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    • 6. 发明公开
    • Discolour-free silanol condensation catalyst containing polyolefin composition
    • 聚烯烃缩合反应
    • EP1760111A1
    • 2007-03-07
    • EP05018918.2
    • 2005-08-31
    • Borealis Technology Oy
    • Hagstrand, Per-OlaNylander, PerryPalmlöf, MagnusOderkerk, Jeroen
    • C08K5/524C08K5/527C08K5/51C08K5/42
    • C08K5/0025C08K5/51C08L23/06C08L43/04C08L51/06C08L2312/08C08L23/02C08L2666/24
    • The present invention relates to a polyolefin composition comprising a crosslinkable polyolefin with hydrolysable silane groups and a silanol condensation catalyst, and
      (A) a compound containing one or more PO m (O n R)(O o R')(O p R") groups, wherein
      R, R', and R" are the same or different organic residues; m is 0 or 1; n, o, and p each are 0 or 1; and n + o + p = 1 to 3;

      a master batch for a crosslinkable polyolefin composition comprising a polymer and a silanol condensation catalyst and component (A), a stabilized polyolefin containing cross-linked silane groups wherein cross-linking has been performed by the use of a silanol condensation catalyst, further comprising component (A), and to the use of component (A) for stabilizing a polyolefin composition comprising a crosslinkable polyolefin with hydrolysable silane groups and a silanol condensation catalyst. The polyolefin composition of the invention can be used for pipe, wire & cable, film, fibre and moulding applications.
    • 本发明涉及包含具有可水解硅烷基团的可交联聚烯烃和硅烷醇缩合催化剂的聚烯烃组合物,和(A)含有一个或多个PO m(O n R)(O o R')(O o R')(O p R“ )基团,其中R,R'和R“是相同或不同的有机残基; m为0或1; n,o和p各自为0或1; 和n + o + p = 1〜3; 用于包含聚合物和硅烷醇缩合催化剂和组分(A)的可交联聚烯烃组合物的母料,含有交联硅烷基团的稳定的聚烯烃,其中通过使用硅烷醇缩合催化剂进行交联,还包含组分 (A),以及组分(A)用于稳定含有可水解硅烷基团的可交联聚烯烃的聚烯烃组合物和硅烷醇缩合催化剂的用途。 本发明的聚烯烃组合物可用于管道,电线和电缆,膜,纤维和模塑应用。
    • 9. 发明公开
    • UV stabilisation of a cross-linkable polyolefin composition comprising an acidic silanol condensation catalyst
    • 紫外线稳定剂eern vernetzbaren Polyolefinzusammensetzung mit einem sauren Silanol-Kondensationskatalysator
    • EP2072568A1
    • 2009-06-24
    • EP07024836.4
    • 2007-12-20
    • Borealis Technology OY
    • Nylander, Perry
    • C08K5/00C08K5/3435C08K5/3475
    • C08K5/3475C08K5/42C08L43/04C08L23/0892
    • The present invention relates to a polyolefin composition comprising
      (A) a cross-linkable polyolefin with hydrolysable silane groups;
      (B) and a silanol condensation catalyst

      characterized in that the Δ F is more than 40 Nm and the cross-linking speed is more than 0.1 Nm/s in the ice test and retention of more than 60% of the elongation at break after 500 h in SEPAP UV exposure,
      further a polyolefin composition comprising
      (A) a cross-linkable polyolefin with hydrolysable silane groups;
      (B) an acidic silanol condensation catalyst, and
      (C) at least one UV stabilizer that is acidic, i.e. pH equal or less than 6.2, measured at 20-25 °C and with 1 wt% suspension;

      to an article comprising such a composition, and to the use of such a composition for the production of an article.
    • 本发明涉及一种聚烯烃组合物,其包含(A)具有可水解硅烷基团的可交联聚烯烃; (B)和硅烷醇缩合催化剂,其特征在于,在冰试验中,“F大于40Nm,交联速度大于0.1Nm 3 / s,并且在500℃后保持60%以上的断裂伸长率 在SEPAP UV曝光中,还包括聚烯烃组合物,其包含(A)具有可水解硅烷基团的可交联聚烯烃; (B)酸性硅烷醇缩合催化剂,和(C)在20-25℃和1重量%悬浮液下测量的至少一种酸性,即pH等于或小于6.2的UV稳定剂; 涉及包含这种组合物的制品,以及这种组合物用于生产制品的用途。