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81. 发明公开

EP1313685A1 CARBON MONOXIDE HYDROGENATION 有权
标题翻译：一氧化碳加氢
公开(公告)号：EP1313685A1
公开(公告)日：2003-05-28
申请号：EP01957406.0
申请日：2001-08-03
申请人： Exxonmobil Research and Engineering Company
发明人： KOVEAL, Russell, John , DAAGE, Michel, A.
IPC分类号： C07C1/04 , B01J23/75
CPC分类号： C10G2/33 , B01J25/00 , B01J25/04 , B01J38/60 , C07C1/045 , C07C1/049 , C07C2523/75 , C10G2/342 , Y02P20/584
摘要： A method is disclosed for enhancing the activity of a particulate Dispersed Active Metal (DAM) catalyst during operation of a reactor wherein the hydrogenation of carbon monoxide to produce a mixture of hydrocarbons is being carried out comprising withdrawing a mixture of hydrocarbons and a portion of the DAM catalyst from the reactor, reducing the hydrocarbon content thereof with hydrogen at a temperature above the temperature of the reactor, oxidizing a slurry of the catalyst particles in a suitable fluid at low temperature to form an oxidized precursor, reducing the precursor at elevated temperature to reform the catalyst and returning it to the reactor. The catalyst may be passivated before returning it to the reactor. The process is carried out until it is evident that the operation of the reactor will no longer be economical due to a decrease in catalyst performance or accumulation of fines at which point the catalyst is preferably renewed during operation of the reactor by a process comprising withdrawing a mixture ofhydrocarbon content thereof, heating the mixture above the melting temperature of at least one of the metals to form a melt, removing any slag that forms on the melt, cooling the melt to form a solid, reducing the particle size thereof to form a renewed particulate DAM catalyst, which is then returned to the reactor.
摘要翻译：公开了一种在反应器操作过程中增强颗粒状分散活性金属（DAM）催化剂活性的方法，其中一氧化碳加氢生成烃混合物包括将烃混合物和一部分来自反应器的DAM催化剂，在高于反应器温度的温度下用氢气还原其烃含量，在低温下在合适的流体中氧化催化剂颗粒的浆料以形成氧化的前体，在升高的温度下将前体还原至重整催化剂并将其返回反应器。催化剂在返回到反应器之前可以被钝化。进行该方法直至明显由于催化剂性能的降低或细粉的积累而使反应器的操作不再经济，此时催化剂优选在反应器操作期间通过包括以下步骤的方法更新：将其混合物加热，将混合物加热到至少一种金属的熔化温度以上以形成熔体，除去在熔体上形成的任何熔渣，冷却熔体以形成固体，减小其粒度以形成更新颗粒状DAM催化剂，然后将其返回反应器。

82. 发明授权

EP1034031B1 THROAT AND CONE GAS INJECTOR AND GAS DISTRIBUTION GRID FOR SLURRY REACTOR 有权
标题翻译：喷嘴颈部和锥体和气体分布污泥床反应器
公开(公告)号：EP1034031B1
公开(公告)日：2002-07-31
申请号：EP98952273.5
申请日：1998-10-14
申请人： ExxonMobil Research and Engineering Company
发明人： CHANG, Min , COULALOGLOU, Constantine, A. , HSU, Edward, C.
IPC分类号： B01J8/44 , B01J8/22 , C10G2/00
CPC分类号： C10G2/342 , B01J8/006 , B01J8/22 , B01J8/44
摘要： A gas distribution grid (106) for a slurry reactor includes a plurality of gas injectors (10) horizontally arrayed across, and extending through, an otherwise gas and liquid impervious plate (82). The injectors (10) have a throat (20) open at both ends, with a gas pressure reducing bore (14) at one end which is the entrance end and with the other end opening into an upward opening cone (30). Flow diverting means (26) in the injectors prevents slurry solids from entering the throat (20) and being attrited by the high velocity gas jet exiting the bore (14) into the throat (20). It is preferred that the gas injectors not protrude above the top surface of the grid and flat space is eliminated by means such as angular fillers (94), to prevent solids accumulation top of the grid. A chamfer (13) may be present at the junction of the bore and throat to prevent unrestricted expansion of the gas jet entering the throat. This is useful for injecting gas into a reactive hydrocarbon synthesis slurry in a slurry reactor, with reduced catalyst attrition and deactivation.

