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1. 发明授权

EP0381122B2 Two stage polymerization of vinyl acetate/ethylene emulsion copolymers containing incompatible monomers 失效
标题翻译：乙酸乙烯酯/乙烯乳液共聚物与不相容的单体的两阶段聚合
公开(公告)号：EP0381122B2
公开(公告)日：1998-12-30
申请号：EP90101751.7
申请日：1990-01-29
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Goldstein, Joel Erwin , Mao, Chung-Ling , Iacoviello, John Generoso
IPC分类号： C08F263/04 , D04H1/64
CPC分类号： C08F263/04 , D04H1/587 , D04H1/64

2. 发明公开

EP0066174A2 Vinyl acetate-ethylene emulsions for nonwoven goods 有权
标题翻译： Vinylactetat - 乙烯乳液的非织造织物。
公开(公告)号：EP0066174A2
公开(公告)日：1982-12-08
申请号：EP82104320.5
申请日：1982-05-17
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso
IPC分类号： C08F218/08 , C08F210/02 , D06M15/263
CPC分类号： C08F218/08 , D04H1/587 , D04H1/64 , Y10T442/2484 , C08F210/02
摘要： This invention relates to a vinyl acetate-ethylene copolymer containing emulsion particularly adapted for the preparation of nonwoven goods. The vinyl acetate-ethylene emulsion is prepared by an improved process for producing an aqueous emulsion suitably adapted for producing non- woven goods said emulsion containing a vinyl acetate-ethylene copolymer wherein said copolymer contains from about 75-96% by weight of vinyl acetate. It is produced by forming an aqueous suspension of vinyl acetate, ethylene, and stabilizer, initiating the polymerization of the reaction mixture by the addition of catalysts, and adding from about 0.5-10% by weight of the vinyl acetate of a crosslinkable monomer. The improvement for enhancing the absorptivity of the copolymer comprises:

pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig;
initiating the reaction mixture by the addition of catalyst at a temperature from about 10-35 = C and bringing the reaction mixture to a reaction temperature of from 45-85°C and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20 c C;
adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and
continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.

3. 发明公开

EP0381122A3 Two stage polymerization of vinyl acetate/ethylene emulsion copolymers containing incompatible monomers 失效
标题翻译：乙酸乙烯酯/乙烯乳液共聚物的两阶段聚合含不相容单体
公开(公告)号：EP0381122A3
公开(公告)日：1991-07-31
申请号：EP90101751.7
申请日：1990-01-29
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Goldstein, Joel Erwin , Mao, Chung-Ling , Iacoviello, John Generoso
IPC分类号： C08F263/04 , D04H1/64
CPC分类号： C08F263/04 , D04H1/587 , D04H1/64
摘要： A two stage polymerization process for preparing a vinyl acetate emulsion copolymer containing a monomer which is normally incompatible with vinyl acetate. In the first stage the vinyl acetate, desirably ethylene and, optionally, an active crosslinking comonomer and/or latent crosslinking comonomer are free radical polymerized in the presence of a stabilizing system to yield a first stage polymer emulsion. When the free vinyl acetate monomer content of the first stage emulsion is less than about 5%, the second stage polymerization begins by adding the incompatible monomer. Preferably, there is no cessation of the addition of the free radical source during the transition from the first stage to the second stage polymerization. No additional stabilizing system is added to the reaction in the second stage. Vinyl acetate/ethylene/incompatible comonomer/latent crosslinking comonomer copolymers prepared by the two stage polymerization process are suitably used as binders for making nonwoven products.

