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61. 发明公开

EP1863864A4 CROSSLINKABLE BIOPOLYMER 审中-公开
标题翻译：网络生物多样性
公开(公告)号：EP1863864A4
公开(公告)日：2009-10-28
申请号：EP05806593
申请日：2005-11-03
申请人： JVS POLYMERS OY
发明人： SEPPAELAE JUKKA VELI
IPC分类号： C08G63/91 , C08F283/00 , C08F283/01 , C08F289/00 , C08F290/06 , C08F290/14 , C08G20060101 , C08G4/00 , C08L67/07 , C09D151/00 , C09D151/08 , C09D167/07 , C09J151/00 , C09J151/08 , C09J167/07
CPC分类号： C09J167/07 , C08F283/00 , C08F283/01 , C08F289/00 , C08F290/06 , C08F290/14 , C08G4/00 , C08G63/912 , C08L67/07 , C08L2666/02 , C09D151/003 , C09D151/08 , C09D167/07 , C09J151/003 , C09J151/08
摘要： A composition, prepolymer and method to produce a polymer based on biodegradable or essentially renewable crude materials, which can be crosslinked by free radicals. The composition is based on polyesters that are functionalized with unsaturated monomer units, in a way that unsaturated groups can be located along the polymer main chain as well as at the ends of the prepolymer. In connection to the product production, the prepolymer is exposed to free radicals that leads to network formation. The composition of the crosslinked biopolymer can be adjusted from a stiff engineering material to an elastic rubbery material. The new biopolymer can be used in composite materials, dispersions, barrier materials, rubbery materials, biomedical applications, and the like.

62. 发明公开

EP1888680A1 UNSATURATED POLYESTER RESIN OR VINYL ESTER RESIN COMPOSITION 有权
标题翻译：不饱和聚酯树脂或乙烯基酯树脂组合物含
公开(公告)号：EP1888680A1
公开(公告)日：2008-02-20
申请号：EP06754131.8
申请日：2006-06-06
申请人： DSM IP Assets B.V.
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L67/07 , C08L63/10 , C08K3/22 , C08K3/24 , C08K3/26 , C08K5/05 , C08K5/098 , C08K5/17 , C08F290/06 , C08F290/14 , C08L33/08 , C08L33/10
CPC分类号： C08L63/10 , C08K5/07 , C08L33/08 , C08L33/10 , C08L67/06 , C08L67/07 , C08L67/08 , C08L2666/04
摘要： This invention relates to unsaturated polyester resin or vinyl ester resin compositions comprising (I) a polymer containing reactive unsaturations as a resin; (ii) a 1,3-dioxo-component, and (iii) optionally a reactive diluent and/or an inhibitor and/or a stabilizer; the resin compositions being curable with a peroxide component, and wherein (a) the resin in the resin composition has an acid value ≤ 10; and (b) the resin composition contains - while being cured - a base, which is either (I) selected from the group of organic or inorganic oxides, hydroxides, alkoxides or carboxylates for each of which the cation has a redox potential of the metal of at most -1V, or of ammonium ions; or is (ii) selected from the group of nitrogen-containing organic compounds. The present invention also relates to objects and structural parts prepared from such resin composition by curing with a peroxide. Finally the invention also relates to methods of peroxide curing of unsaturated polyester or vinyl ester curing and its use in chemical anchoring, roof coatings etc.

63. 发明授权

EP1624024B1 BIODEGRADABLE POLYESTER RESIN COMPOSITION, PROCESS FOR PRODUCING THE SAME AND FOAMED ARTICLE AND MOLDED ARTICLE USING THE SAME 有权
标题翻译：生物可降解聚酯含组成，用于生产和波光粼粼的成型及其用途下
公开(公告)号：EP1624024B1
公开(公告)日：2007-07-04
申请号：EP03721095.2
申请日：2003-05-12
申请人： UNITIKA LTD.
发明人： UEDA, Kazue, UNITIKA LTD. , MATSUOKA, Fumio, UNITIKA LTD. , OGAMI, Akinobu, UNITIKA LTD. , MATSUMOTO, Tatsuya, UNITIKA LTD. , YANO, Takuma, /o UNITIKA LTD. , YOSHIMURA, Kazuko, /o UNITIKA LTD. , YAMADA, Kazunobu, /o UNITIKA LTD. , OKAMOTO, Masami
IPC分类号： C08L67/04 , C08L67/07 , C08K3/34 , C08K5/00 , C08J9/16
CPC分类号： C08K5/10 , C08J9/0061 , C08J2205/052 , C08J2367/04 , C08J2433/00 , C08K3/34 , C08K5/0008 , C08K5/103 , C08K5/11 , C08K5/1515 , C08K7/00 , C08K2201/008 , C08L67/04
摘要： It is intended to provide a biodegradable polyester resin composition which is excellent in gas barrier properties, mechanical strength and heat resistance and has rheological characteristics advantageously usable in molding a foamed article, etc., a process for producing the same, and a foamed article and a molded article using the same. The biodegradable polyester resin composition contains 100 parts by mass of a biodegradable polyester resin containing 50% mol or more of a hydroxycarboxylic acid unit, 0.01 to 10 parts by mass of a (meth)acrylic acid ester compound and 0.05 to 20 parts by mass of a layered silicate.

