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    • 4. 发明公开
    • Dyes and dye-donor elements for thermal dye transfer recording
    • 用于热染料转印记录的染料和染料供体元件
    • EP0788891A1
    • 1997-08-13
    • EP96200257.2
    • 1996-02-06
    • AGFA-GEVAERT naamloze vennootschap
    • Vanmaele, Luc
    • B41M5/38C09B26/06C09B29/00C09B55/00
    • B41M5/385B41M5/388B41M5/39C09B26/06C09B29/0059C09B55/003D06P5/006
    • The present invention provides a dye corresponding to the following general formula (I) and a dye-donor element for use according to thermal dye sublimation transfer. The dye-donor element comprises a support having thereon a dye layer comprising a polymeric binder and a dye corresponding to said general formula (I):
      wherein:

      A represents an electron withdrawing groups, e.g. CN, NO 2 , alkanoyl, alkenoyl, alkynoyl, aroyl, alkylsulphonyl, alkenylsulphonyl, alkynylsulphonyl, arylsulphonyl, carboxylic ester, carboxyl amide;
      Z represents hydrogen or a substituent,

      X represents N-R or
      R represents NR 3 R 4 or the residue of an aromatic coupling compound R-Q wherein Q is a group displaceable by a diazotised amine;
      R 1 represents NR 3 R 4 , OR 12 or SR 12 ;
      R 2 represents hydrogen, cyano, COR 13 , CO 2 R 13 , CONR 14 R 15 , SO 2 R 16 ;
      R 3 and R 4 each independently represent hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group or R 3 and R 4 together with the nitrogen atom to which they are attached represent the atoms necessary to complete a ring or R 3 and/or R 4 and one of the Y-substituents together with the atoms to which they are attached represent the necessary atoms to form a 5- or 6- membered, fused-on heterocyclic ring;
      Y represents a substituent, e.g. SH, OH, an amino group, a halogen, CN, NO 2 , an alkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a thioalkoxy group, a carbamoyl group, a sulfamoyl.
    • 本发明提供对应于以下通式(I)的染料和根据热染料升华转印使用的染料给体元素。 所述染料供体元件包括其上具有染料层的载体,所述染料层包含聚合物粘合剂和对应于所述通式(I)的染料:其中:A表示吸电子基团,例如吸电子基团。 CN,NO2,烷酰基,烯酰基,炔酰基,芳酰基,烷基磺酰基,烯基磺酰基,炔基磺酰基,芳基磺酰基,羧酸酯,羧基酰胺; Z代表氢或取代基,X代表N-R或R代表NR3R4或芳族偶联化合物R-Q的残基,其中Q是可被重氮化胺置换的基团; R1代表NR3R4,OR12或SR12; R2代表氢,氰基,COR13,CO2R13,CONR14R15,SO2R16; R3和R4各自独立地表示氢,烷基,烯基,炔基,芳基,杂环基或R3和R4与它们所连接的氮原子一起代表完成环所需的原子或 R3和/或R4和Y-取代基之一与它们所连接的原子一起代表形成5-或6-元稠合杂环的必要原子; Y代表取代基,例如 SH,OH,氨基,卤素,CN,NO 2,烷基,链烯基,炔基,烷氧基,硫代烷氧基,氨基甲酰基,氨磺酰基。
    • 7. 发明公开
    • Dyes and dye-donor elements for thermal dye transfer recording
    • 和在热染料转印的染料供体元件的染料,
    • EP0701906A1
    • 1996-03-20
    • EP94202634.5
    • 1994-09-13
    • AGFA-GEVAERT naamloze vennootschap
    • Vanmaele, Luc
    • B41M5/38C09B26/06C09B29/00C09B55/00C07D513/04
    • B41M5/3856B41M5/388B41M5/39C07D513/04C09B26/06C09B29/0074C09B43/003C09B55/003Y10S428/913Y10S428/914Y10S430/146
    • The present invention provides a dye-donor element for use according to thermal dye sublimation transfer. The dye-donor element comprises a support having thereon a dye layer comprising a polymeric binder and a dye corresponding to the following general formula (I):

      wherein :
      Z represents hydrogen or a substituent,
      X represents N-R or

