效
标题翻译：一种用于生产含氟化合物及其作为阳离子表面活性剂的使用过程。
公开(公告)号：EP0002004A1
公开(公告)日：1979-05-30
申请号：EP78101284.4
申请日：1978-11-02
申请人： CIBA-GEIGY AG
发明人： Cooke, Thomas W. , Kleiner, Eduard K. , Dear, Robert Ernest Arthur
IPC分类号： C07C149/24 , C07D213/20 , C07D295/08 , C11D1/62
CPC分类号： G03C11/16 , B01F17/0057 , B41N1/003 , C07D213/20 , C11D1/004 , G03C1/385
摘要： Fluorinated cationic compounds of the formula
wherein

R f is perfluoroalkyl or said perfluoroalkyl substituted by perfluoroalkoxy,
Q is alkylene, alkylene thioalkylene, alkylene oxyalkylene or alkylene iminoalkylene, wherein the imino group is optionally substituted by alkyl of 1 to 6 carbon atoms,
V, R, and R 2 independently of one another represent optionally substituted alkyl, or cycloalkyl, benzyl, phenyl or polyalkyleneoxy of 2 to 20 alkoxy units and alkylene units of 2 to 4 carbon atoms, or R, and R 2 together with the nitrogen atom to which they are attached, represent a 5- or 6-membered heterocyclic radical or
R 1 , R 2 and V, together with the nitrogen atom which links them, represent a pyridine ring and
A⊖ represents the anion of an organic or inorganic acid which are prepared by reacting a mercaptan com- oound of the formula
with a compound of the formula
wherein Y represents halogen.

These compounds are particularly useful as surfactants.
摘要翻译：式 worin RF的氟化阳离子化合物是全氟烷基或所述的全氟烷基被全氟烷氧基substituiertem，Q是亚烷基，亚烷基硫代亚烷基，亚烷基氧亚烷基或亚烷基iminoalkylene，worin亚氨基任选被1烷基substituiertem至6个碳原子，V 中，一个R 1和R 2unabhängig另一个与氮原子到它们是表示任选substituiertem烷基，或环烷基，苄基，苯基或2/2〜20的烷单元和亚烷基单元聚亚至4个碳原子，或R1和R2一起相连，表示一个5-或6-元杂环基团或R 1，R 2和V具有其中左边它们的氮原子一起代表吡啶环和A <（ - ）> darstellt制备，其中有机或无机酸的阴离子由式Rf-Q-SH的硫醇化合物与式 worinÿdarstellt卤素的化合物反应。这些化合物可用作表面活性剂是特别有用的。

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