64. 发明公开

EP1753820A1 TRÄNKHARZFORMULIERUNG 有权
公开(公告)号：EP1753820A1
公开(公告)日：2007-02-21
申请号：EP05754530.3
申请日：2005-06-08
申请人： Altana Electrical Insulation GmbH
发明人： TÖDTER-KÖNIG, Sascha , HEGEMANN, Günter , ABENDROTH, Mark , LIENERT, Klaus-W.
IPC分类号： C08L67/06 , C08L67/07 , C09D167/06 , C09D167/07 , H02K3/30 , H02K3/44 , H01B3/42
CPC分类号： C09D167/06 , C08L33/08 , C08L33/10 , C08L67/06 , C08L67/07 , C08L71/02 , C09D167/07 , C08L2666/02
摘要： The invention relates to an impregnating resin formulation containing a component A which contains an unsaturated polyester resin comprising allyethers, a component B which contains dicyclopentadiene terminated, unsaturated polyester resin which is different from the component A, a component C which contains an additional unsaturated polymer which is different from polyester resins of components A and B, and, optionally, hardeners, accelerators, stabiliziers, additives and rheology additives. Said invention also relates to the use thereof in order to impregnate windings for the production of base materials of flat isolating material and in order to cover printed circuit boards.

65. 发明公开

EP1705218A1 Gel time drift-free resin compositions 审中-公开
标题翻译： Harzzusammensetzungen ohne Abtrift der Gelzeit
公开(公告)号：EP1705218A1
公开(公告)日：2006-09-27
申请号：EP05075689.9
申请日：2005-03-23
申请人： DSM IP Assets B.V.
发明人： Jansen, Johan Franz Gradus Antonius , Kleuskens, Engelina Catharina , Kraeger, Ivo Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L67/07 , C08L63/10 , C08F290/06 , C08F290/14 , C08F283/01
CPC分类号： C08K5/07 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions; that are curable with a peroxide component; and that, comprise - while being cured - an inhibitor, a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which compositions are essentially free of cobalt; and in which the dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by adjusting their transition metal content.
The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且其包含 - 同时固化 - 抑制剂，含有反应性不饱和度的聚合物，任选的反应性稀释剂和二氧代组分; 该组合物基本上不含钴; 并且其中二氧代组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，其是通过手段计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差的Turbomol版本5程序，范围为-5至-30千卡/摩尔。这些树脂组合物显示出降低的凝胶时间漂移趋势。此外，已经发现，通过调节它们的过渡金属含量，可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

66. 发明公开

EP1705216A1 Gel time drift-free resin compositions 审中-公开
标题翻译：凝胶时间漂移树脂组合物
公开(公告)号：EP1705216A1
公开(公告)日：2006-09-27
申请号：EP05075687.3
申请日：2005-03-23
申请人： DSM IP Assets B.V.
发明人： Jansen, Johan Franz Gradus Antonius , Kleuskens, Engelina Catharina , Kraeger, Ivo Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L67/07 , C08L63/10 , C08K3/22 , C08K3/24 , C08K3/26 , C08K5/05 , C08K5/098 , C08K5/17 , C08F290/06 , C08F290/14 , C08F4/40
CPC分类号： C08K5/07 , C08F283/01 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/14 , C08F290/141 , C08F290/144 , C08K5/14 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions; that are curable with a peroxide component; and that, comprise - while being cured - a salt and/or a base, a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which compositions are essentially free of cobalt; and contain either as the salt an organic or inorganic salt of which the cation has a redox potential of the metal of at most -1 V, or is an ammonium ion; and/or as the base either an inorganic base of which the cation has a redox potential of the metal of at most -1 V, or a nitrogen containing organic compound; and in which the dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by varying the amount of base.
The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且在固化时包含盐和/或碱，含有反应性不饱和基团的聚合物，任选的反应性稀释剂和二氧代组分; 该组合物基本上不含钴; 并且包含作为盐的有机或无机盐，其阳离子的金属氧化还原电位至多为-1V，或者是铵离子; 和/或作为碱或者是阳离子具有至多为-1V的金属氧化还原电位的无机碱，或者是含氮有机化合物; 并且其中二氧代组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，所述计算的还原能（CRE）是通过平均值计算的自由基阴离子和相应中性分子的最低能量构象之间的能量差（千卡/摩尔）的Turbomole版本5程序，范围从-5到-30千卡/摩尔。这些树脂组合物显示出减少的凝胶时间漂移趋势。此外，已经发现，通过改变碱的量，可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及由这种不饱和聚酯或乙烯基酯树脂组合物通过用过氧化物固化制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

