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1. 发明公开

EP0087803A3 Binder compositions for making nonwoven fabrics having good hydrophobic rewet properties 失效
标题翻译：用于制造具有良好的疏水性布莱特属性的非织造布的粘合剂组合物
公开(公告)号：EP0087803A3
公开(公告)日：1987-05-13
申请号：EP83101983
申请日：1983-03-01
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Cook, Gerald Robert , Iacoviello, John Generoso , Pinschmidt, Robert Krantz, Jr. , Davidowich, George
IPC分类号： D04H01/64 , A61L15/00
CPC分类号： A61L15/48 , D04H1/587 , D04H1/64 , Y10T442/671
摘要： A binder composition for nonwoven fabrics which comprises
(a) a fugitive base salt of a phosphate ester surfactant or a carboxylate surfactant, (b) a latex comprising a vinyl acetate-ethylene-olefinically unsaturated carboxylic acid interpolymer colloidally suspended in water, the interpolymer containing about 0.5 to 7.0 weight percent olefinically unsaturated carboxylic acid and sufficient ethylene to provide the interpolymer with a glass transition temperature of from about -30 to +20°C, and (c) a polyvalent metal complex compound comprising a polyvalent metal ion and counter ions or ligands which hinder interaction of the polyvalent metal ion with the carboxylate and phosphate groups of the surfactant and interpolymer at room temperature, but at elevated temperature permit such interaction because the counter ions or ligands are expelled or are replaced by the anionic group of the surfactant and interpolymer. Nonwoven fabrics, particularly diaper innerliners, bonded with such binder compositions possess good dry and wet tensile strengths and good low rewet properties.
摘要翻译：一种无纺布用粘合剂组合物，其包含（a）磷酸酯表面活性剂或羧酸盐表面活性剂的挥发性碱盐，（b）包含胶体悬浮在水中的乙酸乙烯酯 - 乙烯 - 不饱和羧酸互聚物的胶乳，所述共聚体含有约0.5至7.0重量％的烯属不饱和羧酸和足够的乙烯以提供互聚物，玻璃化转变温度为约-30℃至+ 20℃，和（c）包含多价金属离子的多价金属络合物和阻止多价金属离子与表面活性剂和互聚物的羧酸盐和磷酸基团在室温下的相互作用的抗衡离子或配体，但在升高的温度下允许这种相互作用，因为反离子或配体被排出或被阴离子基团表面活性剂和互聚物。与这种粘合剂组合物粘合的无纺布，特别是尿布内衬具有良好的干和湿拉伸强度和良好的低再湿性能。

2. 发明公开

EP0133277A2 Vinyl acetate-ethylene binder composition having good wet tensile strength and low heat seal temperature for nonwoven products 失效
标题翻译：对于无纺布制品合适的粘合剂组合物具有良好湿抗张强度和低Heissverschweissungstemperatur。
公开(公告)号：EP0133277A2
公开(公告)日：1985-02-20
申请号：EP84108748.9
申请日：1984-07-24
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Mango, Phillip Anthony , Cook, Gerald Robert
IPC分类号： D04H1/64 , C08L31/04
CPC分类号： C08L31/04 , C08L2205/04 , D04H1/587 , D04H1/64 , Y10S428/913 , Y10T428/24994 , Y10T442/2738 , C08L2666/04
摘要： An emulsion composition is disclosed which provides a binder having good wet tensile strength and low heat seal temperature for nonwoven products which comprises an aqueous dispersion of a mixture consisting essentially of 50 to 95 wt% of a vinyl acetate-ethylene copolymer and 5 to 50 wt% of a vinyl acetate-ethylene-crosslinking monomer copolymer.

3. 发明公开

EP0133277A3 Vinyl acetate-ethylene binder composition having good wet tensile strength and low heat seal temperature for nonwoven products 失效
标题翻译：乙烯乙酸乙烯酯乙烯酯组合物，具有良好的湿润强度和低密度非密封性产品的温度
公开(公告)号：EP0133277A3
公开(公告)日：1988-08-31
申请号：EP84108748
申请日：1984-07-24
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Mango, Phillip Anthony , Cook, Gerald Robert
IPC分类号： D04H01/64 , C08L31/04
CPC分类号： C08L31/04 , C08L2205/04 , D04H1/587 , D04H1/64 , Y10S428/913 , Y10T428/24994 , Y10T442/2738 , C08L2666/04
摘要： An emulsion composition is disclosed which provides a binder having good wet tensile strength and low heat seal temperature for nonwoven products which comprises an aqueous dispersion of a mixture consisting essentially of 50 to 95 wt% of a vinyl acetate-ethylene copolymer and 5 to 50 wt% of a vinyl acetate-ethylene-crosslinking monomer copolymer.

4. 发明公开

EP0324382A3 Zirconium (III) salts as cure co-catalysts for nonwoven binders comprising acrylamidoglycolic acid 失效
标题翻译： ZIRCONIUM（III）作为包含丙烯酰胆酸的非挥发性粘合剂的固化CO催化剂
公开(公告)号：EP0324382A3
公开(公告)日：1990-08-08
申请号：EP89100175.2
申请日：1989-01-05
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Goldstein, Joel Erwin , Iacoviello, John Generoso , Hawn, Gary Gerald , Cook, Gerald Robert
IPC分类号： D04H1/64
CPC分类号： D04H1/64 , D04H1/587 , Y10T428/24826 , Y10T442/69
摘要： A crosslinkable anionic binder composition which comprises an emulsion copolymer containing acrylamldoglycolic acid (AGA) and a zirconium III salt of an alpha or beta hydroxycarboxylic acid, the pH of the composition being from about 1.5 to 4.5. Provided are nonwoven binder compositions which are stable for extended periods prior to application of the binder composition onto the nonwoven substrate and initiation of crosslinking by application of heat.

