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    • 5. 发明公开
    • Imaging element comprising a photopolymerizable composition and methods for producing lithographic plates therewith
    • 图像记录时,含有光聚合性组合物和用于生产与其平版印刷版的方法。
    • EP0653684A1
    • 1995-05-17
    • EP94202990.1
    • 1994-10-14
    • AGFA-GEVAERT naamloze vennootschap
    • Vermeersch, JohanDaems, EddieVan Damme, MarcLeenders, LucNouwen, TomUytterhoeven, HermanHendrickx, Peter
    • G03F7/34G03F7/11
    • G03F7/11G03F7/34
    • The present invention provides an imaging element comprising on a hydrophilic base a hydrophobic photopolymerizable composition capable of being irradiated with actinic light through the support and/or through the front and comprising at least one monomer and at least one polymeric binder, characterized in that said imaging element comprises on top of said photopolymerizable composition one or more protective layers selected from the group consisting of:

      a transfer layer which is capable of adhering to the underlying contiguous layer and to a receptor layer, said transfer layer, when being a thermoadhesive layer having a glas transition temperature T g between 1O °C and 100 °C as measured with the 1090 THERMOANALYZER of Du Pont Co. and a melt viscosity of more than 3000 Poise measured at 120 °C with the VISCOELASTIC MELT TESTER of Rheometrics Co, Surrey, UK.,
      and a receptor layer which is capable of adhering to the underlying contiguous layer and which is upperlying said transfer layer(s) if any is present, said receptor layer, when being the only protective layer in said imaging element being paper or a poly-Alpha-olefin coated paper.
    • 本发明提供一种成像元件上的亲水性基,其包含能够通过支撑和/或通过前用光化光照射和包含至少一种单体和至少一种聚合物粘合剂中的疏水性聚合性组合物,在所述成像特征的上 元件包括在选自下组中选择的。所述可光聚合的组合物的一个或多个保护层的顶部上:一个转移层的所有其能够粘附到下面的邻接层以及在受体层,所述转移层,当被具有一个热粘合层的 玻璃化转变温度1O℃,并作为测量用杜邦公司的1090热分析仪,在120℃下用流变钴,萨里,UK的粘弹性MELT测试仪测量超过3000泊的熔体粘度100℃之间的Tg。 和受体层中的所有其能够粘附到下面的邻接层的和所有其upperlying说TRANSF 他层(一个或多个),如果有的话,所述受体层,当处于所述摄像元件是纸或聚α-烯烃的涂布纸的唯一保护层。
    • 7. 发明公开
    • Method for preparation of a photothermographic material with increased photosensitivity
    • Verfahren zur Herstellung eines photothermographischen材料mit verbesserter Lichtempfindlichkeit
    • EP1345076A1
    • 2003-09-17
    • EP03100321.3
    • 2003-02-13
    • AGFA-GEVAERT
    • Uytterhoeven, HermanCallant, Paul
    • G03C1/498G03C1/10G03C1/09G03C1/22
    • G03C1/102C09B23/0008C09B23/0066C09B23/0075C09B23/086C09B23/102C09B23/105C09B23/107G03C1/09G03C1/22G03C1/49845G03C1/49854
    • A process for preparing a photothermographic material with increased photosensitivity, the photothermographic material comprising a support and a photo-addressable thermally developable element, exclusive of a compound R-S(M) n wherein R is an aliphatic hydrocarbon, aryl or heterocyclic group, M is a hydrogen atom, or cation, and letter n is a number determined so as to render the molecule neutral and also exclusive of a compound capable of releasing a mobile dye corresponding to or inversely corresponding to the reduction of silver halide to silver at elevated temperatures, the photo-addressable thermally developable element containing a photosensitive agent in catalytic association with a light-insensitive organic silver salt, a reducing agent for the light-insensitive organic silver salt in thermal working relationship therewith and a binder, comprising the steps of: (i) increasing the photosensitivity of a photosensitive silver halide by chemical sensitisation with a chemical sensitising merocyanine dye containing a thione group in a non-oxidative aqueous medium, optionally in the presence of the light-insensitive organic silver salt, thereby producing the photosensitive agent; (ii) coating the support with one or more aqueous solutions or dispersions together containing the light-insensitive organic silver salt, the photosensitive agent, the reducing agent and the binder; (iii) drying the coating or coatings thereby producing the photo-addressable thermally developable element.