83. 发明公开

EP1027311A1 SLURRY HYDROCARBON SYNTHESIS WITH REDUCED CATALYST ATTRITION AND DEACTIVATION 有权
标题翻译：具有减少摩擦和DE催化剂MUD烃合成
公开(公告)号：EP1027311A1
公开(公告)日：2000-08-16
申请号：EP98952339.4
申请日：1998-10-16
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： CHANG, Min , COULALOGLOU, Constantine, Anastasious , HSU, Edward, Ching-Sheng , PEDRICK, Larry, Esteen
IPC分类号： C07C1/04 , C10G2/00 , B01J8/44 , B01J8/22
CPC分类号： C10G2/342 , B01J8/22 , B01J8/44 , C07C1/066
摘要： A slurry hydrocarbon synthesis process with reduced catalyst attrition is achieved by injecting a synthesis gas comprising a mixture of H2 and CO up into the reactive slurry with a gas distribution grid (106) having gas injectors (10) horizontally arrayed across, and vertically extending through, an otherwise gas and liquid impervious plate (32). The injectors (10) have a throat (20) with a gas pressure reducing orifice (12) at one end, which is the bottom and gas entrance end, and the other end opening into an open cone (30) in which the uprising gas contacts the slurry. Flow diverting means in the injectors prevents slurry from entering the throat (20) and being attrited. The gas injectors do not protrude above the top surface of the plate and flat space is eliminated by means such as angular fillers (94), to prevent solids accumulation top of the tray.

84. 发明公开

EP0938371A1 GAS SPARGER FOR A SUSPENSION REACTOR AND USE THEREOF 失效
标题翻译：气体分布器用于悬架反应器及其用途
公开(公告)号：EP0938371A1
公开(公告)日：1999-09-01
申请号：EP97909225.0
申请日：1997-08-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： VAN DER HONING, Geert , PELSEZ, Laurent, Bernard, Georges , VAN SWAAIJ, Willibrordus, Petrus, Maria
IPC分类号： B01J8 , C07B61 , C07C1 , C10G2
CPC分类号： C10G2/342 , B01J8/1818 , B01J8/22
摘要： The present invention relates to a gas sparger (31) for feeding gas into the suspension zone of a suspension reactor, which gas sparger (31) comprises a hollow body (32) equipped with a gas inlet (35) and having one or more gas outlet opening(s) (37), and a gas inlet valve body (40) which can be displaced relative to the hollow body (32) by the action of gas supplied through the gas inlet (35) from a closed position to an open position. The invention further relates to a suspension reactor containing at least one gas sparger (31) as described above, and to the use of the said suspension reactor in a process for carrying out an exothermic reaction involving one or more gaseous reactants. Moreover, the present invention relates to a process for the preparation of organic compounds from synthesis gas in the said suspension reactor.

