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1. 发明公开

EP2445974A1 MODIFIZIERTE ZNO-NANOPARTIKEL 审中-公开
标题翻译：改性ZNO-NANOPARTIKEL
公开(公告)号：EP2445974A1
公开(公告)日：2012-05-02
申请号：EP10725770.1
申请日：2010-06-22
申请人： BASF SE
发明人： RIGGS, Richard , KARPOV, Andrey , SCHAMBONY, Simon , BEST, Wolfgang
IPC分类号： C09C1/04
CPC分类号： C09C1/043 , B82Y30/00 , C01P2004/64 , C01P2006/60 , C08K3/22 , C08K9/06 , C09D7/62
摘要： The invention relates to a method for producing modified zinc oxide nanoparticles, characterized in that the zinc oxide nanoparticles, which are dissolved in a solvent, are reacted in the presence of ammonia or amines with a tetraalkyl-orthosilicate, and optionally with an organosilane, under the proviso that the reaction takes place at a content of less than 5% by weight water, relative to the total quantity of solvent and water. Said production method can be used to obtain modified zinc oxide nanoparticles, which comprise Si-O-alkyl groups and can be solved in organic solvents. In addition, liquid or solid formulations containing modified ZnO nanoparticles can be obtained. Inanimate organic materials, such as plastics or paints, containing modified ZnO nanoparticles may also be obtained. The invention further relates to a method for stabilizing inanimate organic materials against the effects of light, radicals or heat, wherein modified ZnO nanoparticles, which optionally comprise UV absorbers and/or stabilizers as further additives, are added to the materials.
摘要翻译：制备改性氧化锌纳米颗粒的方法，其包括将溶于溶剂的氧化锌纳米颗粒在氨或胺与原硅酸四烷基酯和任选的有机硅烷的存在下反应，条件是反应发生在基于溶剂和水的总量小于5重量％的水的含量。具有Si-O-烷基且可溶于有机溶剂的改性氧化锌纳米颗粒，可通过该制备方法获得。包含改性ZnO纳米颗粒的液体或固体制剂。无生命的有机材料，例如塑料或涂层，其包含改性的ZnO纳米颗粒。对于光，自由基或热的影响稳定无生命有机材料的方法，其中任选地包含UV吸收剂和/或稳定剂作为其它添加剂的改性ZnO纳米颗粒被加入到材料中。

2. 发明公开

EP2313345A1 MODIFIZIERTE ZINKOXID-TEILCHEN 有权
标题翻译：改性的氧化锌粒子
公开(公告)号：EP2313345A1
公开(公告)日：2011-04-27
申请号：EP09780531.1
申请日：2009-07-14
申请人： BASF SE
发明人： KARPOV, Andrey , HIBST, Hartmut , SCHAMBONY, Simon , RIGGS, Richard , HAREMZA, Sylke
IPC分类号： C01G9/02 , C09C1/04
CPC分类号： C09C1/043 , C01G9/02 , C01P2002/84
摘要： The invention relates to a method for producing modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and the polar solvent is optionally removed after precipitation of a precipitation product, resulting in a residue, wherein the residue is absorbed in a non-polar solvent, surface active substances are added, other active substances are optionally added and then the modified ZnO particles are separated from other byproducts. The invention also relates to materials such as plastics, varnishes or paints containing modified ZnO particles. The invention also relates to a method for incorporating modified ZnO particles into materials, wherein the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions, and to the use of modified ZnO particles for protecting materials against the effects of light, heat, oxygen or radicals, as catalysts, for semiconducting layers or for cosmetic uses.