    • 一种制备具有增加的光敏性的光热敏成像材料的方法,所述光热成像材料包含载体和光寻址热可显影元素,不包括化合物RS(M)n,其中R是脂族烃,芳基或杂环基,M是 氢原子或阳离子,并且字母n是为了使分子中性而且除了可以释放与升高的温度下的卤化银还原成银相反或相反地对应的可移动染料的化合物的数量, 包含与光不敏感有机银盐催化缔合的感光剂的光寻址热可显影元件,与其热处理关系的光不敏感有机银盐的还原剂和粘合剂,包括以下步骤:(i) 通过化学敏化增加光敏卤化银的感光度 任选在光不敏感的有机银盐存在下,在非氧化性水性介质中含有硫酮基团的部分花菁染料,从而制备感光剂; (ii)用一种或多种含有光不敏感有机银盐,感光剂,还原剂和粘合剂的水溶液或分散体涂覆载体; (iii)干燥涂层或涂层,从而产生可光寻址的热显影元件。
    • 8. 发明公开
    • Photothermographic recording material comprising IR-sensitizing dyes
    • 一种用于生产光热成像记录材料中,红外增感染料的过程
    • EP0821272A1
    • 1998-01-28
    • EP97201905.3
    • 1997-06-21
    • AGFA-GEVAERT N.V.
    • Deroover, GeertCallant, PaulUytterhoeven, Herman
    • G03C1/498G03C5/16G03C1/20G03C1/28
    • G03C1/28G03C1/20G03C1/49854G03C5/164
    • A photothermographic recording material comprising a support and a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized to wavelengths > 700nm with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a water-soluble binder, a water-dispersible binder or a mixture of a water-soluble and a water-dispersible binder, characterized in that the photothermographic recording material has an infra-red sensitivity of less than 80J/m 2 and the dye satisfies the following test: an exposure required by a photothermographic recording material A, consisting of a polyester 100µm thick support provided with a photo-addressable thermally developable element produced as described in the description and including the dye and a compound corresponding to the formula
      is > 90% of an exposure required by a photothermographic recording material B produced as described for the photothermographic recording material A except that the compound is omitted, the exposure of the materials A and B being that required to obtain an optical density in an exposed part thereof 0.5 higher than in an non-exposed part thereof when exposed to infra-red light to which it is sensitive and heating with a heat source at 105°C for 15s with the polyester support thereof in contact with the heat source; and a production process therefor.
    • 一种光热图形记录材料包含载体和可光寻址热显影元件包含一个基本上光不敏感的有机银盐,还原剂为此在热工作关系那里,感光卤化银光谱增感波长> 700nm的用染料和在催化 与基本上非感光的有机银盐和水溶性粘合剂,水分散性的粘合剂或一种水溶性和水分散性粘合剂的混合物,在没有照片特征的关联热图形记录材料具有对红外灵敏度 的小于80J /米<2>和染料SATIS外资企业以下测试:通过光热成像图形记录材料的必需的曝光,其中包括设置有产生的光可寻址热显影元件的聚酯100微米厚的支持体,如所描述的 说明和包括染料和对应于下式的化合物是> 90%的作为除DASS光热敏成像图形记录材料A中所描述制造的光热成像图像记录材料B所需要的曝光的模具省略化合物,被没有所需的材料A的曝光和B中以获得在光密度在露出部分及其0.5 中比在非曝光部分其当暴露于红外光更高其所敏感中并在105℃的热源,用于与聚酯支撑在与热源接触其15S; 和其制造方法。
    • 10. 发明公开
    • Thermal transfer printing of a reducing agent to a silver source contained in an image receiving layer
    • 通过在图像接收层含有银组的还原剂热转移印刷方法
    • EP0706080A1
    • 1996-04-10
    • EP94201827.6
    • 1994-06-27
    • AGFA-GEVAERT naamloze vennootschap
    • Van Damme, MarcUytterhoeven, HermanDefieuw, Geert
    • G03C1/498B41M5/32B41M5/38B41M5/00
    • G03C1/4989
    • The present invention discloses a thermal imaging process using (i) a donor element comprising on a support a donor layer containing a binder and a thermotransferable reducing agent capable of reducing a silver source to metallic silver upon heating and (ii) a receiving element comprising on a support in the order given a receiving layer and a curable layer, said receiving layer comprising a silver source capable of being reduced by means of heat in the presence of a reducing agent for said silver source and a binder, said thermal imaging process comprising the steps of

      bringing said donor layer of said donor element into face to face relationship with said receiving layer of said receiving element,
      image-wise heating a thus obtained assemblage, thereby causing image-wise transfer of an amount of said thermotransferable reducing agent to said receiving element in accordance with the amount of heat supplied,
      separating said donor element from said receiving element,
      curing said release layer and
      overall heating said receiving element.
    • 本发明光盘使用(i)的供体元件上的支撑件,包括一供体层包含粘合剂和热可转移还原剂能够在加热时和(ii)包含在接收元件还原银源为金属银的松热成像过程 在给定的接收层和固化性层的次序的支撑件,所述接收层,其包含能够被还原通过加热在所述银源和粘合剂的还原剂的存在下,银源,所述热成像方法包括 使所述供体元件的所述施主层进入面的步骤,以面对所述接收所述的层接收元件,图像状加热由此获得的组合,从而使得接收所述热转移还原剂的量的图像方式转移到所述关系 在与供给热量从所述接收元件,固化所述释放分离所述施主元件的量雅舞蹈元件 层和整体加热所述接收元件。