85. 发明公开

EP0820806A1 Procédé et descriptif pour le fonctionnement d'une colonne à bulles triphasique avec application en synthese fischer-tropsch 无效
标题翻译：用气体 - 液体鼓泡塔和应用到费 - 托合成的方法
公开(公告)号：EP0820806A1
公开(公告)日：1998-01-28
申请号：EP97401637.0
申请日：1997-07-08
申请人： INSTITUT FRANCAIS DU PETROLE , Agip Petroli
发明人： Casanave, Dominique , Galtier, Pierre , Viltard, Jean-Charles
IPC分类号： B01J8/00 , B01J8/18 , B01J8/22 , C10G2/00
CPC分类号： C10G2/342 , B01J8/0005 , B01J8/1836 , B01J8/226 , B01J8/228 , B01J2208/00123 , B01J2208/00132 , B01J2208/0015 , B01J2208/00283
摘要： L'invention concerne un procédé permettant de faire fonctionner de manière optimale un réacteur triphasique à bulles contenant une suspension de particules solides au sein d'un liquide caractérisé en ce que l'on injecte, sous forme de bulles, à proximité de l'extrémité inférieure dudit réacteur (1) une phase gazeuse contenant le (ou les) réactif(s) nécessaire(s) à la production des produits recherchés et on recircule au moins une partie de la fraction liquide et éventuellement de la fraction solide de ladite suspension, prélevée à proximité d'une extrémité dudit réacteur et réintroduite à proximité de l'autre extrémité dudit réacteur, avec une vitesse du liquide U l au sein du réacteur au moins égale et de préférence supérieure à la vitesse de sédimentation Us des particules solides. L'invention concerne aussi un dispositif permettant le fonctionnement optimal dudit procédé. L'invention concerne enfin l'utilisation desdits procédé et dispositif en synthèse Fischer-Tropsch.
摘要翻译：单元，其包括一个立式反应器含有一个的固体悬浮液包含催化剂颗粒在液体中，besteht的： - （a）在所述反应器的下末端引入气体的装置; （B）排出点为在反应器的上端的气体; 和（c）一个排出点的悬浮液的一部分。所述单元包括用于暂停的在反应器中至少等于所述固体particles.The气体和悬浮液循环的沉降的速度的芯实现该悬浮液的UI的循环的速度的液体馏分的一部分的再循环手段逆流。

86. 发明公开

EP0676030A4 ENHANCED GAS SEPARATION FOR BUBBLE COLUMN DRAFT TUBES. 失效
标题翻译：改进的气体分离，鼓泡塔，ZUGRÖHREN。
公开(公告)号：EP0676030A4
公开(公告)日：1996-02-28
申请号：EP94904454
申请日：1993-12-15
申请人： EXXON RESEARCH ENGINEERING CO
发明人： CHANG MIN
IPC分类号： B01J8/22 , C10G2/00 , F27B15/08 , B01J8/20
CPC分类号： C10G2/342 , B01J8/226
摘要： Slurry bubble colums (1) equipped with downcomers which have high efficiency gas disengagement structure fitted on top of the slurry liquid reaction mixture comprising an inverted channel (8) having a gas vent (12) extending out of the apex (8c) of the inverted channel (8) and a liquid by-pass pipe (13) extending from the side of the inverted channel at a point below the apex (8c) to under the liquid level (9) and emptying into the downcomer. The inverted channel is fitted to the top of the downcomer and the bottom edge (8B) of which inverted channel is in contact with the surface of the slurry mixture in the slurry bubble column reaction zone. Improved catalyst distributing and circulation, mass and heat transfer results from catalyst in gas-lean slurry flowing through the liquid by-pass tubes (13) in the inverted channel and flowing into and down the downcomer to the bottom of the bubble column reactor. Hydrogen or any rejuvenating gas can be introduced into the bottom of the downcomer to restore catalyst activity as the catalyst moves down the downcomer.

87. 发明授权

EP0450859B1 Method of performing catalytic reaction in 3-phase slurry bubble column 失效
标题翻译：用于执行催化转化为三相鼓泡塔方法。
公开(公告)号：EP0450859B1
公开(公告)日：1995-07-05
申请号：EP91302709.0
申请日：1991-03-27
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： Herbolzheimer, Eric , Kaiser, Frederick John, Jr. , Iglesia, Enrique
IPC分类号： B01J8/22 , B01J8/32 , B01J8/34
CPC分类号： C10G2/342 , B01J8/22 , B01J8/32 , B01J8/34 , C07C1/0415 , C07C2521/06 , C07C2523/02 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75