5. 发明授权

EP0133277B1 Vinyl acetate-ethylene binder composition having good wet tensile strength and low heat seal temperature for nonwoven products 失效
标题翻译：乙烯乙酸乙烯酯乙烯酯组合物，具有良好的湿润拉伸强度和低热密封温度
公开(公告)号：EP0133277B1
公开(公告)日：1991-04-03
申请号：EP84108748.9
申请日：1984-07-24
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Mango, Phillip Anthony , Cook, Gerald Robert
IPC分类号： D04H1/64 , C08L31/04
CPC分类号： C08L31/04 , C08L2205/04 , D04H1/587 , D04H1/64 , Y10S428/913 , Y10T428/24994 , Y10T442/2738 , C08L2666/04

6. 发明公开

EP0324382A2 Zirconium (III) salts as cure co-catalysts for nonwoven binders comprising acrylamidoglycolic acid 失效
标题翻译：锆（III）盐作为固化Amidoglykolsäure粘合剂的非织造织物含有Co的催化剂。
公开(公告)号：EP0324382A2
公开(公告)日：1989-07-19
申请号：EP89100175.2
申请日：1989-01-05
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Goldstein, Joel Erwin , Iacoviello, John Generoso , Hawn, Gary Gerald , Cook, Gerald Robert
IPC分类号： D04H1/64
CPC分类号： D04H1/64 , D04H1/587 , Y10T428/24826 , Y10T442/69
摘要： A crosslinkable anionic binder composition which comprises an emulsion copolymer containing acrylamldoglycolic acid (AGA) and a zirconium III salt of an alpha or beta hydroxycarboxylic acid, the pH of the composition being from about 1.5 to 4.5. Provided are nonwoven binder compositions which are stable for extended periods prior to application of the binder composition onto the nonwoven substrate and initiation of crosslinking by application of heat.
摘要翻译：可交联粘合剂组合物的乳液共聚物包含acrylamldoglycolic基乙醇酸（AGA）和α或β羟基羧酸的锆盐III，所述组合物从约1.5〜4.5为的pH的阴离子，其包括。本发明提供的无纺粘合剂组合物，其事先通过施加热来应用所述粘合剂组合物的到非织造基底和交联的引发是稳定的长时间。

7. 发明公开

EP0087803A2 Binder compositions for making nonwoven fabrics having good hydrophobic rewet properties 失效
标题翻译： Bindemittelzusammensetzungenfürdie Herstellung von nichtgewebten wasserabstossenden Vliesstoffen。
公开(公告)号：EP0087803A2
公开(公告)日：1983-09-07
申请号：EP83101983.1
申请日：1983-03-01
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Cook, Gerald Robert , Iacoviello, John Generoso , Pinschmidt, Robert Krantz, Jr. , Davidowich, George
IPC分类号： D04H1/64 , A61L15/00
CPC分类号： A61L15/48 , D04H1/587 , D04H1/64 , Y10T442/671
摘要： A binder composition for nonwoven fabrics which comprises

(a) a fugitive base salt of a phosphate ester surfactant or a carboxylate surfactant,
(b) a latex comprising a vinyl acetate-ethylene-olefinically unsaturated carboxylic acid interpolymer colloidally suspended in water, the interpolymer containing about 0.5 to 7.0 weight percent olefinically unsaturated carboxylic acid and sufficient ethylene to provide the interpolymer with a glass transition temperature of from about -30 to +20°C, and
(c) a polyvalent metal complex compound comprising a polyvalent metal ion and counter ions or ligands which hinder interaction of the polyvalent metal ion with the carboxylate and phosphate groups of the surfactant and interpolymer at room temperature, but at elevated temperature permit such interaction because the counter ions or ligands are expelled or are replaced by the anionic group of the surfactant and interpolymer.

Nonwoven fabrics, particularly diaper innerliners, bonded with such binder compositions possess good dry and wet tensile strengths and good low rewet properties.
摘要翻译：一种无纺布用粘合剂组合物，其包含（a）磷酸酯表面活性剂或羧酸盐表面活性剂的挥发性碱盐，（b）包含胶体悬浮在水中的乙酸乙烯酯 - 乙烯 - 不饱和羧酸互聚物的胶乳，所述共聚体含有约0.5至7.0重量％的烯属不饱和羧酸和足够的乙烯以提供互聚物，玻璃化转变温度为约-30℃至+ 20℃，和（c）包含多价金属离子的多价金属络合物和阻止多价金属离子与表面活性剂和互聚物的羧酸盐和磷酸基团在室温下的相互作用的抗衡离子或配体，但在升高的温度下允许这种相互作用，因为反离子或配体被排出或被阴离子基团表面活性剂和互聚物。与这种粘合剂组合物粘合的无纺布，特别是尿布内衬具有良好的干和湿拉伸强度和良好的低再湿性能。

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