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    • 4. 发明公开
    • METHODS FOR REDUCING SOLUBLE METAL IONS IN DIATOMACEOUS EARTH FILTER AIDS
    • VERFAHREN ZUR REDUZIERUNG DES ANTEILSLÖSLICHERMETALLIONEN IN KIESELGURFILTER-HILFSVORRICHTUNGEN
    • EP2547757A1
    • 2013-01-23
    • EP11710370.5
    • 2011-03-11
    • Miller Brewing International, Inc.
    • TING, Patrick, L.SAUNDERS, Fran, L.DANNENBERG, Rhonda, M.LAUMANN, Jacqueline, A.EPLETT, John, T.CASEY, Gregory, P.RYDER, David, S.
    • C12H1/04B01J20/14B01D39/06
    • B01J20/14B01D39/06C12H1/0408
    • A method for reducing the amount of beverage soluble metal ions in a diatomaceous earth filter aid is disclosed. The beverage soluble metal ions can be copper and/or iron. In the method, the diatomaceous earth filter aid is contacted with a hop compound selected from iso-alpha-acids, dihydroiso-alpha-acids, tetrahydroiso-alpha-acids, hexahydroiso-alpha-acids, alpha-acids, and beta-acids. The diatomaceous earth filter aid can also be contacted with and an acid other than the hop compound such as phosphoric acid. The iso-alpha-acids, dihydroiso-alpha-acids, tetrahydroiso-alpha-acids, hexahydroiso-alpha-acids, alpha-acids, or beta- acids bind the copper and iron metal ions and/or change the form of copper and iron in diatomaceous earth so the copper and iron are rendered substantially insoluble in a beverage such as beer. A method for filtering a beverage using the treated diatomaceous earth filter aid is also disclosed. A method for increasing the flavor stability of a malt beverage filtered with a diatomaceous earth filter aid is also disclosed.
    • 公开了一种减少硅藻土助滤剂中饮料可溶性金属离子的量的方法。 饮料可溶性金属离子可以是铜和/或铁。 在该方法中,硅藻土助滤剂与选自异-α-酸,二氢异-α-酸,四氢异-α-酸,六氢异-α-酸,α-酸和β-酸的跳跃化合物接触。 硅藻土助滤剂也可以与除磷酸等啤酒花化合物以外的酸接触。 异-α-酸,二氢异-α-酸,四氢异-α-酸,六氢异-α-酸,α-酸或β-酸结合铜和铁的金属离子和/或改变铜和铁的形式 在硅藻土中,铜和铁基本上不溶于饮料如啤酒。 还公开了使用经处理的硅藻土助滤剂对饮料进行过滤的方法。 还公开了一种增加用硅藻土助滤剂过滤的麦芽饮料的风味稳定性的方法。
    • 5. 发明公开
    • PREPARATION OF HOP ACIDS AND THEIR DERIVATIVES
    • 达芙蓉达人的ZUBEREITUNG VONHOPFENSÄUREN
    • EP2571974A1
    • 2013-03-27
    • EP11726002.6
    • 2011-05-20
    • Miller Brewing International, Inc.
    • TING, Patrick, L.PRATT, JasonRYDER, David, S.
    • C12C3/08C12C3/12
    • C07C49/713A61K31/122C07C45/85C12C3/12C12C5/026C07C49/743
    • A method for preparing a hop acid mixture having an enantiomeric excess of a (+)-tetrahydro-α-acid is disclosed. In the method, a racemate of a tetrahydro-α-acid is contacted with an amine to form a precipitate having an enantiomeric excess of the (+)-tetrahydro-α-acid. A method for preparing a hop acid is also disclosed. In the method, a racemate of a tetrahydro-α-acid is contacted with an amine to form a precipitate comprising a (+)-tetrahydro-α-acid, and the (+)-tetrahydro-α-acid is isomerized to a hop acid selected from the group consisting of (+)-trans-tetrahydro-iso-α-acids, (−)-cis-tetrahydro-iso-α-acids, and mixtures thereof, and reduced to (+)-trans-hexahydroiso-α-acids and (−)-cis-hexahydroiso-α-acids. An additive for flavoring a malt beverage is also disclosed. The additive includes a bittering agent selected from the group consisting of (+)-trans-tetrahydro-iso-α-acids, (−)-cis-tetrahydro-iso-α-acids, (+)-trans-hexahydroiso-α-acids, (−)-cis-hexahydroiso-α-acids, and mixtures thereof.
    • 公开了一种制备具有对映体过量的(+) - 四氢-α-酸的啤酒花酸混合物的方法。 在该方法中,四氢-α-酸的外消旋体与胺接触以形成具有对映体过量的(+) - 四氢-α-酸的沉淀。 还公开了一种制备啤酒花酸的方法。 在该方法中,将四氢-α-酸的外消旋体与胺接触以形成包含(+) - 四氢-α-酸的沉淀物,并将(+) - 四氢-α-酸异构化为啤酒花 选自(+) - 反 - 四氢 - 异α-酸,( - ) - 顺 - 四氢 - 异α-酸及其混合物的酸,并且还原为(+) - 反六氢异构体 - α-酸和( - ) - 顺 - 六氢异-α-酸。 还公开了一种用于调味麦芽饮料的添加剂。 添加剂包括选自(+) - 反 - 四氢 - 异α-酸,( - ) - 顺 - 四氢 - 异α-酸,(+) - 反六氢异-α-酸的苦味剂, 酸,( - ) - 顺 - 六氢异-α-酸及其混合物。