88. 发明公开

EP0627958A1 CATALYTIC MULTI-PHASE REACTOR 失效
标题翻译：催化多级反应器。
公开(公告)号：EP0627958A1
公开(公告)日：1994-12-14
申请号：EP93905652.0
申请日：1993-02-24
申请人： DEN NORSKE STATS OLJESELSKAP A.S.
发明人： RYTTER, Erling , LIAN, Petter , MYRSTAD, Trond , ROTERUD, Per, T. , SOLBAKKEN, Age
IPC分类号： B01D29 , B01D36 , B01J8 , C07C1 , C10G2
CPC分类号： B01D29/115 , B01D29/605 , B01D29/665 , B01D29/72 , B01D29/86 , B01D29/92 , B01D36/001 , B01D2201/48 , B01J8/22 , C07C1/066 , C10G2/342
摘要： A reactor for conducting a continuous multi-phase catalytic reaction such as the conversion of syngas to higher hydrocarbon fuels. Gaseous reactants are introduced via a gas-permeable plate into a slurry which includes the product and a finely divided catalyst. The liquid product is separated from the remainder of the slurry by means of a filter unit including a filter member. A pressure differential is established across the filter member by means of a constant level device within the filter unit which maintains a level of filtrate within the filter unit below the level of the slurry. The slurry is maintained in a constant state of agitation by the introduction of the gaseous components as a steam of bubbles. Fluctuations in the pressure differential across the filter member prevent the filter member from clogging and the gas spaces above the filtrate and the slurry are in communication.

89. 发明授权

EP1668093B1 PROCESS FOR THE RUNNING OF A REACTOR SUITABLE FOR HETEROGENEOUS REACTIONS COMBINED WITH REACTIONS TAKING PLACE IN THREE-PHASE SYSTEMS 有权转让
公开(公告)号：EP1668093B1
公开(公告)日：2018-12-05
申请号：EP04765499.1
申请日：2004-09-17
申请人： ENI S.p.A. , IFP Energies nouvelles
发明人： MARETTO, Cristina , PEDERZANI, Giovanni
IPC分类号： C10G2/00
CPC分类号： C10G2/342 , C10G2/33
摘要： Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.

90. 发明授权

EP2664380B1 CATALYST RECOVERY SYSTEM, HYDROCARBON SYNTHESIS REACTION APPARATUS, HYDROCARBON SYNTHESIS REACTION SYSTEM, AND CATALYST RECOVERY METHOD 有权
公开(公告)号：EP2664380B1
公开(公告)日：2018-11-21
申请号：EP12734649.2
申请日：2012-01-13
申请人： Japan Oil, Gas and Metals National Corporation , INPEX Corporation , JXTG Nippon Oil & Energy Corporation , Japan Petroleum Exploration Co., Ltd. , Cosmo Oil Co., Ltd. , Nippon Steel & Sumikin Engineering Co., Ltd.
发明人： SHIBATA, Toshiyuki , HONDA, Hidekatsu , KAWAMURA, Akira
IPC分类号： B01J19/06 , B01D21/00 , B01J38/00 , B01J8/00 , C10G2/00
CPC分类号： B01J19/06 , B01D21/0045 , B01D21/0048 , B01J8/0045 , B01J38/00 , B01J2219/0077 , B01J2219/185 , B01J2219/1943 , B01J2219/1946 , C10G2/32 , C10G2/342 , C10G2/343 , C10G2300/4081 , C10G2300/70
摘要： A catalyst recovery system that includes a concentrated slurry production unit that concentrates a slurry extracted from a reactor main unit and continuously produces a concentrated slurry, a first discharge unit that discharges the concentrated slurry from the concentrated slurry production unit, a solidified slurry production unit that cools the concentrated slurry discharged from the concentrated slurry production unit, thereby solidifying the liquid medium within the concentrated slurry and producing a solidified slurry, and a recovery mechanism that recovers the solidified slurry from the solidified slurry production unit.

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