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    • 5. 发明公开
    • LATENT ACIDS AND THEIR USE
    • LATENTESÄURENUND IHRE VERWENDUNG
    • EP2539316A1
    • 2013-01-02
    • EP11702482.8
    • 2011-02-10
    • BASF SE
    • YAMATO, HitoshiASAKURA, ToshikageMATSUMOTO, AkiraTANAKA, KeitaNISHIMAE, Yuichi
    • C07C309/08C07C309/12C07C311/53C07C333/06C07C381/12C07C25/18G03F7/004G03F7/039C07D209/00C07D241/00C07D265/00C07D311/00C07D235/00
    • C07C381/12C07C25/18C07C309/08C07C309/12C07C311/53C07C333/06C07C2601/14C07C2602/42C07C2603/74C07D207/28C07D233/38C07D241/08C07D295/205C07D295/215C07D493/08G03F7/0045G03F7/0046G03F7/0382G03F7/0392
    • The invention pertains to a compound generating an acid of the formula (I) or (II), for instance corresponding sulfonium and iodonium salts, as well as corresponding sulfonyloximes, Formula (I) and Formula (II), wherein X is CH
      2 or CO; Y is O, NR
      4 , S, O(CO), O(CO)O, O(CO)NR
      4 , OSO
      2 , O(CS), or O(CS)NR
      4 ; R
      1 is for example C
      1 -C
      18 alkyl, C
      1 -C
      10 haloalkyl, C
      2 -C
      12 alkenyl, C
      4 -C
      30 cycloalkenyl, phenyl-C
      1 -C
      3 -alkyl, C
      3 -C
      30 cycloalkyl, C
      3 -C
      30 cycloalkyl-C
      1 -C
      18 alkyl, interrupted C
      2 -C
      18 alkyl, interrupted C
      3 -C
      30 cycloalkyl, interrupted C
      3 -C
      30 cycloalkyl-C
      1 -C
      18 alkyl, interrupted C
      4 -C
      30 cycloalkenyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or heteroaryl, all unsubstituted or are substituted; or R
      1 is NR
      12 R
      13 ; R
      2 and R
      3 are for example C
      3 -C
      30 cycloalkylene, C
      3 -C
      30 cycloalkyl-C
      1 -C
      18 alkylene, C
      1 -C
      18 alkylene, C
      1 -C
      10 haloalkylene, C
      2 -C
      12 alkenylene, C
      4 -C
      30 cycloalkenylene, phenylene, naphthylene, anthracylene, phenanthrylene, biphenylene or heteroarylene; all unsubstituted or substituted; R
      4 is for example C
      3 -C
      30 cycloalkyl, C
      3 -C
      30 cycloalkyl-C
      1 -C
      18 alkyl, C
      1 -C
      18 alkyl, C
      1 -C
      10 haloalkyl, C
      2 -C
      12 alkenyl, C
      4 -C
      30 cycloalkenyl, phenyl-C
      1 -C
      3 -alkyl; R
      12 and R
      13 are for example C
      3 -C
      30 cycloalkyl, C
      3 -C
      30 cycloalkyl-C
      1 -C
      18 alkyl, C
      1 -C
      18 alkyl, C
      1 -C
      10 haloalkyl, C
      2 -C
      12 alkenyl, C
      4 -C
      30 cycloalkenyl, phenyl-C
      1 -C
      3 -alkyl, Ar, (CO)R
      15 , (CO)OR
      15 or SO
      2 R
      15 ; and Ar is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl or heteroaryl, all unsubstituted or substituted.
    • 本发明涉及产生式(I)或(II)的酸的化合物,例如相应的锍盐和碘鎓盐,以及相应的磺酰肟,式(I)和式(II),其中X是CH 2或CO ; Y是O,NR4,S,O(CO),O(CO)O,O(CO)NR4,OSO2,O(CS)或O(CS)NR4; R1是例如C1-C18烷基,C1-C10卤代烷基,C2-C12链烯基,C4-C30环烯基,苯基-C1-C3-烷基,C3-C30环烷基,C3-C30环烷基-C1-C18烷基,间断的C 2 -C 18烷基,间断的C 3 -C 30环烷基, 间断的C 3 -C 30环烷基-C 1 -C 18烷基,间断的C 4 -C 30环烯基,苯基,萘基,蒽基,菲基,联苯基,芴基或杂芳基,全部未取代或被取代; 或R1为NR12R13; R 2和R 3例如为C 3 -C 30亚环烷基,C 3 -C 30环烷基-C 1 -C 18亚烷基,C 1 -C 18亚烷基,C 1 -C 10卤代亚烷基,C 2 -C 12亚烯基,C 4 -C 30亚环烯基,亚苯基,亚萘基,亚蒽基,亚菲基,亚联苯基或亚杂芳基。 全部未取代或取代; R4是例如C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12链烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基; R 12和R 13例如为C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基,Ar,(CO)R 15( CO)OR15或SO2R15; 并且Ar是苯基,联苯基,芴基,萘基,蒽基,菲基或杂芳基,全部是未取代或取代的。