3. 发明授权

EP1976925B1 STABILISATORMISCHUNG 有权
公开(公告)号：EP1976925B1
公开(公告)日：2009-05-27
申请号：EP07703822.2
申请日：2007-01-12
申请人： BASF SE
发明人： SCHAMBONY, Simon , GLASER, Alban , TRAUTH, Hubert , APPEL, Manfred , HAREMZA, Sylke
IPC分类号： C08K5/3435 , C08K5/00
CPC分类号： C08K5/3435 , C07B63/04 , C07D211/58 , C08K5/34 , C08K2201/014 , C08L23/12 , C08L2201/08 , C09D7/48 , C09D7/65 , C09K15/20 , C09K15/30
摘要： A mixture comprising A. at least one oligomeric compound comprising repeat units of the formula (I) in which the symbols are each defined as follows: R1 is hydrogen, C1- to C6-alkyl, formyl, C2- to C6-alkanoyl, C1- to C12-alkoxy, C5- to C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula -CR'=CH-CO-OR' where R' is hydrogen, C1- to C6-alkyl or a radical of the formula -CO-OR', and R' is C1- to C18-alkyl, C5- to C8-cycloalkyl, C7- to C18-aralkyl, phenyl or tolyl; R2 is a mixture of C14- to C28-alkyl groups, where two of these alkyl groups, which must not differ by more than two carbon atoms, each make up at least 30% of this mixture; R3, R4 are each independently C1- to C6-alkyl; and B. at least one compound of the formula (II) or (III) where the symbols and indices are each defined as follows: n, m are each independently a natural number from 2 to 22 and R1, R3, R4 are each independently defined as specified in formula (I); is suitable as stabilizers for organic material.
摘要翻译：用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物，其包含式（I）的重复单元，其中符号的含义如下：R 1是氢，C 1 -C 6 - 烷基，甲酰基， C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 -C 6 - 环烷氧基，氰基甲基，2-羟基乙基，苄基或式-CR'= CH-CO-OR的基团，其中R'是氢， C 6 - 烷基或式-CO-OR基团，R“为C 1 -C 18烷基，C 5 -C 8 - 环烷基，C 7 -C 18 - 芳烷基，苯基或甲苯基; R2是由C14-C28-烷基组成的混合物，其中不允许两个以上碳原子数不同的烷基中的两个分别构成该混合物的至少30％ R3和R4彼此独立地为C1-C6-烷基; 和B.至少一种式（II）或（III）的化合物，其中符号和指数的含义如下：n和m彼此独立地是2-22的自然数，R1， R 3和R 4彼此独立地具有式（I）中给出的含义。

4. 发明公开

EP2215156A2 FLÜSSIGE STABILISATORMISCHUNG 有权
标题翻译：液体稳定剂混合物，
公开(公告)号：EP2215156A2
公开(公告)日：2010-08-11
申请号：EP08854484.6
申请日：2008-11-24
申请人： BASF SE
发明人： SCHAMBONY, Simon , FINK, Jochen , BRUCHMANN, Bernd
IPC分类号： C08K5/00 , C08K5/3435
CPC分类号： C08K5/101 , C08K5/315 , C08K5/3492 , C08L21/00
摘要： The invention relates to a mixture comprising (a) one or more liquid UV absorbers, under the stipulation that Tinuvin 384-2 is excluded as a liquid UV absorber, (b) one or more branched polymers comprising stabilizing groups, (c) optionally one or more further additives. Use of such a mixture for stabilizing inanimate organic materials against the effects of light, oxygen, and/or heat. Inanimate organic materials comprising at least one such mixture, and objects produced from such inanimate organic materials. Method for stabilizing inanimate organic materials against the effects of light, oxygen, and/or heat, wherein at least one such mixture is applied to the inanimate organic materials in an effective amount.

5. 发明授权

EP2318454B1 STABILISATOREN FÜR UNBELEBTE ORGANISCHE MATERIALIEN 有权
标题翻译：稳定剂的非居住在有机材料
公开(公告)号：EP2318454B1
公开(公告)日：2012-02-29
申请号：EP09781835.5
申请日：2009-08-14
申请人： BASF SE
发明人： GLASER, Alban , HAREMZA, Sylke , SCHAMBONY, Simon
IPC分类号： C08K5/00 , C08K5/32 , C07D211/94
CPC分类号： C07D211/94
摘要： The invention relates to the use of sterically hindered amines containing one or more groups of general formula (I), for stabilising inanimate organic materials, in particular of plastics or paints, where R
1 , R
2 independently = H, C
1 -C
20 alkyl, C
3 -C
15 cycloalkyl, aryl, heteroaryl, heterocyclyl, R
4 , R
5 , R
6 , R
7 independently = C
1 -C
20 alkyl, or R
4 and R
6 or R
5 and R
7 together = tetramethylene or pentamethylene and R
3 = aryl, or heteroaryl. The invention further relates to a method for stabilising inanimate organic materials, in articular of plastics or paints. Also disclosed are selected sterically hindered amines containing one or more groups of general formula (I) and materials containing the selected sterically hindered amines.