4. 发明授权

EP0150059B1 Metal container coating compostions comprising stable emulsions of water resistant vinyl chloride-ethylene copolymers 失效
标题翻译：金属容器涂料组合物，包含耐水性乙烯基乙烯共聚物的稳定乳液
公开(公告)号：EP0150059B1
公开(公告)日：1989-08-02
申请号：EP85100504.1
申请日：1985-01-18
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso
IPC分类号： C09D3/74 , C08F214/06 , C08L27/06
CPC分类号： C08F214/06 , C09D127/06 , C08L2666/02

5. 发明公开

EP0296499A1 Polyvinyl alcohol-stabilized vinyl chloride-ethylene-hydroxyethyl acrylate copolymer emulsions having enhanced water and solvent resistant properties 失效
标题翻译：氯乙烯 - 乙烯 - 丙烯酸羟基乙酯共聚物的聚乙烯醇稳定化的乳液具有改进的水和溶剂的抗性。
公开(公告)号：EP0296499A1
公开(公告)日：1988-12-28
申请号：EP88109679.6
申请日：1988-06-16
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso , Hook, William Joseph , Vijayendran, Bheema R
IPC分类号： C08L27/06 , C08F214/06
CPC分类号： C08F214/06 , C08F14/06 , C08F210/02 , C08F220/26 , C08F2/30
摘要： An aqueous copolymer emulsion comprising a copolymer consisting essentially of vinyl chloride, ethylene and up to 10 wt% hydroxyalkyl (meth)acrylate colloidally dispersed in an aqueous medium. The copolymer demonstrates improved solvent resistance and metal adhesion, especially to low energy films.
摘要翻译：在wässrige共聚物乳液包括共聚物本质氯乙烯，乙烯和建立由10重量％的羟烷基（甲基）丙烯酸酯在wässrige介质胶状分散英寸该共聚物表现出改进的耐溶剂性和金属粘合性，爱特别是低能量膜。

6. 发明公开

EP0087803A3 Binder compositions for making nonwoven fabrics having good hydrophobic rewet properties 失效
标题翻译：用于制造具有良好的疏水性布莱特属性的非织造布的粘合剂组合物
公开(公告)号：EP0087803A3
公开(公告)日：1987-05-13
申请号：EP83101983
申请日：1983-03-01
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Cook, Gerald Robert , Iacoviello, John Generoso , Pinschmidt, Robert Krantz, Jr. , Davidowich, George
IPC分类号： D04H01/64 , A61L15/00
CPC分类号： A61L15/48 , D04H1/587 , D04H1/64 , Y10T442/671
摘要： A binder composition for nonwoven fabrics which comprises
(a) a fugitive base salt of a phosphate ester surfactant or a carboxylate surfactant, (b) a latex comprising a vinyl acetate-ethylene-olefinically unsaturated carboxylic acid interpolymer colloidally suspended in water, the interpolymer containing about 0.5 to 7.0 weight percent olefinically unsaturated carboxylic acid and sufficient ethylene to provide the interpolymer with a glass transition temperature of from about -30 to +20°C, and (c) a polyvalent metal complex compound comprising a polyvalent metal ion and counter ions or ligands which hinder interaction of the polyvalent metal ion with the carboxylate and phosphate groups of the surfactant and interpolymer at room temperature, but at elevated temperature permit such interaction because the counter ions or ligands are expelled or are replaced by the anionic group of the surfactant and interpolymer. Nonwoven fabrics, particularly diaper innerliners, bonded with such binder compositions possess good dry and wet tensile strengths and good low rewet properties.
摘要翻译：一种无纺布用粘合剂组合物，其包含（a）磷酸酯表面活性剂或羧酸盐表面活性剂的挥发性碱盐，（b）包含胶体悬浮在水中的乙酸乙烯酯 - 乙烯 - 不饱和羧酸互聚物的胶乳，所述共聚体含有约0.5至7.0重量％的烯属不饱和羧酸和足够的乙烯以提供互聚物，玻璃化转变温度为约-30℃至+ 20℃，和（c）包含多价金属离子的多价金属络合物和阻止多价金属离子与表面活性剂和互聚物的羧酸盐和磷酸基团在室温下的相互作用的抗衡离子或配体，但在升高的温度下允许这种相互作用，因为反离子或配体被排出或被阴离子基团表面活性剂和互聚物。与这种粘合剂组合物粘合的无纺布，特别是尿布内衬具有良好的干和湿拉伸强度和良好的低再湿性能。