67. 发明公开

EP1484371A2 Degradable powder coatings, methods and apparatus for powder coating biodegradable substrates and products produced thereby 审中-公开
标题翻译：可降解的粉末涂料，方法和用于可生物降解基材的粉末涂敷设备，因此制品制成
公开(公告)号：EP1484371A2
公开(公告)日：2004-12-08
申请号：EP04253051.9
申请日：2004-05-24
申请人： ROHM AND HAAS COMPANY
发明人： Annan, Nikoi , Horinka, Paul R. , Tullos, Tina L. , Zimmerman, Scott A.
IPC分类号： C09D167/00 , C09D167/02 , C09D167/04 , C09D167/06 , C09D167/07 , C09D5/03 , C08L67/02 , C08L67/04 , C08L67/06 , C08L67/07 , C08L67/08 , B29C41/00
CPC分类号： B29C33/18 , B05D1/002 , B05D1/06 , B05D3/0263 , B05D3/0493 , B05D2201/02 , B05D2401/32 , B29C41/003 , B29C41/20 , B29K2105/251 , C08L67/02 , C08L67/06 , C09D167/00 , C09D167/02 , Y10T428/1352 , C08L2666/18
摘要： An inventive powder composition comprises one or more than one finely divided resin chosen from a thermoplastic degradable copolyester resin containing both aliphatic and aromatic groups, a degradable UV curable polyester, a mixture of a cyclic oligomeric polyester resin, a ring opening polymerization catalyst and a degradable polyester, a degradable thermosetting polyester resin and mixtures thereof, the powder having an average particle size or diameter, as determined by laser light scattering, of from 30 to 125 µm. The composition provides thin, degradable coatings for foamed and biodegradable substrates, e.g. starch disposal articles. An apparatus for holding foam or light weight substrates comprises one or more than one perforated female pattern or jig molded in the shape of a substrate and a stand for holding said jig(s) having within it at least one enclosed chamber attached to one or more than one vacuum line, wherein the perforations in each of said jig(s) lead into said enclosed chamber. Coatings may be provided by placing a substrate in the jig, applying the powder composition to the substrate, and heating the substrate to flow out or melt said powder and to, with vacuum assistance, coalesce the melt or flow out to form a film to thoroughly coat the substrate.
摘要翻译：根据本发明的粉末组合物包含由含有脂族和芳族基团，一个可降解的UV可固化的聚酯，环状低聚聚酯树脂，开环聚合催化剂和可降解的混合物的热塑性降解共聚酯树脂中的一种或多于一种细碎树脂聚酯，可降解的热固性聚酯树脂和它们的混合物，平均具有颗粒尺寸或直径的粉末，通过激光散射作为确定性开采的从30至125微米。所述组合物提供用于发泡和可生物降解的基底薄，可降解的涂层，E.G. 淀粉处置文章。用于保持泡沫或轻基板的装置包括：在基片的形状和支架模制的一个或一个以上的穿孔的女性型或夹具用于保持所述夹具（一个或多个），其具有在其内的至少一个封闭的腔室连接到一个或多个多于一个的真空管线，worin在每个所述夹具（一个或多个）的穿孔引入所述封闭室中。涂层可以通过将底物转化成夹具，将粉末组合物的基材，并加热该基板流出或熔化所述粉末和，在真空的帮助，聚结熔体或流出被提供到形成膜，彻底涂覆基材。

