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    • 8. 发明公开
    • Production of mixed gases of controlled composition by pressure swing adsorption
    • 具有通过变压吸附特定的组成的气体混合物的生产。
    • EP0278437A2
    • 1988-08-17
    • EP88101715.6
    • 1988-02-05
    • AIR PRODUCTS AND CHEMICALS, INC.
    • Sircar, Shivaji
    • B01D53/04C01B3/56
    • B01D53/047B01D2253/102B01D2253/108B01D2256/10B01D2256/16B01D2256/20B01D2257/102B01D2257/502B01D2257/504B01D2259/40007B01D2259/40052B01D2259/40064B01D2259/40081B01D2259/4061C01B3/56C01B2203/043C01B2203/047Y02C10/08Y02P20/152
    • Adjusted gas compositions having two or more components in desired proportions for particular industrial uses are obtained from available feed gas mixtures accompanied by recovery of one or more valuable indi­vidual gases of high purity, by a novel selective adsorption-desorption scheme carried out in a multi-column PSA system. Following initial ad­sorption of one or more components from the feed gas mixture at high pressure the sorbate-laden column is subjected to a high pressure rinse using as rinse gas the previously recovered more strongly adsorbed spe­cies. After the rinsing step, the column is depressured to a selected level and purged with part of the unsorbed gas effluent discharged during the initial adsorption step until a preset amount of the earlier sorbed gas is recovered in the purge effluent as the readjusted binary gas mix­ture of desired proportions. As an example, there is disclosed the pro­duction from a starting gas mixture rich in hydrogen and carbon monoxide, such as that obtained from steam-methane reforming, an industrially use­ful gas mixture having a desired H₂/CO ratio with the accompanying in­dividual recovery of high purity hydrogen and carbon monoxide as by-prod­ucts.
    • 具有用于特定工业用途所需的比例两种或多种组分调整气体组合物由伴随着高纯度的一种或多种有价值的单一气体的回收可用的进料气体混合物获得,通过在多进行了新的选择性吸附 - 解吸方案 柱PSA系统。继高压初始吸附来自进料气体混合物的一种或多种组分的吸附物载货列使用先前回收的更强烈吸附的物种作为冲洗气体经受高压冲洗。 在漂洗步骤后,将柱器降压到一个选定的水平,并与在初始吸附步骤,直到此前吸附气体的预设量排出的未吸附的气体流出物的一部分吹扫在清洗排出回收作为的调整二元气体混合物 期望中的比例。 如在实施例中,存在盘游离缺失从原料气体混合物富含氢和一氧化碳生产,谋求作为没有从蒸汽 - 甲烷获得重整,在工业上有用的气体混合物具有的高相应的单独回收所需的H 2 / CO比 纯度氢气和一氧化碳作为副产物。