6. 发明授权

EP2185641B1 STABILISATORMISCHUNG 有权
标题翻译：稳定剂混合物，
公开(公告)号：EP2185641B1
公开(公告)日：2010-12-29
申请号：EP08802956.6
申请日：2008-08-01
申请人： BASF SE
发明人： SCHAMBONY, Simon , YAMAZAKI, Hideo , COUGHLIN, Greg
IPC分类号： C08K5/00 , C08K5/3492 , C08K5/3435 , C08K5/134
CPC分类号： C09K15/30 , C07D211/58 , C07D249/20 , C08K5/1345 , C08K5/3435 , C08K5/3475 , C08K5/34926 , C08L23/12 , C08L2666/78
摘要： The invention relates to mixtures containing (a) an oligomeric compound, containing repeating units of the general formula (I) or the acid addition salts thereof, and/or (b) a compound of the general formula (II) or the acid addition salts thereof, and (c) at least one compound of the general formula (III), and (d) optionally further additives, as well as to the use of these mixtures for stabilizing inanimate organic materials against the action of light, oxygen and/or heat. Furthermore, the invention relates to inanimate organic materials, containing at least one of these mixtures and objects produced therefrom. Furthermore, the invention relates to methods for stabilizing inanimate organic materials against the action of light, oxygen and/or heat.

7. 发明授权

EP1687278B1 USE OF 4-CYANO-NAPHTHALENE-1, 8-DICARBOXIMIDE DERIVATIVES AND RELATED COMPOUNDS TO PROTECT ORGANIC MATERIAL FROM THE DAMAGING EFFECTS OF LIGHT 有权
标题翻译：作者4-氰基萘-1,8-DICARBONSÄUREIMIDDERIVATEN及相关化合物用于保护有机材料对光的有害影响USE
公开(公告)号：EP1687278B1
公开(公告)日：2009-03-11
申请号：EP04818398.2
申请日：2004-11-12
申请人： BASF SE
发明人： SCHAMBONY, Simon , GLASER, Alban , SENS, Rüdiger , BÖHM, Arno , REICHELT, Helmut
IPC分类号： C07D221/14
CPC分类号： C07D221/14
摘要： A description is given of the use of naphthalene-1,8-dicarboxylic monoimides of the formula (I), in which R1 is hydrogen, alkyl, alkenyl, cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl and R2 is a radical containing at least one π electron system containing a carbon atom and at least one further atom selected from carbon, oxygen, and nitrogen, with the proviso that the radical contains at least one atom other than carbon; to protect organic material from the damaging effects of light, of compositions which comprise at least one naphthalene-1,8-dicarboxylic monoimide of the formula (I) in an amount which provides protection from the damaging effects of light, and at least one organic material, and of new naphthalene-1,8-dicarboxylic monoimides (I).

8. 发明授权

EP2430089B1 HOCHMOLEKULARE UNPOLARE BENZTRIAZOLE 有权
标题翻译：高相对分子无极性苯并三唑
公开(公告)号：EP2430089B1
公开(公告)日：2013-07-31
申请号：EP10721438.9
申请日：2010-05-11
申请人： BASF SE
发明人： HAREMZA, Sylke , MISSKE, Andrea , SCHAMBONY, Simon , GLASER, Alban
IPC分类号： C08K5/3475 , C07D249/20
CPC分类号： C08K5/3475 , C07D249/20 , C07D401/14 , C08F8/00

9. 发明授权

EP2215156B1 FLÜSSIGE STABILISATORMISCHUNG 有权
标题翻译：液体稳定剂混合物，
公开(公告)号：EP2215156B1
公开(公告)日：2013-01-09
申请号：EP08854484.6
申请日：2008-11-24
申请人： BASF SE
发明人： SCHAMBONY, Simon , FINK, Jochen , BRUCHMANN, Bernd
IPC分类号： C08K5/00 , C08K5/101 , C08K5/315 , C08K5/3492 , C08K5/3435
CPC分类号： C08K5/101 , C08K5/315 , C08K5/3492 , C08L21/00

10. 发明公开

EP2430089A2 HOCHMOLEKULARE UNPOLARE BENZTRIAZOLE 有权
标题翻译：高相对分子无极性苯并三唑
公开(公告)号：EP2430089A2
公开(公告)日：2012-03-21
申请号：EP10721438.9
申请日：2010-05-11
申请人： BASF SE
发明人： HAREMZA, Sylke , MISSKE, Andrea , SCHAMBONY, Simon , GLASER, Alban
IPC分类号： C08K5/3475 , C07D249/20
CPC分类号： C08K5/3475 , C07D249/20 , C07D401/14 , C08F8/00
摘要： The invention relates to the use of specific benztriazole derivatives of general formula (I), wherein B represents an optionally substituted 2-(2-hydroxyphenyl)- 2H-benztriazole group, n is a whole number between 3 - 20 and A represents an n-valent organic radical, as a UV-absorber or stabiliser in inanimate organic materials. The invention also relates to methods for stabilising inanimate organic materials, in particular plastics, counter to the effects of light by means of specific benztriazole derivatives. The invention also relates to specific benztriazole derivatives and inanimate organic materials containing specific benztriazole derivatives.

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