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    • 86. 发明公开
    • NON-CHROME THIN ORGANIC-INORGANIC HYBRID COATING ON ZINCIFEROUS METALS
    • 铬薄膜不含有机 - 无机杂化涂层对含锌METALS
    • EP2064365A1
    • 2009-06-03
    • EP06792121.3
    • 2006-09-18
    • Henkel AG & Co. KGaA
    • SITTHICHAI Choed-AmpaiHONG, Jingxian
    • C23C22/36C23C22/42C23C22/44C09D5/00C09D5/08
    • C23C22/364C09D5/002C09D5/08C23C22/42C23C22/44Y10T428/273
    • The present invention relates to a treatment solution for the deposition of a thin organic/inorganic hybrid coating on a zinciferous metal surface, comprising water and (i) a concentration of phosphoric acid (A); (ii) a concentration of dissolved inorganic components (B) containing at least one complex fluoro metallate anion selected from the group of titanium, zirconium, hafnium and/or silicium, preferably hexafluorotitanic acid; (iii) a concentration of dissolved inorganic components (C) consisting of bivalent cations of zinc (C1) and/or manganese (C2); (iv) a concentration of a dissolved inorganic component (D) consisting of oxoanions of molybdenum; (v) a concentration of a water soluble and/or water dispersable polymeric compound (E) which is based on a chelating poly(vinylphenol) compound; (vi) a concentration of a water-soluble and/or water-dispersable polymeric resin (F) being not part of or identical with component (E). The thin organic/inorganic hybrid coating on the zinciferous metal surface is deposited according to this invention with a film weight of at least about 0.4 g/m2 and not more than about 1.6 g/m2 imparting to the coated material a temporary corrosion protection and excellent lack adhesion to further applied organic coatings. Additionally, the invention relates to the use of a zinciferous metal substrate coated with an organic/inorganic hybrid coating that provides a surface resistance of said coated substrate that is not more than 1.5 mΩ and preferably not more than 1 mΩ in industrial assembling and forming routines and for applying a multi-layer coating to said substrate in industrial metal surface finishing such as coil coating, car body painting lines, white goods and electronic housing production.