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    • 7. 发明公开
    • VERFAHREN ZUR BESEITIGUNG VON N2O UND NOX AUS DEM PROZESS ZUR SALPETERSÄUREHERSTELLUNG UND DAFÜR GEEIGNETE ANLAGE
    • 程序的去除NOx N2O和过程OUT硝酸生产和合适的投资
    • EP2678270A1
    • 2014-01-01
    • EP12706771.8
    • 2012-02-14
    • ThyssenKrupp Uhde GmbH
    • SCHWEFER, MeinhardSIEFERT, RolfFUCHS, JürgenRUTHARDT, KlausGROVES, Michael
    • C01B21/26C01B21/38B01D53/86
    • C01B21/40B01D53/8628B01D53/869B01D2255/2065B01D2255/20738B01D2255/20746B01D2255/20761B01D2255/502B01D2255/504B01D2257/402B01D2257/404B01J29/072B01J29/46B01J29/68B01J29/7615B01J2229/42C01B21/265C01B21/38Y02C20/10Y02P20/153
    • The invention relates to a method for producing nitric acid by catalytically oxidising NH
      3 with oxygen and then reacting the obtained ΝΟ
      x with an absorption agent in an absorption tower, said tower comprising a catalyst bed for N
      2 O decomposition arranged in the process gas after the catalytic NH
      3 oxidation and before the absorption tower in the direction of flow, and a catalyst bed for ΝΟ
      x reduction and further N
      2 O reduction, arranged in the residual gas after the absorption tower in the direction of flow. In the catalyst bed for N
      2 O decomposition that is arranged in the process gas, as much N
      2 O as possible is broken down such that before the residual gas enters the catalyst bed for ΝΟ
      x reduction, the N
      2 O content is at > 100 ppmv and a molar N
      2 O/ΝΟ
      x ratio of > 0.25 is the result; the catalyst bed for ΝΟ
      x reduction and further N
      2 O reduction, arranged in the residual gas, containing at least one zeolite catalyst loaded with iron; there being such an amount of NH
      3 added to the residual gas prior to entry into the catalyst bed that upon exit from the catalyst bed, an ΝΟ
      x concentration of 2 O concentration of 2 O, formed during the catalytic NH
      3 oxidation, is catalytically removed in the process gas, with the ΝΟ
      x content being reduced and the N
      2 O content being further reduced in the residual gas, downstream of the absorption tower, and which is characterised in that at least the following elements are present: A) a reactor for the catalytic oxidation of NH
      3 with oxygen to produce a process gas containing ΝΟ
      x , B) an absorption tower for reacting the obtained ΝΟ
      x from the process gas with an absorption agent, a residual gas containing ΝΟ
      x and N
      2 O being the result, C) at least one first catalyst bed for N
      2 O decomposition through which the process gas flows and which is arranged after the catalytic NH
      3 oxidation and before the absorption tower in the direction of flow, D) at least one second catalyst bed for ΝΟ
      x reduction and further N
      2 O reduction, through which the residual gas flows and which is arranged after the absorption tower in the direction of flow, E) at least one device, for feeding a gaseous reduction agent into the residual gas, arranged after the absorption tower and before the second catalyst bed in the direction of flow, F) the first catalyst bed containing a catalyst for decomposing N
      2 O, and G) the second catalyst bed containing a catalyst which contains at least one zeolite loaded with iron. The method and installation allow N
      2 O and ΝΟ
      x emissions from nitric acid installations to be reduced in a particularly efficient manner.