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    • 1. 发明公开
    • RUBBER COMPOSITION FOR TIRE
    • KAUTSCHUKZUSAMMENSETZUNGFÜRREIFEN
    • EP3202840A4
    • 2017-08-09
    • EP15846150
    • 2015-09-28
    • BRIDGESTONE CORP
    • YAMAGISHI JUNICHIMUSHA SHINICHIKANATOMI YOSHIHIKO
    • C08L21/00B60C1/00C08G8/22C08K3/04C08K3/22C08L7/00C08L9/00C08L61/12
    • C08L7/00B60C1/00C08G8/22C08K3/04C08K3/22C08K2003/2296C08K2201/006C08K2201/014C08L9/00C08L21/00C08L61/12
    • The rubber composition of the present invention is prepared by mixing a rubber component (A), zinc oxide (B), and a co-condensate (C) having a softening point of 150°C or lower and containing a p-tert-butylphenol-derived constituent unit represented by the following formula (1), an o-phenylphenol-derived constituent unit represented by the following formula (2) and a resorcinol-derived constituent unit represented by the following formula (3), wherein the nitrogen adsorption specific surface area (N 2 SA) of the zinc oxide (B) measured according to the BET method is 6 m 2 /g or more and 110 m 2 /g or less, the mixing amount of the zinc oxide (B) is 5 parts by mass or more and 13 parts by mass or less based on 100 parts by mass of the rubber component (A), and the mixing amount of the co-condensate (C) is 0.1 parts by mass or more and 10 parts by mass or less based on 100 parts by mass of the rubber component (A). The co-condensate (C) is usable as a replacement for p-tert-octylphenol and p-nonylphenol, has a softening point lower than the maximum temperature in a rubber processing step, and has excellent dispersibility in rubber.
    • 本发明的橡胶组合物通过混合橡胶组分(A),氧化锌(B)和软化点为150℃或更低的共缩合物(C)并含有对叔丁基苯酚 (1)表示的衍生结构单元,下述式(2)表示的来自邻苯基苯酚的结构单元和下述式(3)表示的来自间苯二酚的结构单元,其中,氮吸附特性 根据BET法测得的氧化锌(B)的表面积(N 2 SA)为6m 2 / g以上且110m 2 / g以下,氧化锌(B)的混合量为5份 (A)100质量份,共聚缩合物(C)的配合量为0.1质量份以上且10质量份以下,或者相对于100质量份橡胶成分(A)为10质量份以上且13质量份以下, 基于100质量份橡胶组分(A)较少。 共缩合物(C)可用作对叔辛基酚和对壬基酚的替代物,其软化点低于橡胶加工步骤中的最高温度,并且在橡胶中具有优异的分散性。