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    • 4. 发明公开
    • ARTIFICIAL LEATHER AND BASE THEREFOR, AND PROCESSES FOR PRODUCTION OF BOTH
    • KUNSTLEDER UND GRUNDLAGEDAFÜRUND HERSTELLUNGSVERFAHRENFÜRBEIDES
    • EP1867779A1
    • 2007-12-19
    • EP06713187.0
    • 2006-02-07
    • Tradik Co. Ltd.Fleissner GmbH
    • OKADA, Hozuma
    • D06N3/00
    • D21H15/06B32B5/26D06N3/0004D06N3/0013D21H13/24D21H17/57
    • An artificial leather that feels like natural leather and a substrate for artificial leather are provided at low cost. A method for manufacturing the substrate for artificial leather includes the following: laminating an upper layer web, a fabric, and a lower layer web in the indicated order; subjecting the resultant laminate to hydroentanglement to form a non-woven fabric; and impregnating the non-woven fabric with an elastic polymer solution. The upper layer web is obtained by wet papermaking and drying, and includes a group of fibers having a fineness of 1 denier or less, a fiber length of 3 to 15 mm, and a basis weight of 20 to 150 g/m 2 and a water-soluble polymer. The fabric includes fibers having a fineness of 1 denier or more and has an air permeability of 3 to 250 cm 3 /cm 2 ·sec based on JIS L 1096 Method A. The lower layer web is obtained by wet papermaking and drying, and includes a group of fibers having a fineness greater than that of the upper layer web, a fiber length of 5 to 25 mm, and a basis weight of 50 to 200 g/m 2 and a water-soluble polymer filled into the lower layer web at a density higher than that of the upper layer web.
    • 以低成本提供感觉像天然皮革和人造皮革基材的人造革。 制造人造革用基材的方法包括以下顺序层叠上层织物,织物和下层织物; 对所得到的层压体进行水力缠结以形成无纺织物; 并用弹性聚合物溶液浸渍无纺织物。 通过湿造纸和干燥获得上层网,并且包括纤度为1旦以下,纤维长度为3〜15mm,基重为20〜150g / m 2的纤维,以及 水溶性聚合物。 该织物包含细度为1旦尼尔或更高的纤维,并且基于JIS L 1096方法A具有3至250cm 3 / cm 2·sec的透气度。下层纤维网通过湿法造纸和干燥获得,并且包括 一组纤维的纤度大于上层纤维网,纤维长度为5〜25mm,基重为50〜200g / m 2,水溶性聚合物填充在下层纤维网中 密度高于上层网的密度。
    • 7. 发明公开
    • PROCESS FOR THE PRODUCTION OF ARTIFICIAL LEATHER
    • VERFAHREN ZUR HERSTELLUNG VON KUNSTLEDER
    • EP0943726A1
    • 1999-09-22
    • EP98945605.8
    • 1998-10-05
    • Ichikintechnical Co., Ltd.Tradik Co. Ltd.
    • KAWAGUCHI, Hiroshi, Ichikintechnical Co., LtdIGARASHI, Toshiki
    • D06N3/00
    • D06N3/0081D06N3/0077D06N3/14
    • Artificial leather can be produced, without using any organic solvent, by coating or impregnating a fibrous base material to be formed into artificial leather with a polymer solution in the form of an aqueous emulsion, in which the polymer exhibits elasticity when it is solidified and adhered to the base material; and then solidifying and adhering or fixed, in the fibrous base material, the polymer solution contained in the base material using a combination of wet heat (using the heat of water vapor) and microwave heating. Therefore, the method is not harmful to the environment and permits the reduction of the degree of migration as compared with the conventional methods in which the solidification and adhesion or fixation are performed by dry heating while making use of hot air. The method also permits the formation of a product having clear voids (contact-free portions) formed between fibers in the fibrous base material and the impregnated polymer, the voids being indispensable to the handling or feeling of the artificial leather. The resulting product further has gas permeability due to the presence of numerous very fine pores formed by the release of water vapor generated during the solidification and adhesion or fixation of the polymer. There is also observed the presence of porous structures in the polymer solidified and adhered or fixed within the fibrous base material. In addition, the method permits the elimination of the shrinking step which is essential for the conventional processing steps and this correspondingly allows the simplification of the production process. Moreover, the method of the invention permits the reduction of the processing time and the improvement of the production efficiency.
    • 通过将水性乳液形式的聚合物溶液涂布或浸渍成人造皮革的纤维基材,可以在不使用任何有机溶剂的情况下制造人造革,其中当聚合物固化和粘附时,其表现出弹性 到基材; 然后使用湿热(使用水蒸汽的热)和微波加热的组合,在纤维基材中固化和粘合或固定包含在基材中的聚合物溶液。 因此,与使用热空气通过干燥加热进行凝固和粘合或固定的常规方法相比,该方法对环境无害并且允许降低迁移度。 该方法还允许形成在纤维基材中的纤维和浸渍聚合物之间形成的具有透明空隙(无接触部分)的产品,空隙对于人造革的处理或感觉是必不可少的。 所得到的产物由于存在许多非常细小的孔而进一步具有气体渗透性,这些孔通过在固化和聚合物的固化和固定期间产生的水蒸气的释放而形成。 还观察到聚合物中存在多孔结构物,固化并粘附或固定在纤维基材内。 此外,该方法允许消除对于常规加工步骤是必需的收缩步骤,并且相应地允许简化生产过程。 此外,本发明的方法允许减少处理时间并提高生产效率。