      R represents NR³R⁴ or the residue of an aromatic coupling compound E-Q wherein Q is a group displaceable by a diazotised amine;
      R¹ represents NR³R⁴, OR¹² or SR¹²;
      R² represents hydrogen, cyano, COR¹³, CO₂R¹³, CONR¹⁴R¹⁵, SO₂R¹⁶;
      R³ and R⁴ each independently represent hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an a heterocyclic group or R³ and R⁴ together with the atoms to which they are attached represent the atoms necessary to complete a ring;
      Y represents a substituent;
      n represents 0, 1, 2, 3 or 4, the substituents being the same or different when n is greater than 1 or two or more Y substituents can form an annelated ring system;
      R¹², R¹³, R¹⁴ and R¹⁵ each independently represent hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic ring or R³ and R⁴ together with the atoms to which they are attached represent the necessary atoms to form a 5- or 6-membered ring or R³ and/or R⁴ together with the atoms to which they are attached and one of the Y-substituents represent the necessary atoms to form a 5- or 6- membered, fused-on heterocyclic ring or R¹⁴ and R¹⁵ together with the atoms to which they are attached represent the necessary atoms to form a 5- or 6- membered ring or R¹³ or R¹⁴ or R¹⁵ or R¹⁴ and R¹⁵ together with one of the Y-substituents and the atoms to which they are attached represent the necessary atoms to form a 5- or 6-membered fused-on heterocyclic ring;
      R¹⁶ represents hydroxy, an alkoxy group, an aryloxy group, NR¹⁷R¹⁸, an aryl group or an alkyl group, an alkenyl group, an alkynyl group, or R¹⁶ together with one of the Y-substituents and the atoms to which they are attached represent the necessary atoms to form a 5- or 6-membered fused-on heterocyclic ring;
      R¹⁷ and R¹⁸ each independently represent hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic ring or R¹⁷ and R¹⁸ together with the atoms to which they are attached represent the necessary atoms to form a 5- or 6-membered ring.
      The present invention further provides a method for making an image using the aforementioned dye donor element.
    • 本发明提供了用于使用雅丁到热染料升华转印的染料供体元件。 该染料供体元件包括在其上的染料层具有包含聚合物粘合剂和一种染料对应于下述通式(I)的支持: worin位:Z darstellt氢或取代基,X darstellt NR或ř darstellt NR <3> [R <4>或芳族偶合化合物EQ worin Q是由重氮化的胺的基团可移位的残基; [R <1>表示NR <3> [R <4>或<1> <2>或SR <1> <2>; [R <2> darstellt氢,氰基,COR <1> <3>,CO 2 <1> <3>,CONR <1> <4> - [R <1> <5>,SO 2 <1> <6>; [R <3>和R <4>每个unabhängig表示在烷基氢,在链烯基与原子向其炔基于芳基,以一个杂环基团或R <3>和R <4>一起 它们所连接代表原子必要完成环; Y代表的取代基; Ñdarstellt 0,1,2,3或4,取代基可以相同或不同,当n是大于1个或者两个或更多个Y取代基可以形成在Anne迟来环体系; [R <1> <2>,R <1> <3>,R <1> <4>和R <1> <5>各自独立地表示氢,上的烷基,在链烯基,在炔基与芳基 基,杂环,或R <3>和R <4>连同原子它们所连接代表了必要的原子形成5-或6-元环,或R <3>和/或R <4> 连同原子它们所连接和Y取代基中的一个所代表的必要原子形成5-或6-元,稠合的杂环或R <1> <4>和R <1> <5 >连同原子它们所连接表示的必要原子形成5-或6-元环,或R <1> <3>或R <1> <4>或R <1> <5>或R <1> <4>和R <1> <5>与Y取代基中的一个和的原子一起与它们所连接所代表的必要原子形成5-或6-元稠合的杂环; [R <1> <6> darstellt羟基于烷氧基,在芳氧基,NR <1> <7> - [R <1> <8>,在芳基或烷基上的基团,在链烯基,在炔基,或 [R <1> <6>与Y取代基中的一个和的原子一起与它们所连接所代表的必要原子形成5-或6-元稠合的杂环; [R <1> <7>和R <1> <8>各自独立地表示氢,上的烷基,在链烯基,在炔基与芳基烷基,杂环或R <1> <7>和R < 1> <8>使用的原子一起与它们所连接所代表的必要原子形成5-或6-元环。 本发明进一步提供了使用上述的染料供体元件制造图像的方法。
    • 10. 发明公开
    • Dyes and dye-donor elements for thermal dye transfer recording
    • Farbstoffe und Farbstoffdonorelemente zur thermischenFarbstoffübertragungsaufzeichnung
    • EP0794068A1
    • 1997-09-10
    • EP96200599.7
    • 1996-03-09
    • AGFA-GEVAERT naamloze vennootschap
    • Vanmaele, Luc
    • B41M5/38C09B56/02
    • B41M5/385B41M5/388B41M5/39B41M5/465C09B56/02D06P5/006
    • The present invention discloses a dye-donor element for use according to thermal dye sublimation transfer, said dye-donor element comprising a support having thereon a dye layer comprising a binder, preferably polymeric, and at least one dye, wherein said at least one dye corresponds to the following general formula (I) :
         wherein :

      A and B independently represent a heterocyclic ring;
      E represents the residue of an aromatic coupling compound E-Q wherein Q is a group displaceable by a diazotised amine;
      R 7 represents hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an aryloxy group, an alkoxy group, an alkylthio group, an amino group or an electron withdrawing group.
    • 本发明公开了一种根据热染料升华转移使用的染料供体元件,所述染料供体元件包括其上具有染料层的载体,所述染料层包含粘合剂,优选聚合物和至少一种染料,其中所述至少一种染料 对应于以下通式(I):其中:A和B独立地表示杂环; E表示芳族偶联化合物E-Q的残基,其中Q是可被重氮化的胺置换的基团; R 7表示氢,烷基,烯基,炔基,芳基,芳氧基,烷氧基,烷硫基,氨基或吸电子基。