68. 发明公开

EP1168934A4 HYDROGEL-FORMING SYSTEM WITH HYDROPHOBIC AND HYDROPHILIC COMPONENTS 有权
标题翻译：形成水凝胶的体系具有疏水和亲水组分
公开(公告)号：EP1168934A4
公开(公告)日：2004-12-08
申请号：EP00917865
申请日：2000-03-20
申请人： CORNELL RES FOUNDATION INC
发明人： WON CHEE-YOUB , ZHANG YELI , CHU CHIH-CHANG
IPC分类号： A61K9/20 , A61K9/22 , A61K9/58 , A61K31/405 , A61K38/00 , A61K38/28 , A61K47/32 , A61K47/36 , A61P3/10 , A61P29/00 , C08B37/02 , C08F299/00 , C08G18/64 , C08G18/81 , C08L5/02 , C08L67/07 , A23L1/28 , A23L1/36 , A23L2/02 , A23P1/00 , C08B37/00 , C08F16/06 , C08F116/06 , C08F216/06 , C08G18/00 , C08G63/48 , C08G63/91
CPC分类号： C08L5/02 , A61K9/205 , A61K47/36 , C08B37/0021 , C08G18/6484 , C08G18/8108 , C08G2210/00 , C08L67/07 , Y10S525/937 , C08L2666/02 , C08L2666/26
摘要： A hydrogel forming system which comprises a hydrophobic macromer with unsaturated group terminated ends and a hydrophilic polymer which is a polysaccharide (e.g., dextran) containing hydroxy groups which are reacted with unsaturated group introducing compound, is convertible by free radical polymerization to form a hydrogel containing a three dimensional crosslinked polymer network containing hydrophobic and hydrophilic components. Agent can be entrapped in the polymer network, e.g., drugs, macromolecules or synthetic or natural polymers, for controlled release therefrom.

69. 发明公开

EP1185567A1 ACRYLIC MODIFIED WATERBORNE ALKYD OR URALKYD DISPERSIONS 有权
标题翻译：水性丙烯酸改性醇酸树脂或Uralkyds
公开(公告)号：EP1185567A1
公开(公告)日：2002-03-13
申请号：EP00932794.1
申请日：2000-05-26
申请人： EASTMAN CHEMICAL COMPANY
发明人： CLARK, Mark, D. , HELMER, Bradley, J. , SHOAF, Glenn, L.
IPC分类号： C08F283/01 , C08F283/00 , C08G63/21 , C08L67/07
CPC分类号： C08F273/00 , C08F283/00 , C08F283/006 , C08F283/01 , C08F283/02 , C08F291/00 , C08G63/48 , C08G63/6888 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , C09D167/07 , C09D167/08 , C08L2666/02 , C08L33/00
摘要： A water-based latex of an acrylic-modified waterborne alkyd or uralkyd dispersion inwater is described. The acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by the polymerization of at least one latent oxidatively-functional (LOF) acrylic monomer in the presence of a waterborne alkyd or uralkyd. Alternatively, the acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by shearing a mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer. Preparation of the latexes may be achieved by emulsion polymerization of at least one latent oxidatively-functional acrylic monomer in the presence of a waterborne alkyd or uralkyd whereby the latent oxidative functionality of the acrylic polymer survives polymerization. Water-based latexes may also be prepared by polymerizing a sheared mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer such that the latent oxidative functionality of the acrylic polymer survives polymerization. Such acrylic-modified waterborne alkyd or uralkyds are useful in a variety of coating compositions.

70. 发明公开

EP1181334A1 RESIN COMPOSITION BASED ON UNSATURATED POLYESTER 审中-公开
标题翻译：树脂组合物基于不饱和聚酯
公开(公告)号：EP1181334A1
公开(公告)日：2002-02-27
申请号：EP00927974.6
申请日：2000-05-11
申请人： DSM N.V.
发明人： BUHL, Dieter , GERTH, Dale , ZWECKER, Joachim
IPC分类号： C08L67/06 , F21V7/22 , C08L67/07
CPC分类号： F21V15/01 , C08L67/06 , C08L67/07 , F21S41/37 , F21V7/22
摘要： The invention relates to a resin composition comprising (A) an unsaturated polyester, (B) a monomer that is copolymerizable with the unsaturated polyester (A), (C) optionally an anti-shrink component, (D) reinforcing fibres and (E) fillers, and is characterized in that the unsaturated polyester (A) has an acid number of less than 18 mg KOH/g and is a combination of a standard unsaturated polyester (A1) having an acid number of more than 13 mg of KOH/g and of a modified unsaturated polyester (A2) having an acid number of less than 13 mg of KOH/g, the acid number being as measured according to ISO 3682.

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