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    • 3. 发明公开
    • POLYMERIZABLE MONOMER COMPOSITION FOR DENTAL MATERIAL
    • 聚对苯二甲酸丁二醇酯
    • EP3135271A1
    • 2017-03-01
    • EP15774169.5
    • 2015-03-31
    • Mitsui Chemicals, Inc.Shofu Inc.SUN MEDICAL CO., LTD.
    • YOSHINAGA, KazuhikoNARUSE, HiroshiTERAMAE, MitsujiFUCHIGAMI, KiyomiFUJIMURA, HidefumiTSUCHIKAWA, MasujiIMAI, Hirofumi
    • A61K6/083A61C5/73A61K6/09
    • A61K6/083A61K6/0023A61K6/0073A61K6/0097A61K6/0835C07C271/20C07C2602/42C08L33/10
    • The invention provides dental polymerizable monomer compositions that can give cured products having high toughness and high rigidity, and provides dental compositions containing such dental polymerizable monomer compositions and cured products thereof having high mechanical properties.
      [Solution]
      The dental polymerizable monomer composition includes a urethane acrylate compound (A) and a polymerizable compound (B) having at least one polymerizable group selected from methacryloyl groups and acryloyl groups, the urethane acrylate compound (A) being obtained by reacting a specific hydroxyacrylate (a1) with a diisocyanate (a2) having two isocyanate groups bonded to a divalent C 6-9 aromatic hydrocarbon group or a divalent C 6-9 bridged cyclic hydrocarbon group via a methylene group optionally substituted with a hydrocarbon group in place of a hydrogen atom, the proportion of the number of acryloyl groups present in the urethane acrylate compound (A) being 10% to less than 90% relative to the total number of methacryloyl groups and acryloyl groups in the dental polymerizable monomer composition. The dental composition includes the dental polymerizable monomer composition.
    • 本发明提供了可以提供具有高韧性和高刚性的固化产物的牙科可聚合单体组合物,并提供含有这种可口可聚合单体组合物的牙科用组合物及其具有高机械性能的固化产物。 [解决方案]牙科可聚合单体组合物包括具有至少一个选自甲基丙烯酰基和丙烯酰基的可聚合基团的聚氨酯丙烯酸酯化合物(A)和可聚合化合物(B),所述聚氨酯丙烯酸酯化合物(A) 羟基丙烯酸酯(a1)与具有二价C 6-9芳香族烃基键合的两个异氰酸酯基的二异氰酸酯(a2)或任选被烃基取代的亚甲基代替二价C 6-9桥连环状烃基代替 氢原子,聚氨酯丙烯酸酯化合物(A)中存在的丙烯酰基的数量相对于可聚合单体组合物中的甲基丙烯酰基和丙烯酰基的总数为10〜小于90%。 牙科用组合物包括牙科可聚合单体组合物。
    • 4. 发明公开
    • EASILY REMOVABLE CURABLE COMPOSITION FOR DENTAL USE
    • LEICHT ENTFERNBAREHÄRTBAREZUSAMMENSETZUNG ZURZAHNÄRZTLICHENVERWENDUNG
    • EP2491915A1
    • 2012-08-29
    • EP10825090.3
    • 2010-10-22
    • SUN MEDICAL CO., LTD.
    • ORI TatsuyaNISHITANI HarukaIWASAKI SayuriYAMAMOTO YuyaNISHIMOTO Chidzuru
    • A61K6/00A61K6/06A61K6/08A61K6/083
    • A61K6/083A61K6/0023A61K6/0052C08L33/04
    • A dental curable composition whose polymerization is not impeded even in a moist environment and in the presence of oxygen and which has excellent marginal sealability and enables the provision of flexibility and the control of removability.
      The dental curable composition comprises (A) a polymerizable monomer and (B) an organic amine-based polymerization initiator, wherein (A') a long-chain polymerizable monomer having a chain length of 17 or more atoms is contained in the component (A) and/or (C) a soft resin material are/is contained in the composition, and when the amount (parts by weight) based on 100 parts by weight of the component (A) of the component (Aʹ) is represented by [aʹ] and the amounts (parts by weight) based on 100 parts by weight of the total of the components (A) and (B) of the components (A), (B) and (C) are represented by (a), (b) and (c), respectively, 70 ≦ (a) ≦ 99.99, 0.01 ≦ (b) ≦ 30,1 ≦ [aʹ]/5 + (c)/1, 0 ≦ [aʹ] ≦ 95, and 0 ≦ (c) ≦ 250.
    • 即使在潮湿环境和氧气存在下也不会阻碍其聚合并且具有优异的边缘密封性并且能够提供柔韧性和可移除性的控制的牙科用可固化组合物。 牙科用固化性组合物包含(A)可聚合单体和(B)有机胺基聚合引发剂,其中(A')具有17个或更多个链长的长链可聚合单体包含在组分(A )和/或(C)组合物中含有软质树脂材料,并且当基于100重量份组分(A 1)的组分(A)的量(重量份)由[ (A),(B)和(C)的组分(A)和(B)的总计100重量份的量(重量份)由(a)表示, (b)和(c)分别为70‰|(a)‰| 99.99,0.01‰|(b)‰| 30,1‰| [a¹] / 5 +(c)/ 1,0‰| [a¹ ]‰| 95,0‰|(c)‰| 250。
    • 10. 发明公开
    • EASILY REMOVABLE CURABLE COMPOSITION FOR DENTAL USE
    • 易于拆卸的固化性组合物的牙科用
    • EP2272486A4
    • 2014-04-30
    • EP09735616
    • 2009-04-24
    • SUN MEDICAL CO LTD
    • ORI TATSUYAYAMAMOTO AKARIARATA MASAMIYOSHIKAWA MAHO
    • A61K6/083
    • A61K6/0038C08L43/02C08L81/06C08L23/00
    • An easily removable dental curable composition which prevents the fall or leakage of a temporary prosthetic appliance or a root canal filling material which is easily removed by bonding and adhering it to tooth, shows such high flowability that its operation is easy, has a long working time and excellent X-ray contrast properties and sealability and can be easily removed as required, and a filling kit. The dental curable compositon comprises (A) a polymerizable monomer mixture containing a polymerizable monomer having an acid group in the molecule and (B) a polymerization initiator, wherein the component (A) contains (A') a long-chain polymerizable monomer having a structure with a chain length of 17 or more atoms and/or the composition further comprises (D1) a soft resin material; and when the amount of the component (A') based on 100 parts by weight of the component (A) is represented by [a'] and the amounts of the components (A), (B) and (D1) based on 100 parts by weight of the total of the components (A) and (B) are represented by (a), (b) and (d1), respectively, the following expressions (1) to (5) are satisfied: 70 ‰¦ a ‰¦ 99.99 0.01 ‰¦ b ‰¦ 30 1 ‰¦ a¹ / 5 + d �¢ 1 / 1 a¹ ‰¦ 95 d �¢ 1 ‰¦ 250