7. 发明公开

EP0121864A3 Nonwoven products having low residual free formaldehyde content 失效
标题翻译：具有低残留免费甲醛含量的非诺沃产品
公开(公告)号：EP0121864A3
公开(公告)日：1984-12-05
申请号：EP84103437
申请日：1984-03-28
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso
IPC分类号： D21H03/38 , D04H01/64 , A61L15/00
CPC分类号： D21H17/45 , A61L15/24 , D04H1/587 , D04H1/64 , D21H17/35 , D21H17/36 , D21H17/37 , D21H17/39 , Y10T442/2885 , Y10T442/2893 , C08L33/26
摘要： A nonwoven product formed from a nonwoven web of fibers bonded together with a binder comprising an interpolymer of vinyl acetate/ethylene/N-methylol acrylamide/acrylamide, the interpolymer comprising about 5 to 40 wt % ethylene and an amount of N-methylol acrylamide and acrylamide which is about 3.0 to 10wt % of the interpolymer, the N-methylol acrylamide being about 1.75 to 3.5 wt % and the acrylamide about 1.25 to 8.25 wt %. Such nonwoven products have a low residual free formaldehyde content and good tensile properties.

8. 发明公开

EP0066174A3 Vinyl acetate-ethylene emulsions for nonwoven goods 有权
标题翻译：乙烯乙酸乙烯酯乳液用于非商品
公开(公告)号：EP0066174A3
公开(公告)日：1983-08-10
申请号：EP82104320
申请日：1982-05-17
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso
IPC分类号： C08F218/08 , D06M15/36 , C08F210/02
CPC分类号： C08F218/08 , D04H1/587 , D04H1/64 , Y10T442/2484 , C08F210/02
摘要： This invention relates to a vinyl acetate-ethylene copolymer containing emulsion particularly adapted for the preparation of nonwoven goods. The vinyl acetate-ethylene emulsion is prepared by an improved process for producing an aqueous emulsion suitably adapted for producing non- woven goods said emulsion containing a vinyl acetate-ethylene copolymer wherein said copolymer contains from about 75-96% by weight of vinyl acetate. It is produced by forming an aqueous suspension of vinyl acetate, ethylene, and stabilizer, initiating the polymerization of the reaction mixture by the addition of catalysts, and adding from about 0.5-10% by weight of the vinyl acetate of a crosslinkable monomer. The improvement for enhancing the absorptivity of the copolymer comprises:
pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10-35 = C and bringing the reaction mixture to a reaction temperature of from 45-85°C and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20 c C; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.

9. 发明授权

EP0561221B1 RF curable type I wood adhesive composition comprising vinyl acetate/NMA copolymer emulsions containing tetramethylol glycoluril 失效
标题翻译： RF固化性I型Holzklebzusammensetzung用含有甘脲乙酸乙烯酯/ N-羟甲基丙烯酰胺共聚物乳液。
公开(公告)号：EP0561221B1
公开(公告)日：1995-10-18
申请号：EP93103399.7
申请日：1993-03-03
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Iacoviello, John Generoso , Horwat, David William
IPC分类号： C09J151/08 , C09J131/04
CPC分类号： C09J151/00 , C08F218/08

10. 发明授权

EP0279384B1 Vinyl acetate-ethylene copolymer emulsions prepared in the presence of a stabilizing system of a low molecular weight polyvinyl alcohol and a surfactant 失效
标题翻译：在聚乙烯醇的稳定体系的存在下与低分子量和表面活性剂制备的醋酸乙烯酯 - 乙烯共聚物乳液。
公开(公告)号：EP0279384B1
公开(公告)日：1994-12-07
申请号：EP88102113.3
申请日：1988-02-12
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Lenney, William Edward , Iacoviello, John Generoso
IPC分类号： C08F218/08
CPC分类号： C08F218/08

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